===================== Product Identification =====================
MSDS NAME:HYDROGEN PEROXIDE SOLUTION 50% H2O2
NIIN:01-353-4876
Status Code:A
MSDS Number: CLBLJ
=== Responsible Party ===
Company:HACH COMPANY
Address:5600 LINDBERGH DR
Box:389
City:LOVELAND
State:CO
ZIP:80539
Country:US
Info Phone Num:970-669-3050
Emergency Phone Num:303-623-5716/515-232-2533
Resp. Party Other MSDS Num.:M00478
CAGE:91224
=== Contractor Identification ===
Company:ADI SERVICES
Address:ROUTE 3 BOX 94L
Box:UNKNOW
City:MARTINSBURG
State:WV
ZIP:25401-9533
Country:US
Phone:304-263-7722
Contract Num:SP0450-01-M-D889
CAGE:0GD25
Company:HACH CO
Address:5600 LINDBERGH DR
Box:389
City:LOVELAND
State:CO
ZIP:80539
Country:US
Phone:970-669-3050/ 303-623-5716
CAGE:91224
Company:HACH COMPANY
Address:100 DAYTON RD.
Box:907
City:AMES
State:IA
ZIP:50010
Country:US
Phone:800-227-4224
CAGE:4T252
============= Composition/Information on Ingredients =============
Name:HYDROGEN PEROXIDE
CAS:7722-84-1
RTECS #:MX0900000
Minumum % Wt:45.
Maxumum % Wt:55.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 PPM
ACGIH TLV:1 PPM
Name:OTHER COMPONENTS (TYPE NOT SPECIFIED)
< Wt:.1
Other REC Limits:NONE RECOMMENDED
Name:DEMINERALIZED WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:45.
Maxumum % Wt:55.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: NONE REPORTED. EYE
CONTACT: CAUSES EYE BURNS. SKIN CONTACT: CAUSES BURNS. SKIN
ABSORPTION: NONE REPORTED. INGESTION: MAY CAUSE: BURNS OF THE MOUTH
AND ESOPHAGUS, ABDOMINAL PAIN. HYDAROG EN PERXIDE DECOMPOSES IN THE
BOWEL BEFORE ABSORPTION YIELDING LARGE VOLUMES OF OXYGEN WHICH MAY
CAUSE THE BOERL TO RUPTURE. INHALATION: CAUSES SEVERE IRRITATION OF
RESPIRATORY TRACT. CHRONIC EFFECTS: NONE REPORTED.
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY OSHA
LISTED CARCINOGENS. IARC GROUP 3: NON-CLASSIFIABLE. THIS PRODUCT
DOES NOT CONTAIN ANY NTP LISTED CHEMICALS. ADDITIONAL
CANCER/REPRODUCTIVE TOXICITY INFORMATION: CONTAINS: AN
EXPERIMENTAL MUTAGEN.
Effects of Overexposure:CAUSES BURNS; DECOMPOSES IN THE BOWEL BEFORE
ABSORPTION YIELDING LARGE VOLUME OF OXYGEN WHICH MAY CAUSE BOWEL TO
RUPTURE.
Medical Cond Aggravated by Exposure:PRE-EXISTING: EYE CONDITIONS. SKIN
CONDITIONS. RESPIRATORY CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15
MINUTES. CALL PHYSICIAN. SKIN CONTACT: WASH SKIN WITH PLENTY OF
WATER FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING. CALL PHYSICIAN
IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING. GIVE 1-2 GLASSES
OF WATER. CALL PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE
ARTIFICAL RESPIRA TION IF NECESSARY. CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE MEDIA APPROPIRATE TO SURROUNDING FIRE
CONDITIONS.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING
APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR. CONTAINERS CAN
BUILD UP PRESSURE IF EXPOSED TO HEAT.
Unusual Fire/Explosion Hazard:MAY REACT VIOLENTLY WITH: COMBUSTIBLE
MATERIALS, REDUCERS, ALCOHOLS. MECHANICAL IMPACT: MIXTURES OF
HDROGEN PEROXIDE AND ORGAINC MATERIAL ARE DETONATABLE UPON FIRE OR
IMPACT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL COMBUSTIBLE MATERIAL FROM SPILL
AREA. ABSORB SPILLED LIQUID WITH NON-REACTIVE SORBENT MATERIAL.
STOP SPILLED MATERIAL FROM BEING RELEASED TO THE ENVIRONMENT. DIKE
LARGE SPILLS TO KEEP SPILL ED MATERIAL FROM ENTERING SEWAGE AND
DRAINAGE SYSTEMS OR BODIES OF WATER. "SEE OTHER INFO"
Neutralizing Agent:SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: AVOID CONTACT WITH EYES,
SKIN, CLOTHING. DO NOT BREATHE VAPORS. WASH THOROUGHLY AFTER
HANDLING. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING
THIS PRODUCT. STORAGE: KEEP AWAY FROM OXIDIZABLE MATERIUALS,
COMBUSTIBLE MATERIALS. STORE AWAY FROM AKLALIES, METALS, REDUCERS.
Other Precautions:STORAGE: AVOID CONTAMINATION BY ORGANIC MATERIALS.
PROTECT FROM EXPOSURE TO DIRECT SUNLIGHT. EMPTY CONTAINERS: RINSE
THREE TIMES WITH AN APPROPRIATE SOLVENT. DISPOSE OF EMPTY
CONTAINER AS NORMAL TRA SH.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A FUME HOOD TO AVOID EXPOSURE TO DUST, MIST
OR VAPOR.
Ventilation:USE A FUME HOOD TO AVOID EXPOSURE TO DUST, MIST OR VAPOR.
LABORATORY FUME HOOLD.
Protective Gloves:DISPOSABLE LATEX GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:HAVE AN EYEWASH STATION NEARBY. HAVE A
SAFETY SHOWER NEARBY. DISPOSABLE LAB COAT.
Work Hygienic Practices:MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES
WHEN USING THIS PRODUCT
Supplemental Safety and Health
AVOID CONTACT WITH EYS, SKIN, CLOTHING. DO NOT BREATHE MIST/VAPOR. WASH
THOROUGHLY AFTER HANDLING. KEEP AWAY FROM COMBUSTIBLE MATERIAL,
ALKALIES, OXIDIZING MATERIALS. *INTENDED USE: LABORATORY REAGENT .
================== Physical/Chemical Properties ==================
HCC:D3
Boiling Pt:=113.9C, 237.F
Melt/Freeze Pt:M.P/F.P Text:ND
Vapor Pres:18.3
Spec Gravity:1.196
pH:1-3
Evaporation Rate & Reference:<1(WATER=1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS, LIQUID; SHARP ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY REACT VIOLENTLY IN CONTACT WITH: ALKALIES, REDUCERS, COMBUSTIBLE
MATERIALS AND FLAMMABLE LIQUIDS.
Stability Condition to Avoid:EVAPORATION. EXPOSURE TO DIRECT SUNLIGHT,
HEAT.
Hazardous Decomposition Products:DECOMPOSITION FORMS OXGEN THAT WILL
SUPPORT COMBUSTION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:TLV: 1 PPM. PEL: 1 PPM. PRODUCT TOXICOLOGICAL
DATA: LD50: NONE REPORTED. LC50: NONE REPORTED. DERMAL TOXICITY
DATA: ALBINO RAT DERMAL LD50=4060 MG/KG (905 H2O2). SKIN AND EYE
IRRITATION DATA: NONE REP ORTED. MUTATION DATA: CYTOGENIC
ANALYSIS-HUMAN EMBRYO-20 UMOL/L., DNA DAMAGE-RAT LYMPHOCYTES - 50
UMOL/L. REPRODUCTIVE EFFECTS DATAL NONE REPORTED. INGREDIENT
TOXICOLOGICAL DATA: HYDROGEN PEROXIDE 90% : ALBINO AT LC50=2 G/M3
(4 HOURS EXPOSURE): HYDROGEN PEROXIDE 90%: ORAL MOUSE LD50=2 G/KG.
TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NONE REPORTED.
===================== Ecological Information =====================
Ecological:PRODUCT ECOLOGICAL INFORMATION: CHANNEL ATFISH; 96 HOURS
LC50=37.4 MG/L. FATHEAD MINNOW; 96 HOURS LC50=16.4 MG/L. DAPHINE
MAGNA; 24 HOURS EC50=7.7 MG/L. INGREDIENT ECOLOGICAL INFORMATION:
NOT APPLICAB LE. *NOTICE (DISPOSAL): THESE DISPOSAL GUIDELINES ARE
BASED ON FEDERAL REGULATIONS AND BY BE SUPERSEDED BY MORE STRINGENT
STATE OR LOCAL ENVIRONMENTAL REGULATIONS FOR MORE INFORMATION.
==================== Disposal Considerations ====================
Waste Disposal Methods:WORK IN AN APPROVED FUME HOOD. DILUTE MATERIAL
WITH EXCESS WATER MAKING A WEAKER THAN 5% SOLUTION. ADD GRADUALLY,
WITH STIRRING A 1.5.1 AMOUNT OF AQUEOUS SODIUM METABISULFITE. WHEN
THE REACTION IS COM PLETE, CHECK AND ADJUST THE PH AS NECESSARY.
OPEN COLD WATER TAP COMPLETELY, SLOWLY POUR THE REACTED MATERIAL
TO THE DRAIN. "SEE ECOLOGICAL INFO"
=================== MSDS Transport Information ===================
Transport Information:D.O.T.: D.O.T. PROPER SHIPPING NAME: HYDROGEN
PEROXIDE, AQUEOUS SOLUTION (50% PEROXIDE). DOT HAZARD CLASS: 5.2.
DOT SUBSIDIARY RISK: 8. DOT ID NUMBER: UN2014. DOT PACKING GROUP:
II. I.C.A.O.: I.C.A.O. PROPER SHIPPING NAME: HYDROGEN PEROXIDE,
AQUEOUS SOLUTION. ICAO HAZARD CLASS: 5.1. ICAO SUBSIDIARY RISK: 8.
ICAO ID NUMBER: UN2014. ICAO PACKING GROUP: II. I.M.O.: I.M.O.
PROPER SHIPPING NAME: HYDROG EN PEROXIDE, AQUEOUS SOLUTION (50%
PEROXIDE). I.M.O. HAZARD CLASS: 5.1. I.M.O. SUBSIDIARY RISK: 8.
I.M.O. ID NUMBER: UN2014. I.M.O. PACKING GROUP: II. D.O.T.
EMERGENCY RESPONSE GUIDE NUMBER: 140.
===================== Regulatory Information =====================
SARA Title III Information:E.P.A.: S.A..A. TITLE III SECTION 311/312
CATEGORIZATION (40 CFR 370): IMMEDIATE (ACUTE) HEALTH HAZARD, FIRE
HAZARD. S.A.R.A. TITLE III SECTION 313 (40 CFR 372): THIS PRODUCT
DOES NOT CONTAIN ANY CHEM ICAL SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA.
Federal Regulatory Information:NEPA WASTE ID NUMBER: D001. O.S.H.A.:
THIS PRODUCT MEETS THE CRITERIA FOR A HAZARDOUS SUBSTANCE AS
DEFINED IN THE HAZARD COMMUNICATION STANDARD. (29 CFR 1910.1200).
301 (EHS) TPQ (40 CFR 355): NOT AP PLICABLE. 304 CERCLA RQ (40 CFR
302.4): NOT APPLICABLE. 304 EHS RQ (40 CFR 355): NOT APPLICABLE.
CLEAN WATER ACT (40 CFR 116.4): NOT APPLICABLE. RCRA: CONTAINS
REGULATED SUBSTANCES. C.P.S.C.: NOT APPL ICABLE. SPECIAL
INSTRUCTIONS (FOR ACCIDENTAL RELEASE): MIXTURE CONTAINS A COMPONENT
WHICH IS REGULAT ED AS HAZARDOUS WASTE. 304 EHS RQ (40 CFR 355):
NOT APPLICABLE. U.S. INVENTORY STATUS: TSCA LISTED: YES. TSCA CAS
#:7722-84-1.
State Regulatory Information:CALIFORNIA PROP. 65: NO PROP 65 LISTED
CHEMICALS ARE PRESENT IN THIS PRODUCT. IDENTIFICATION OF PROP. 65
INGREDIENT(S): NONE. TRADE SECRET REGISTRY: NOT APPLICABLE.
======================= Other Information =======================
======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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