===================== Product Identification =====================
MSDS NAME:METHYL ALCOHOL
NIIN:00-687-8056
Status Code:A
MSDS Number: CKWHJ
=== Responsible Party ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
City:RICHMOND
State:VA
ZIP:23222
Country:US
Info Phone Num:804-264-5183
Emergency Phone Num:804-264-5183
Preparer's Name:NOT PROVIDED
Chemtrec Ind/Phone:(800)424-9300
CAGE:0YED2
=== Contractor Identification ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP0450-01-M-X035
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:METHYL ALCOHOL
CAS:67-56-1
RTECS #:PC1400000
Minumum % Wt:99.
Maxumum % Wt:100.
Other REC Limits:200 PPM (NIOSH)
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) = 5,628 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE MODERATE IRRITATION
AND PAINFUL SENSITIZATION TO LIGHT. SKIN: MAY CAUSE IRRITAION. MAY
BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INGESTION: MAY CAUSE
IRRITATION OF DIGESTIVE TRACT A ND RESPIRATORY FAILURE. MAY CAUSE
VASCULAR COLLAPSE, DAMAGE AND KIDNEY FAILURE. INHALATION: MAY CAUSE
RESPIRATORY IRRITATION, LIVER AND KIDNEY DAMAGE. MAY CAUSE ADVERSE
CNS EFFECTS INCLUDING HEADACHE, CONVULSIONS, AND POSSIBLE DEATH.
MAY CAUSE VISUAL IMPAIRMENT, POSSIBLE PERMANENT BLINDNESS. CHRONIC:
MAY CAUSE DERMATITIS. CHRONIC INHALATION AND INGESTION MAY CAUSE
EFFECTS SIMILAR TO THOSE OF ACUTE INHALATION AND INGESTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: MAY CAUSE MODERATE IRRITATION AND PAINFUL
SENSITIZATION TO LIGHT. SKIN: MAY CAUSE IRRITAION. INGESTION: MAY
CAUSE IRRITATION OF DIGESTIVE TRACT AND RESPIRATORY FAILURE. MAY
CAUSE VASCULAR COLLAP SE, DAMAGE AND KIDNEY FAILURE. INHALATION:
MAY CAUSE RESPIRATORY IRRITATION, LIVER AND KIDNEY DAMAGE. MAY
CAUSE ADVERSE CNS EFFECTS INCLUDING HEADACHE, CONVULSIONS, AND
POSSIBLE DEATH. MAY CAUSE VISUA L IMPAIRMENT, POSSIBLE PERMANENT
BLINDNESS.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
Eyes: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY
LIFTING UPPER AND LOWER LIDS. GET MEDICAL AID IMMEDIATELY. DO NOT
ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH WITH PLENTY OF
SOAP AND WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET
MEDICAL AID IF IRRITAION DEVELOPS/PERSISTS. INGESTION: IF VICTIM IS
CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MEDICAL
AID IMME DIATELY. INDUCE VOMITING BY GIVING 1 TEASPOON OF SYRUP OF
IPECAC. INHALATION: GET MEDICAL AID IMMEDIATELY. REMOVE FROM
EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
===================== Fire Fighting Measures =====================
Flash Point:=12.C, 53.6F
Autoignition Temp:=455.C, 851.F
Lower Limits:6.0
Upper Limits:36.0
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM. USE WATER SPRAY TO COOL
FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR. DURING A FIRE, IRRITATING
AND HIGHLY TOXIC GASES MAY BE GEN ERATED BY THERMAL DECOMPOSITION
OR COMBUSTION.
Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE IF
EXPOSED TO HEAT AND/OR FIRE. VAPORS CAN TRAVEL TO A SOURCE OF
IGNITION AND FLASH BACK. FLAMMABLE LIQUID. CAN RELEASE VAPORS THAT
FORM FLAMMABLE MIXTURES AT TEMPERAT URES AT OR ABOVE THE
FLASHPOINT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
SPILLS/LEAKS: SCOOP UP WITH A NON-SPARKING TOOL, THEN PLACE INTO A
SUITABLE CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE
GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING AN
ABSORBENT, NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND, OR
VERMICULITE.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION.
STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
SUBSTANCES. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES,
SKIN, CLOTHING. DO NOT INGEST OR INHALE.
Other Precautions:WASH THROUGHLY AFTER HANDLING. REMOVE CONTAMINATED
CLOTHING AND WASH BEFORE REUSE. USE WITH ADEQUATE VENTILATION.
EMPTY CONTAINERS RETAIN PRODUCT RESIDUE, (LIQUID AND/OR VAPOR), AND
CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, SPARKS OR FLAMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR1910.134. ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:WEAR APPROPRIATE PROTECTIVE GLOVES AND CLOTHING TO
PREVENT SKIN EXPOSURE.
Eye Protection:WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL
SAFETY GOGGLES.
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT SKIN EXPOSURE.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT
PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT
ESTABLISHED. CNS=CENTRAL NERVOUS SYSTEM. GI=GASTROINTESTINAL.
================== Physical/Chemical Properties ==================
HCC:F5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=64.8C, 148.6F
Melt/Freeze Pt:=-98.C, -144.4F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:29 MM HG (20C/68F)
Vapor Density:1.1
Spec Gravity:0.7910Q/CM3
Viscosity:0.006 P AT 68F
Evaporation Rate & Reference:NONE KNOWN
Solubility in Water:MISICIBLE WITH WATER
Appearance and Odor:CLEAR COLORLESS LIQUID, SLIGHT ALCOHOL-LIKE ODOR
Percent Volatiles by Volume:99-100
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDANTS (SUCH AS BAIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN
PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, SODIUM HYPOCHLORITE).
ACTIVE METALS (POTASSIUM AND MAGNESIUM). SEE NFPA FIRE PROTECTION
GUIDE.
Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS,
IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE.
=================== Toxicological Information ===================
Toxicological Information:INHALATION RAT: LC50=64000 PPM/4H; ORAL
MOUSE: LD50=7300 MG/KG; ORAL, RABBIT: LD50=14200 MG/KG; SKIN,
RABBIT: LD50=15800 MG/KG.
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH LOCAL,
STATE AND FEDERAL REGULATIONS. RCRA U-SERIES: WASTE NUMBER U154
(IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL
ACCORDING TO RCRA.
=================== MSDS Transport Information ===================
Transport Information:US DOT SHIPPING NAME: METHANOL. HAZARD CLASS: 3.
UN NUMBER: UN1230. PACKING GROUP: I I. ICAO SHIPPING NAME:
METHANOL. HAZARD CLASS: 3. UN NUMBER: UN1230. PACKING GROUP: I I.
===================== Regulatory Information =====================
SARA Title III Information:NOT PROVIDED
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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