===================== Product Identification =====================
MSDS NAME:LUPERSOL DON-9, 129
Status Code:A
MSDS Number: CKWKF
=== Responsible Party ===
Company:ELF ATOCHEM NORTH AMERICA, INC. FINE CHEMICALS GROUP
Address:2000 MARKET STREET ORGANIC PEROXIDES
City:PHILADELPHIA
State:PA
ZIP:19103-3222
Country:US
Info Phone Num:800-245-5858/800-558-5575
Emergency Phone Num:(800)424-9300
Chemtrec Ind/Phone:(800)424-9300
CAGE:86460
=== Contractor Identification ===
Company:ELF ATOCHEM NORTH AMERICA INC
Address:2000 MARKET STREET
Box:City:PHILADELPHIA
State:PA
ZIP:19103-3222
Country:US
Phone:800-245-5858
CAGE:86460
Company:FIBERGLASS HAWAII INC
Address:1377 COLBURN ST
Box:City:HONOLULU
State:HI
ZIP:96817-4902
Country:US
Phone:808-847-3951
CAGE:6F504
============= Composition/Information on Ingredients =============
Name:METHYL ETHYL KETONE PEROXIDE STRUCTURES
CAS:1338-23-4
RTECS #:EL9450000
= Wt:35.
ACGIH STEL:0.2 PPM (CEILING)
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:DIMETHYL PHTHALATE
CAS:131-11-3
RTECS #:TI1575000
= Wt:32.
OSHA PEL:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:2,2,4-TRIMETHYL-1,3-PENTANEDIOL DIISOBUTYRATE.
CAS:6846-50-0
= Wt:23.
Name:HEXYLENE GLYCOL
CAS:107-41-5
RTECS #:SA0810000
= Wt:4.
OSHA STEL:25 PPM (CEILING)
Name:METHYL ETHYL KETONE
CAS:78-93-3
RTECS #:EL6475000
= Wt:1.
OSHA PEL:200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
= Wt:1.5
Name:HYDROGEN PEROXIDE
CAS:7722-84-1
RTECS #:MX0899000
= Wt:.7
OSHA PEL:1 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN CONTACT AND INHALATION EXPECTED
PRIMARY ROUTES OF OCCUPATIONAL EXPOSURE TO METHYL ETHYL KETONE
PEROXIDE (MEKP). MEKP CAN BE DESTRUCTIVE TO TISSUE, PRODUCING BURNS
ON CONTACT WITH ANY BODY TISSUES . CONTACT WITH EYES CAN CAUSE
SEVERE IRRITATION & INJURY, POSSIBLY WITH LOSS OF SIGHT. WHILE
SWALLOWING OF MEKP IS UNLIKELY, IF SWALLOWED, MATERIALL CAN CAUSE
SEVERE IRRITATION & INJURY TO MOUTH, THRO AT, STOMACH & LIVER,
LIVER FAILURE & RESPIRATORY DISTRESS; DEATH MAY FOLLOW.
OVEREXPOSURE TO MEKP VAPORS MAY CAUSE EYE AND RESPIRATORY TRACT
IRRITATION, WITH HEADACHE AND DIZZINESS. ALLERGIC SKIN RESP ONSE
(SIGNS & SYMPTOMS OF OVEREXPOSURE)
Explanation of Carcinogenicity:AS OF THE DATE ON WHICH THIS MSDS WAS
PREPARED, THESE CHEMICALS ARE NOT CLASSIFIED AS CARCINOGENIC BY
IARC, NTP OR OSHA.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT): IS
RARE, BUT HAS BEEN REPORTED FOR MEKP. THIS MATERIAL IS CONSIDERED,
ON BASIS OF SINGLE EXPOSURE (ACUTE) ANIMAL TESTS, TO BE MODERATELY
TOXIC AFTER INGESTION.
======================= First Aid Measures =======================
First Aid:INGESTION: DO NOT INDUCE VOMITING. GET EMERGENCY MEDICAL
ATTENTION FOR GAVAGE. DERMAL: FLUSH WITH SOAP AND WATER. GET
MEDICAL ATTENTION. EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF
WATER FOR AT LE AST 15 MINUTES. GET EMERGENCY MEDICAL ATTENTION.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:=58.3C, 137.F
Extinguishing Media:WATER FOG, DRY CHEMICAL, FOAM, WATER SPRAY.
Fire Fighting Procedures:IF LARGE AMOUNT IS INVOLVED, EVACUATE AREA AND
FIGHT FIRE FROM SAFE DISTANCE. COOL SURROUNDING MATERIAL WITH
WATER. WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTAMINATION, TEMPERATURE - CAN
DECOMPOSE WITH FORCE IF CONFINED DURING EXPOSURE TO FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBANT MATERIAL , SWEEP OR SCOOP UP
USING NON-SPARKING TOOLS & DISPOSE OF IMMEDIATELY.
====================== Handling and Storage ======================
Handling and Storage Precautions:PRECAUTIONARY LABELING: WASH
THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN OR CLOTHING.
DO NOT STORE NEAR COMBUSTIBLES. EMPTY CONTAINER MAY CONTAIN
HAZARDOUS RESIDUES. KEEP CONTAINER CLOSED. KEEP AWAY FROM HEAT,
SPARKS AND FLAME. DO NOT REUSE CONTAINER.
Other Precautions:OTHER STORAGE AND HANDLING CONDITIONS: STORE BELOW
100F TO MAINTAIN ACTIVE OXYGEN CONTENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ONLY NIOSH APPROVED EQUIPMENT. RESPIRATOR
TYPE: SUPPLIED AIR RESPIRATOR WITH FULL FACE PIECE, HOOD OR
HELMET.
Ventilation:USE WITH ADEQUATE VENTILATION. LOCAL EXHAUST.
Protective Gloves:NEOPRENE, NITRILE RUBBER.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES & FULL FACESHIELD
.
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Supplemental Safety and Health
CHEMICAL NAME: METHYL ETHYL KETONE PEROXIDE. MOLECULAR FORMULA:
MIXTURE OF C4H10O4 AND C8H16O6. CHEMICAL FAMILY: ORGANIC PEROXIDE.
SYNONYMS: 2-BUTANONE PEROXIDE. PHYSICAL AND CHEMICAL PROPERTIES (
CONT): MOLECULAR WEIGHT: N/A. * S.A.D.T = SELF ACCELERATING
DECOMPOSITION TEMPERATURE.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:<-30.C, -22.F
Decomp Temp:=70.C, 158.F
Decomp Text:45# CUBE (S.A.D.T.)
Vapor Density:N/E
Spec Gravity:1.0840 MIN. @ 25C (H20=1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, OILY LIQUID, KETONE ODOR.
Percent Volatiles by Volume:N/E
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
STRONG ACIDS, STRONG ALKALIS, STRONG OXIDIZERS, ACETONE, TRANSITION
METAL SALTS, PROMOTERS AND REDUCING AGENTS.
Stability Condition to Avoid:UNSTABLE. CONDITIONS CONTRIBUTING TO
INSTABILITY: THERMAL DECOMPOSITION, CONTAMINATION. CONDITIONS TO
AVOID: HEAT, FLAMES, SPARKS, IGNITION SOURCES, CONTAMINATION.
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS ARE FLAMMABLE
AND MAY AUTOIGNITE.
=================== Toxicological Information ===================
Toxicological Information:DATA FROM SCIENTIFIC LITERATURE ON METHYL
ETHYL KETONE PEROXIDE (MEKP) ARE SUMMARIZED BELOW: SINGLE EXPOSURE
(ACUTE) STUDIES ON 40-60% MEKP IN DIMETHYL PHTHALATE INDICATE:
ORAL-MODERATELY TOXIC TO RAT S (LD50 484 MG/KG). DERMAL - SLIGHTLY
TOXIC TO RABBITS (LD50 4000 MG/KG). INHALATION - PRACTICALLY
NON-TOXIC TO RATS (4 HR-LC50 17-50 MG/L). EYE IRRITATION -CORROSIVE
TO RABBITS. SKIN IRRITATION - MOD ERATELY IRRITATING TO RABBITS (4
HR EXPOSURE, 4.5 / 8.0). REPEATED ORAL ADMINISTRATION OF
INTRAPERITONEAL INJECTION (7 WKS) OF MEKP (07 MG/KG/DAY) WAS
REPORTED TO RESULT IN DEPCREASED BODY WEIGHT, MI LD LIVER INJURY
(STATE REGULATORY)
===================== Ecological Information =====================
Ecological:ECOTOXICOLOGICAL INFORMATION - METHYL ETHYL KETONE PEROXIDE:
96 HR LC50 GUPPY: 44.2 MG/L, SLIGHTLY TOXIC. CHEMCAL FATE
INFORMATION: METHYL ETHYL KETONE PEROXIDE (MEKP) WAS EVALUATED FOR
BIODEGRADABIL ITY IN A CLOSED BOTTLE SYSTEM AND WAS REPORTED TO BE
REDADILY BIODEGRADABLE. AN EC50 OF 16 MG MEKP/L ACTIVATED SLUDGE
REPORTED WAS REPORTED IN AN ACTIVATED SLUDGE RESPIRATION INHIBITION
TEST.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT WITH AN ELF ATOCHEM REPRESENTATIVE FOR
THE TELEPHONE NUMBER OF YOUR STATE'S HAZARDOUS WASTE AGENCY.
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL
REGULATIONS .
=================== MSDS Transport Information ===================
Transport Information:D.O.T. SHIPPING NAME: ORGANIC PEROXIDE TYPE D,
LIQUID (METHYL ETHYL KETONE PEROXIDE(S) <45%). HAZARD
CLASSIFICATION: 3.2. ID NUMBER: UN3105. FREIGHT CLASSIFICATION: NOI
BN. IMDO CODE PAGE: 3225.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS TOXIC CHEMICALS
SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372:
DIMETHYL PHTALATE AND METHYL ETHYL KETONE
Federal Regulatory Information:THIS PRODUCT IS LISTED ON THE US EPA,
TSCA INVENTORY.
State Regulatory Information:AS OF THE DATE THIS MSDS WAS PREPARED,
THESE CHEMICALS ARE NOT LISTED UNDER CALIFORNIA PROPOSITION 65.
TOXICOLOGICAL INFO (CONT): AND DEATH IN RATS. FOLLOWING REPEATED
SKIN APPLICATION (13 WEEKS) O F MEKP IN DIMETHYL PHTHALATE AT DOSES
UP TO 107 MG/RAT/DAY AND 35.7 MG/MOUSE/DAY, SEVERE SKIN DAMAGE AND
ANIMAL DEATHS (ONLY AT THE HIGHEST DOSE LEVELS) WERE THE PRIMARY
EFFECTS IN RATS AND MICE. SPLE EN AND BONE MARROW CHANGES,
CONSIDERED SECONDARY TO THE SEVERE SKIN DAMAGE, WERE NOTED IN
ANIMALS AT THE HIGHEST DOSES. HIGHER DOSES (UP TO 810 AND 1800
MG/KG/DAY IN RATS AND MICE, RESPECTIVELY) APPLIED TO RAT AND MOUSE
(OTHER INFORMATION)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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