Search   
MSDS  
:
 RESORCINOL, R1000
CAS  
:
 108-46-3
NAME  
:
 resorcinol. (mf: c6h602) (ec no.: 203-585-2)
=====================  Product Identification  =====================

MSDS NAME:RESORCINOL, R1000
Status Code:A
MSDS Number: CKWKH
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010
Emergency Phone Num:(314) 771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076

=============  Composition/Information on Ingredients  =============

Name:RESORCINOL. (MF: C6H602) (EC NO.: 203-585-2)
CAS:108-46-3
RTECS #:VG9625000
Other REC Limits:NIOSH TWA 10 PPM
ACGIH TLV:45 MG/M3;10 PPM
ACGIH STEL:90 MG/M3;20 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: 301 MG/KG, ORAL-RAT.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: HARMFUL IF SWALLOWED.
    MAY BE HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGH THE
    SKIN. CAUSES SEVERE EYE IRRITATION. CAUSES SKIN IRRITATION.
    MATERIALL IS IRRITATING TO MUCOUS MEM BRANES AND UPPER RESPIRATORY
    TRACT. DEPENDING ON  THE INTENSITY AND DURATION OF EXPOSURE,
    EFFECTS MAY VARY FROM MILD IRRITATION TO SEVERE DESTRUCTION OF
    TISSUE. PROLONGED CONTACT CAN CAUSE: DAMAGE TO  THE EYES, SEVERE
    IRRITATION OR BURNS.  CHRONIC: TARGET ORGAN(S): BLOOD, NERVES,
    THYROID, LIVER, KIDNEYS. TO THE BEST OF OUR KNOWLEDGE, THE
    CHEMICAL, PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN 
    THOROUGHLY INVESTIGATED.
Explanation of Carcinogenicity:THIS PRODUCT IS OR CONTAINS A COMPONENT
    THAT HAS BEEN REPORTED TO BE POSSIBLY CARCINOGENIC BASED ON ITS
    IARC, ACGIH, NTP OR EPA CLASSIFICATION.
Effects of Overexposure:SEE HEALTH HAZARDS ACUTE AND CHRONIC .

=======================  First Aid Measures  =======================

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
    COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
    CONTAMINATED CLOTHING AND SHOES. ASSURE ADEQUATE FLUSHING OF THE
    EYES BY SEPARAT ING THE EYELIDS WITH FINGERS. IF INHALED, REMOVE TO
    FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
    BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH
    WITH WATER PROVIDED PE RSON IS CONSCIOUS. CALL A PHYSICIAN
    IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE.

=====================  Fire Fighting Measures  =====================

Autoignition Temp:=607.8C, 1126.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
    FOAM.
Fire Fighting Procedures:WEAR (NIOSH APPROVED - ) SELF-CONTAINED
    BREATHING APPARATUS AND  PROTECTIVE CLOTHING TO PREVENT CONTACT
    WITH SKIN AND EYES. USE WATER SPRAY TO COOL FIRE-EXPOSED
    CONTAINERS.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
    CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS (NIOSH
    APPROVED - ), RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH DRY
    LIME OR SODA ASH, PICK UP, KEEP IN A CLOSED CONTAINER AND HOLD FOR
    WASTE DISPOSAL.  VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL
    PICKUP IS COMPLETE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:WEAR APPROPRIATE NIOSH-APPROVED
    RESPIRATOR, CHEMICAL RESISTANT GLOVES, SAFETY GOGGLES, OTHER
    PROTECTIVE CLOTHING. USE ONLY IN A CHEMICAL FUME HOOD. DO NOT
    BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON  CLOTHING. TOXIC.
    SEVERE EYE IRRITANT. KEEP TIGHTLY CLOSED. STORE IN COOL DRY PLACE.
Other Precautions:REACTS WITH ACETANILIDE, ALBUMIN, ANTIPYRINE,
    CAMPHOR, MENTHOL AND URETHANE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR APPROPRIATE NIOSH-APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:WEAR CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
    FACESHIELD .
Other Protective Equipment:SAFETY SHOWER AND EYE BATH (MEETING ANSI
    DESIGN CRITERIA - ). WEAR OTHER PROTHECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.  WASH
    CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
SYNONYMS: BENZENE, M-DIHYDROXY-, M-BENZENEDIOL, 1,3-BENZENEDIOL, C.I.
    76505, C.I. DEVELOPER 4, C.I. OXIDATION BASE 31, DEVELOPER 0,
    DEVELOPER R, DEVELOPER RS, M-DIHYDROXYBENZENE,
    1,3-DIHYDROXYBENZENE,  M-DIOXYBENZENE, DURAFUR DEVELOPER G,
    FOURAMINE RS,  FOURRINE 79, FOURRINE EW, M-HYDROQUINONE,  (OTHER
    INFO)

==================  Physical/Chemical Properties  ==================

Boiling Pt:=178.C, 352.4F
B.P. Text:@ 16 MM.
Melt/Freeze Pt:=110.C, 230.F
M.P/F.P Text:110 C TO 113 C (MELT PT).
Vapor Pres:1 MM  @ 21.1 C.
Vapor Density:3.8
Spec Gravity:1.271
Solubility in Water:SOLUABLE (SEE OTHER INFO)
Appearance and Odor:WHITE POWDER, ODOR:NONE SPECIFIED BY MANUFACTURER .

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
INCOMPATIBILITIES: ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS,
    IRON AND IRON SALTS.
Stability Condition to Avoid:LIGHT SENSITIVE. AIR SENSITIVE.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
    CARBON DIOXIDE.

===================  Toxicological Information	===================

Toxicological Information:IRRITATION DATA: SKN - RBT 500 MG (IHFCAY
    6,1,67), SKN - RBT 20 MG/24H MOD (85JCAE -,234,86), EYE - RBT 100
    MG SEV (BIOFX* 11-4/70).  TOXICITY DATA: ORL - HMN LDLO: 29 MG/KG
    (34ZIAG -,519,69), ORL - R AT LD50: 301 MG/KG (BIOFX* 11-4/70), ORL
    - MUS LD50: 200 MG/KG (JJTOEX 4,105,91), IPR - MUS LD50: 215 MG/KG
    (BEXBAN 61,291,66), SCU - MUS LD50: 213 MG/KG (ZGIMAL 2,333,47),
    SKN - RBT LD50: 3360 MG/KG	(AIHAAP 37,596,76).  TARGET ORGAN DATA:
    PERIPHERAL NERVE AND SENSATION (SPASTIC PARALYSIS WITH / WITHOUT
    SENSORY CH), BEHAVIORAL (CONVULSIONS OR EFFECT ON SEIZURE
    THRESHOLD), BEHAVIORAL (EXCITEMENT),  BEHAVIORAL  (ECOLOGICAL
    INFORMATION)

=====================  Ecological Information  =====================

Ecological:DATA NOT YET AVAILABLE.     TOXICOLOGICAL INFORMATION
    (CONT): (TETANY), BEHAVIORAL (COMA), CARDIAC (OTHER CHANGES),
    LUNGS, THORAX OR RESPIRATION (DYSPNAE), GASTROINTESTINAL (CHANGES
    IN STRUCTURE OR FU NCTION OF SALIVARY GLANDS), BLOOD:
    (METHEMOGLOBINEMIA-CARBOXHEMOGLOBINEMIA). ONLY SELECTED REGISTRY OF
    TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED
    HERE. SEE ACTUAL ENTRY IN RTECS FO R COMPLETE INFORMATION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
    SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
    AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
    ENVIRONMENTAL REGULATIONS.

===================  MSDS Transport Information  ===================

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
    INFORMATION. UN2876 (DOT).	    LABEL PRECAUTIONARY STATEMENTS:
    TOXIC (USA). HARMFUL (EU). HARMFUL IS SWALLOWED. IRRITATING TO
    RESPIRATORY SYSTEM AND  SKIN. RISK OF SERIOUS DAMAGE TO EYES.
    TARGET ORGAN(S): BLOOD, NERVES. IN CASE OF CONTACT WITH EYES, RINSE
    IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEAR
    SUITABLE PROTECTIVE CLOTHING. D O NOT BREATHE DUST.

=====================  Regulatory Information  =====================

SARA Title III Information:N/P.     REVIEWS, STANDARDS, AND
    REGULATIONS: OEL=MAK. ACGIH TLV-NOT CLASSIFIABLE AS A HUMAN
    CARCINOGEN	(DTLVS* TLV/BET,96); ACGIH TLV - STEL 90 MG/M3 (20 PPM)
     (DTLVS* TLV/BEI,96); ACGIH TLV - TWA 4 5 MG/M3 (10 PPM) (DTLVS*
    TLV/BEI,96); IARC CANCER REVIEW: ANIMAL INADEQUATE EVIDENCE (IMEMDT
    15,155,77); IARC CANCER REVIEW: HUMAN NO ADEQUATE DATA (IMEMDT
    15,155,77); IARC CANCER REVIEW: GROUP 3 (IMS UDL 7,56,87); OEL -
    AUSTRALIA, BELGIUM, FINLAND, & UNITED KINGDOM: TWA 10 PPM (45
    MG/M3); STEL 20 PPM (90 MG/M3) JAN93. OEL - DENMARK, FRANCE, THE
    NETHERLANDS, SWITZERLAND:TWA 10 PPM (45 MG/M3) JAN93.  OEL -
    HUNGARY: TWA (FEDERAL REGULATORY)
Federal Regulatory Information:EUROPEAN INFORMATION: EC INDEX NO.
    604-010-00-1. HARMFUL. R 22 HARMFUL IF SWALLOWED. R 36/38 
    IRRITATING TO EYES AND SKIN. R50 VERY TOXIC TO AQUATIC ORGANISMS. S
    26 IN CASE OF CONTACT WITH EYES, RINSE  IMMEDIATELY WITH PLENTY OF
    WATER AND SEEK MEDICAL ADVICE. S 61 AVOID RELEASE TO THE
    ENVIRONMENT. REFER TO SPEICIAL INSTRUCTIONS/SAFETY DATA SHEETS.  
    SARA III (CONT): MG/M3, STEL 90 MG/M3, SKIN JAN93 ; OEL IN
    BULGARIA, COLOMBIA, JORDAN, KOREA, NEW ZEALAND, SINGAPORE, VIETNAM:
    CHECK ACGIH TLV. NIOSH  REL TO RESORCINAL-AIR: 10H TWA 10 PPM, STEL
    20 PPM (NIOSH* DHHS #92-100,92); NOHS 1974: HZD 67220, NIS 45, TNF
    4488, (STATE REGULATORY)
State Regulatory Information:N/P.    FEDERAL REGULATORY (CONT): NOS 42,
    TNE 40431; NOES 1983: HZD 67220, NIS 30, TNF 6642, NOS 43, TNE
    100792, TFE 56465; EPA GENETOX PROGAM 1988, INCONCLUSIVE; MAMMALIAN
    MICRONUCLEUS. EPA TSCA SEC TION 8(B) CHEMICAL INVENTORY. EPA TSCA
    SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES. EPA TSCA TEST
    SUBMISSION (TSCATS) DATA BASE, JANUARY 1997. NTP CARCINOGENESIS
    STUDIES (GAVAGAE); NO EVIDENCE: MOU SE, RAT. NTPTR,  NTP-TR-403,92.
    CARCINOGENESIS STUDIES; LABORATORY ASSIGNED, NOV 1996.
    CARCINOGENESI S STUDIES; ON TEST (PRECHRONIC STUDIES), NOV 1966.

=======================  Other Information  =======================

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***
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NAMECAS
BATTERY WET FILLED W/ ALKALI 8 UN2795 PGIII (NICKEL CADMIUM)
METHYL ALCOHOL 67-56-1
NICKEL CADMIUM AIRCRAFT BATTERY 7440-43-9
21041-95-2
1306-19-0
7440-02-0
12054-48-7
1313-99-1
1310-58-3
7440-48-4
MS-944/CO2 SAFEZONE CLEANING SOLVENT 1717-00-6
67-56-1
75-52-5
124-38-9
A-464-4, 2- PROPANOL 67-63-0
4883077, MOPAR POWER STEERING FLUID 64742-65-0
64742-53-6
64742-71-8
LEAD ACID BATTERY (SEE SUPPLEMENTAL) 7439-92-1
7664-93-9
LEAD-ACID BATTERY 7439-92-1
7440-36-0
7440-38-2
7440-70-2
7440-31-5
7664-93-9
LEAD-ACID BATTERY 7439-92-1
7440-36-0
7440-38-2
7440-70-2
7440-31-5
7664-93-9
9003-07-0
60676-86-0
STARCH,SOLUBLE,ACS REAGENT 9005-84-9
71522, DARINA EP GREASE 2 1302-78-9
15890-25-2
MS-260 SAFEZONE CLEANER FOR PLASTIC, GLASS & METAL 111-76-2
64-17-5
67-56-1
68476-85-7
ZINC CHLORIDE BATTERIES-"NO MERCURY, NO CADMIUM" FORMULA 7439-89-6
1313-13-9
7440-66-6
7782-42-5
7646-85-7
7439-92-1
CONDUCTIVITY NEUTRALIZING SOLUTION, R-7022 67-63-0
77-09-8
77-92-9
7732-18-5
ARDROX 9D6/D495A NON-AQUEOUS DEVELOPER 71-55-6
78-92-2
14808-60-7
471-34-1
ROYCO 770, TYPE 1 AND 2 68649-12-7
25619-56-1
PROPYLENE GLYCOL INDUSTRIAL 57-55-6
CAPASTIC PART A 25068-38-6
1317-65-3
14808-60-7
PO0011, HYSOL PC18M 108-65-6
1330-20-7
100-41-4
108-88-3
26471-62-5
SODIUM BOROHYDRIDE S678-25, S67810, S67825 16940-66-2
SODIUM BOROHYDRIDE, S678 10, S678 25, S678-10 16940-66-2
RANGE GUARD KARBOLOY FIRE EXTINGUISHER SUPPRESSION AGENT 584-08-7
21189, DIETHYLENETRIAMINE 111-40-0
222555, FMR1002, PASA-JELL 105 7664-93-9
7738-94-5
178 2713,PT A,KODAK EKTACOLOR SM PROCESSING UNIT P1 / RA-2SM 7732-18-5
3710-84-7
102-71-6
82640-05-9
7647-14-5
178 2713,PT B,KODAK EKTACOLOR SM PROCESSING UNIT P1 / RA-2SM 7732-18-5
25646-71-3
10377-48-7
10117-38-1
178 2713,PT C,KODAK,EKTACOLOR SM PROCESSING UNIT P1/RA-2SM 7732-18-5
584-08-7
1310-58-3
140-01-2
2809-21-4
178 2713,PT D,KODAK EKTACOLOR SM PROCESSING UNIT P1 / RA-2SM 7732-18-5
9003-39-8
68585-34-2
10377-60-3
NITROGEN IN HELIUM 0.0001% TO 50%, G-154 7440-59-7
7727-37-9
CATALYST 9 112-57-2
112-24-3
4067-16-7
MC 1210 1330-78-5
64742-54-7
METHYL ETHYL KETONE
METHYL ETHYL KETONE
METHYL ETHYL KETONE
BALLISTOL-LUBE 78-83-1
LUPERSOL DON-9, 129 1338-23-4
131-11-3
6846-50-0
107-41-5
78-93-3
7732-18-5
7722-84-1
CATALYST 11 108-45-2
872-50-4
RESORCINOL, R1000 108-46-3
526 3330,KODAK ECN-2 KIT STOP BLEACH AND REPLENISHER 7732-18-5
64-19-7
127-08-2
7757-79-1
7758-02-3
CARTRIDGE, CARBON DIOXIDE 124-38-9
TBF 9-5 63148-62-9
B-534-1-66 RULE 66 INSULATING VARNISH 2807-30-9
1330-20-7
100-41-4
64742-89-8
108-10-1
71-36-3
50-00-0
D.E.R. 732 EPOXY RESIN, 19369 26142-30-3
848 4735,ALTERNATE EDTA DEVELOPER,EASTMAN (SEE SUPPL DATA) 2051-79-8
7757-83-7
64-02-8
7732-18-5
497-19-8
848 4735,DEVELOPER,EASTMAN ECP-2B DEVELOPER (SEE SUPPL DATA) 7732-18-5
497-19-8
2051-79-8
7757-83-7
7647-15-6
C7810-C7820-C7830, SODIUM THIOSULFATE 7772-98-7
STYCAST 2651 BLACK 12001-26-2
122-60-1
1333-86-4
ESP SOLDER PASTE, SOLDER CREAM, SOLDERPLUS 7440-31-5
7439-92-1
7440-22-4
7440-69-9
8009-03-8
68526-86-3
98-55-5
65997-06-0
OXYGEN CANDLE 7775-09-9
1304-29-6
7439-89-6
OXYGEN CANDLE (IGNITER) 7723-14-0

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