===================== Product Identification =====================
MSDS NAME:DOP DLC-A
NIIN:00N093453
Status Code:A
MSDS Number: CKYXN
=== Responsible Party ===
Company:NATROCHEM INC
Box:1205
City:SAVANNAH
State:GA
ZIP:31498-4201
Country:US
Info Phone Num:912-236-4464
Emergency Phone Num:912-236-4464
Preparer's Name:JAMES L. PYE, JR.
CAGE:9C469
=== Contractor Identification ===
Company:HARWICK CHEMICAL CORPORATION
Address:60 SOUTH SEIBERLING STREET
Box:9360
City:AKRON
State:OH
ZIP:44305
Country:US
Phone:216-798-9300
CAGE:84769
Company:NATROCHEM INC
Address:EXLEY AVE
Box:1205
City:SAVANNAH
State:GA
ZIP:31498-4201
Country:US
Phone:912-236-4464
CAGE:9C469
============= Composition/Information on Ingredients =============
Name:DI (2-ETHYLHEXYL) PHTHALATE
CAS:117-81-7
RTECS #:TI0350000
Minumum % Wt:70.
Maxumum % Wt:74.
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SILICON DIOXIDE
CAS:7631-86-9
Minumum % Wt:26.
Maxumum % Wt:30.
Other REC Limits:5 MG/M3 (RESP DUST)
OSHA PEL:6 MG/M3 (TOTAL DUST)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRIMARY ROUTE OF ENTRY: INHALATION,
SKIN CONTACT AND EYE CONTACT. EFFECTS OF EXPOSURE: EYES: MILDLY
IRRITATING. EXCESSIVE CONTACT WITH POWDER CAN CAUSE DRYING OF
MUCOUS MEMBRANES OF EYES DUE TO ABSOR PTION OF MOISTURE AND OILS.
SKIN: EXCESSIVE CONTACT MAY PRODUCE AT LEAST MILD IRRITATION, SKIN
SENSITIZATION AND ALLERGIC DERMATITIS. INHALATION: NUISANCE DUST.
EXCESSIVE CONTACT WITH POWDER CAN CAUSE DRYING OF MUCOUS MEMBRANES
OF NOSE AND THROAT DUE TO ABSORPTION OF MOISTURE AND OILS. THIS
MATERIAL CAN ALSO CAUSE NASAL IRRITATION AND NOSEBLEEDS. IF THE
PRODUCT IS HEATED, MISTED OR SPRAYED, (SIGNS AND SYMPTOMS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:DI (2-ETHYLHEXYL) PHTHALATE: NTP 9TH
ANNUAL REPORT ON CARCINOGENS, 2000: REASONABLY ANTICIPATED TO BE A
HUMAN CARCINOGEN. IARC GROUP 2B, IARC MONOGRAPHS VOLUME 29, PAGE
269, 1982.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT):
CONCENTRATION ABOVE THE RECOMMENDED EXPOSURE LIMIT MAY CAUSE
IRRITATION TO THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
INGESTION: MAY CAUSE NAUSEA, VOMIT ING AND DIARRHEA.
MEDICAL CONDITION AGGRAVATED BY EXPOSURE (CONT): RESPIRATORY
PROTECTION. DEHP: INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS
(I.E. ASTHMA, CHRONIC BRONCHITIS, EMPHYSEMA, E TC.) MAY BE
ADVERSELY AFFECTED BY FUME OR AIRBORNE PARTICULATE MATTER EXPOSURE.
Medical Cond Aggravated by Exposure:SILICON DIOXIDE: PERSONS WITH
BREATHING PROBLEMS OR LUNG DISEASE SHOULD NOT WORK IN DUSTY AREAS
UNLESS A PHYSICIAN APPROVES AND CERTIFIES THEIR FITNESS TO WEAR
(SIGNS AND SYMPTOMS OF OVEREXPOSURE)
======================= First Aid Measures =======================
First Aid:EYE CONTACT: IMMEDIATELY RINSE WITH CLEAN WATER FOR AT LEAST
15 MINUTES. RETRACT EYELIDS OFTEN. SEEK MEDICAL ATTENTION. SKIN
CONTACT: IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH SKIN
THOROUGHLY WIT H MILD SOAP AND WATER. FLUSH WITH LUKEWARM WATER FOR
15 MINUTES. SEEK MEDICAL ATTENTION. INHALATION: IF OVERCOME BY
EXPOSURE, REMOVE VICTIM TO FRESH AIR. IF BREATHING IS DIFFICULT OR
HAS STOPPED, ADMI NISTER RESPIRATION (MOUTH-TO-MOUTH) OR OXYGEN AS
INDICATED. CALL A PHYSICIAN. INGESTION: GIVE 1-2 LARGE GLASSES OF
WATER OR MILK. INDUCE VOMITING BY TOUCHING FINGER TO THE BACK OF
THROAT. CALL A PHYS ICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=215.6C, 420.F
Autoignition Temp:Autoignition Temp Text:N/DA
Lower Limits:0.3%
Extinguishing Media:WATER FOG, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:BURNING OF THIS PRODUCT WILL RESULT IN THE
RELEASE OF TOXIC FUMES. FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS (NIOSH APPROVED - ) AND FULL PROTECTIVE
CLOTHING. USE WATER TO KEEP F IRE EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:WATER OF FOAM MAY CAUSE FROTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:MINIMIZE SPILL AREA. VACUUM SPILL MATERIAL AND
PLACE IN CLOSED PLASTIC BAGS FOR DISPOSAL. BIS (2-ETHYLHEXYL)
PHTHALATE IS A CERCLA HAZARDOUS SUBSTANCE, AS AMENDED, AND
REPORTABLE SPILLS MUST BE BE REP ORTED TO THE NATIONAL RESPONSE
CENTER. IN CASE OF RELEASE TO THE ENVIRONMENT, REPORT SPILLS TO
800-424-8802, THE NATIONAL RESPONSE CENTER.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING CAN CREATE EXPLOSIVE DUST
CLOUDS. ELIMINATE IGNITION SOURCES, USE EXPLOSIVE PROOF EQUIPMENT.
CONVEYING AND PROCESSING EQUIPMENT SHOULD BE SPARK-PROOF, WELL
BONDED AND GROUNDED. AVOID DUST ACC UMULATIONS.
Other Precautions:WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING
BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A RESPIRATOR SUCH AS 3M 9900 OR EQUIVALENT
FOR PROTECTION AGAINST PNEUMOCONIOSIS PRODUCING DUSTS.
PERMISSIBLE EXPOSURE LIMITS: SILICON DIOXIDE: 6 MG/M3 (TOTAL DUST),
8 HR. TWA; 29 CFR 1910. 1000 (REV. 3/1/89). PPG INTERNAL
PERMISSIBLE EXPOSURE LIMIT (IPEL); SYNTHETIC PRECIPITATED SILICATE:
5 MG/M3 (REPIRABLE DUST), 8 HR. TWA.
Ventilation:PROVIDE EXPLOSION PROOF VENTILATION AS REQUIRED TO CONTROL
AIRBORNE DUST LEVELS. THE SUM TOTAL OF ALL INGREDIENTS MAY EMIT
VAPORS DURING (WORK HYGENIC PRACTICE)
Protective Gloves:IMPERVIOUS GLOVES TO PROTECT AGAINST CONTACT WITH
PRODUCT.
Eye Protection:CHEMICAL SAFETY GOGGLES (ANSI APPROVED - ).
Other Protective Equipment:PROTECTIVE CLOTHING (NATURAL RUBBER,
NEOPRENE, POLYVINYL CHLORIDE AND NITRILE PROTECTIVE GARMENTS HAVE
BEEN SUGGESTED FOR PROTECTION AGAINST MATERIALS OF THIS CLASS), EYE
WASH STATION, SAFETY SHOWER.
Work Hygienic Practices:N/P. VENTILATION (CONT): NORMAL
PROCESSING. ALL POSSIBLE HEALTH EFFECTS ARE NOT KNOWN AND
INDIVIDUAL SENSITIVITIES WILL VARY. EFFECTIVE EXHAUST VENTILATION
SHOULD (SUPPLEMENTAL SAFETY AND HEALTH)
Supplemental Safety and Health
HMIS RATING: HEALTH = 1, FLAMMABILITY = 1, REACTIVITY = 0. WORK
HYGENIC PRACT (CONT): ALWAYS BE PROVIDED TO DRAW DUST, FUMES AND
VAPORS AWAY FROM WORKERS TO PREVENT ROUTINE INHALATION.VENTILATION
SHOULD BE ADEQUATE TO MAINTAIN AMBIENT WORKPLACE ATMOSPHERE BELOW
THE LIMITS LISTED IN (RESPIRATORY PROTECTION) SECTION.
================== Physical/Chemical Properties ==================
Boiling Pt:=230.C, 446.F
Vapor Pres:NEGLIGIBLE.
Vapor Density:13.5 AIR=1
Spec Gravity:1.13
Evaporation Rate & Reference:NO DATA AVAILABLE
Solubility in Water:< 0.2%
Appearance and Odor:OFF-WHITE, FREE FLOWING POWDER WITH MILD ODOR.
Percent Volatiles by Volume:NEGLIGIBLE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID ALTERATION OF PRODUCT PROPERTIES BEFORE REUSE. CALCINING, WHICH
MAY RESULT IN CRYSTALLINE FORMATION OR MIXING WITH ADDITIVES MAY
ALTER TOXICOLOGICAL PROPERTIES. NITRATES, STRONG OXIDIZERS, STRONG
ACIDS AND STRONG ALKA
Stability Condition to Avoid:AVOID HIGH TEMPERATURES (> 800 C)
TREATMENT.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN, ORGANIC
ACIDS.
=================== Toxicological Information ===================
Toxicological Information:HEALTH EFFECTS: SILICON DIOXIDE: AN
EPIDEMIOLOGICAL STUDY WAS CONDUCTED WHICH INCLUDED 165 PRECIPITATED
SILICA WORKERS WHO HAD BEEN EXPOSED FOR AN AVERAGE OF 18 YEARS. NO
ADVERSE EFFECTS WERE NOTED IN COMPLETE MEDICAL EXAMINATION
(INCLUDING CHEST ROENTGENOGRAMS) OF THESE WORKERS. PULMONARY
FUNCTION DECREMENTS WERE CORRELATED ONLY WITH SMOKING AND AGE BUT
NOT WITH THE DEGREE OR DURATION OF DUST EXP OSURE. LABORATORY
STUDIES HAVE ALSO BEEN CONDUCTED IN SMALL ANIMALS VIA INHALATION TO
LEVELS OF PRECIPITATED SILICA DUST OF UP TO 126 MG/M3 FOR PERIODS
FROM SIX MONTHS TO TWO YEARS. ALTHOUGH PRECIPITA TED SILICA WAS
(ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:N/P. TOXICOLOGICAL INFO (CONT): TEMPORARILY DEPOSITED
IN THE ANIMALS' LUNGS, MOST OF THE DEPOSITED MATERIAL WAS CLEARED
SOON AFTER THE DUST EXPOSURE ENDED. THE RESULTS OF ALL STUDIES
PERFORMED BY, OR KNOWN TO, PPG INDICATE A VERY LOW ORDER OF
PULMONARY ACTIVITY FOR SYNTHETIC PRECIPITATED SILICA. DEHP: THE
MAJOR TARGET ORGANS SHOWING DEHP RELATED TOXICITY IN ANIMALS ARE
THE LIVER AND TESTES . DEHP CAUSES LIVER ENLARGEMENT AND PEROXISOME
PROLIFERATION IN RODENTS. VERY HIGH DIETARY LEVELS OF DEHP PRODUCED
LIVER CANCER IN MICE AND RATS OF BOTH SEXES (NTP 4TH ANNUAL REPORT
SUMMARY, PG 83, 19 85). DEHP ALSO CAUSES (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED. ECOLOGICAL INFO (CONT)
TESTICULAR DAMAGE AND REDUCE FERTILITY IN MALES AND FETOTOXICITY
AND TERATOGENNICITY IN PREGNAT FEMALE RODENTS (ENVIRON. HEALTH
PERSP. 1982, 45% TOX. APP L. PHARCOL. 1980, 53:35-41). THE TOXICITY
OF DEHP HAS BEEN QUESTIONED, ESPECIALLY SINCE THE NATIONAL CANCER
INSTITUTE (NCI) REPORTED IN 1980 THAT VERY HIGH LEVELS OF THE
PLASTICIZER CAUSED LIVER TUMO RS IN MICE AND RATS OF BOTH SEXES IN
A LIFETIME FEEDING STUDY. EXTENSIVE TOXICOLOGICAL STUDIES ON DEHP
HAVE BEEN REVIEWED AND REPORTED TO THE CONSUMER SAFETY COMMISSION
(CPSC) BY THE CHRONIC HAZARD A DVISORY PANEL (FEDERAL REGULATORY)
===================== Regulatory Information =====================
SARA Title III Information:THRESHOLD PLANNING QUANTITY (TPQ), EPA
REGULATION 40 CFR 355 (SARA SECTIONS 301-313) :DEHP. HAZARDOUS
CHEMICAL REPORTING EPA REGULATION 40 CFR 355 (SARA SECTIONS
311-312): SILICON DIOXIDE - ACUTE H AZARD, DI (2-THEYLHEXYL)
PHTHALATE - CHRONIC HAZARD. THIS PRODUCT CONTAINS THE FOLLOWING
TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SEC 313 OF
THE EMERGENCY PLANNING AND COMMUNITY RIGH T-TO-KNOW ACT OF 1986 (40
CFRF 372): DI (2-ETHYLHEXYL) PHTHALATE, CAS REGISTRY # 117-81-7,
70-74% BY WEIGHT. THIS INFORMATION MUST BE INCLUDED IN ALL MSDS'S
THAT ARE COPIED AND DISTRIBUTED FOR THIS M ATERIAL.
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE
INCLUDED ON THE TSCA TOXIC CHEMICAL SUBSTANCE INVENTORY.
REPORTABLE QUANTITY (RQ), EPA REGULATION 40 CFR 302 (CERCLA SECTION
102): DEHP. THE COMPONENT(S) LISTED BELOW IS IDENTIFIED AS A
HAZARDOUS CHEMICAL UNDER THE CRITERIA OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200): SILICON DIOXIDE, CAS
REGISTRY: 7631-86-9, PERCENT: 26 - 30; DI (2-ETHYLHEXY L) PHTALATE,
CAS REFISTRY: 117-81-7, PERCENT: 70 - 74. TRANSPORT INFO
(CONT): (CHAP) ON DEHP ( 1985). DEHP AND ITS METABOLITES ARE NOT
GENOTOXIC. THE MAJORITY OF CHEMICALS THAT CAUSE TUMORS DO SO BY
DAMAGING GENETIC (STATE REGULATORY)
State Regulatory Information:N/P. FEDERAL REGULATORY (CONT):
MATERIAL. DEHP APPEARS TO BELONG TO A SPECIAL CLASS OF
NON-GENOTOXIC CARCINOGENS THAT SHARE THE PROPERTIES OF INDUCING
LIVER ENLARGEMENT AND LIVER PEROXISOMAL PRO LIFERATION IN MICE AND
RATS. THESE LIVER CHANGES MAY BE UNIQUE TO THESE RODENTS AND MAY
NOT OCCUR IN OTHER ANIMAL SPECIES, INCLUDING MAN. A PLAUSIBLE
MECHANISM OF ACTION FOR THIS TYPE OF CARCINOGENESI S APPEARS TO
INVOLVE THE INDUCTION OF LIVER PEROXISOMES. THIS HYPOTHESIS IMPLIES
A POSSIBLE THRESHOL D FOR DEHP CARCINOGENICITY. DEHP METABOLISM
STUDIES HAVE DEMONSTRATED SIGNIFICANT QUANTITATIVE DIFFERENCES
BETWEEN RATS (OTHER INFORMATION)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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