===================== Product Identification =====================
MSDS NAME:NCI 591481
NIIN:00-515-2235
Status Code:A
MSDS Number: CLCGM
=== Responsible Party ===
Company:BASF CORPORATION
Address:3000 CONTINENTAL DRIVE NORTH
City:MOUNT OLIVE
State:NJ
ZIP:07828
Country:US
Info Phone Num:973-426-4671
Emergency Phone Num:(800) 832-HELP (BASF HOTLINE)
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO384
=== Contractor Identification ===
Company:BASF CORPORATION
Address:3000 CONTINENTAL DRIVE NORTH
Box:City:MOUNT OLIVE
State:NJ
ZIP:07828
Country:US
Phone:973-426-4671
CAGE:TO384
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP0450-01-M-D962
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:CYCLOHEXYLAMINE
CAS:108-91-8
RTECS #:GX0700000
= Wt:99.5
ACGIH TLV:41 MG/M3;10 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:RAT, ORAL LD50- 300 MG/KG (VERY TOXIC)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE- MATERIAL IS CORROSIVE TO BODY
TISSUES. SKIN: MAY RESULT IN DERMATITIS & DEEP BURNS. CAN BE
ABSORBED IN TOXIC AMOUNTS. EYES: MAY RESULT IN BURNS & PERMANENT
INJURY. INHALATION: MAY RESULT IN I RRITATION. INGESTION: VERY
TOXIC BY INGESTION. CHRONIC: HAS PRODUCED EMBRYOTOXICITY, LOW
BIRTH COUNT, POSTNATAL MORTALITY, & DECREASED BODY WEIGHT IN
LABORATORY ANIMALS AT HIGH DOES. NOT CARCINOGENI C OR TERATOGENIC.
NO EFFECTS SEEN IN HUMANS. SHOWS TESTICULAR ATROPHY IN RATS BUT NOT
IN MICE.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:INHALATION: LIGHT-HEADEDNESS, DROWSINESS,
ANXIETY, NAUSEA, & VOMITING.
Medical Cond Aggravated by Exposure:NO DATA IS AVAILABLE WHICH
ADDRESSES MEDICAL CONDITIONS THAT ARE GENERALLY RECOGNIZED AS BEING
AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:SKIN: WASH AFFECTED AREAS WITH WATER WHILE REMOVING
CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. EYE: IMMEDIATELY RINSE EYES
WITH RUNNING WATER F OR 15 MINUTES. GET IMMEDIATE MEDICAL
ATTENTION. INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. DILUTE
WITH WATER OR MILK AND GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE
FLUIDS OR INDUCE VOMITING IF THE VICTIM IS UNCONSCIOUS OR HAVING
CONVULSIONS. INHALATION: MOVE TO FRESH AIR. AID IN BREATHING, IF
NECESSARY, AND GET IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:=27.C, 80.6F
Autoignition Temp:=265.C, 509.F
Lower Limits:1.6%
Upper Limits:9.4%
Extinguishing Media:USE ALCOHOL FOAM, CO2 OR DRY CHEMICAL EXTINGUISHING
MEDIA.
Fire Fighting Procedures:FIREFIGHTERS SHOULD BE EQUIPPED WITH
SELF-CONTAINED BREATHING APPARATUS AND TURN OUT GEAR.
Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPOSED TO HEAT OR FLAMES.
CAN REACT WITH OXIDIZING MATERIALS. EMITS TOXIC GASES WHEN HEATED
TO DECOMPOSITION.
================== Accidental Release Measures ==================
Spill Release Procedures:SPILLS SHOULD BE CONTAINED, SOLIDIFIED AND
PLACED IN SUITABLE CONTAINERS FOR DISPOSAL IN A RCRA LICENSED
FACILITY. THIS MATERIAL IS RCRA HAZARDOUS DUE TO ITS PROPERTIES.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE MATERIALS TO AVOID SOURCES OF
IGNITION AND EXCESSIVE HEAT.
Other Precautions:CONTAINER DISPOSAL: EMPTY CONTAINERS WITH LESS THAN 1
INCH OF RESIDUE MAY BE LANDFILLED AT A LICENSED FACILITY. RECOMMEND
CRUSHING OR OTHER MEANS TO PREVENT UNAUTHORIZED REUSE. OTHER
CONTAINERS MUST B E DISPOSED OF IN A RCRA LICENSED FACILITY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VAPORS OR MISTS ARE GENERATED, WEAR A
NIOSH/MSHA APPROVED ORGANIC VAPOR/MIST RESPIRATOR OR AN
AIR-SUPPLIED RESPIRATOR AS APPROPRIATE.
Ventilation:USE LOCAL EXHAUST TO CONTROL VAPORS/MISTS.
Protective Gloves:WEAR GLOVES AS A NECESSARY TO PREVENT CONTACT.
Eye Protection:CHEMICAL GOGGLES; ALSO WEAR A FACE SHIELD IF SPLASHING
HAZARD EXISTS.
Other Protective Equipment:COVERALLS, APRON, AND BOOTS AS NECESSARY TO
PREVENT CONTACT. EYEWASH FOUNTAINS AND SAFETY SHOWERS MUST BE
EASILY ACCESSIBLE.
Work Hygienic Practices:SHOWER AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:=133.C, 271.4F
B.P. Text:@ 760 MMHG
Melt/Freeze Pt:=-18.C, -.4F
M.P/F.P Text:@ 760 MMHG
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:14 MILLIBARS @ 20C
Vapor Density:3.42
Spec Gravity:0.867
pH:11.5
Viscosity:2.12 MPAS
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS TO YELLOW LIQUID; STRONG AMINE ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS. CORROSIVE. NOT AN OXIDIZER.
Stability Condition to Avoid:MINERAL ACIDS.
Hazardous Decomposition Products:CO, CO2, AND NOX.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:RABBIT, DERMAL LD50- 280 MG/KG, MODERATELY
TOXIC. RABBIT, PRIMARY SKIN IRRITATION, CORROSIVE. RAT INHALATION
RISK TEST; SAT. VAPOR/20C - NO DEATHS @ 10 MIN; 70% AQ. SOLN; AT
20C SENSITIZING POTENTIA L- NOT A SENSITIZER. AMES SALMONELLA
ASSAY- NOT MUTAGENIC. RABBIT, EYE IRRITATION- CORROSIVE.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL TOXICITY TEST DATA: ELIMINATION, (OECD 301D) -
>90 PERCENT. TEST RATING NOT FOUND. MOD. OECD CONFIRMATORY TEST,
ELIMINATION ->60 PERCENT. EASY TO ELIMINATE. GOLDEN ORFE, STATIC 96
HR LC5 0 - 58- 195 MG/L. PRACTICALLY NONTOXIC. DAPHNIA MAGNA, 24 HR
LC50 - 49- 80 MG/L. SLIGHTLY TOXIC. ALGAL, 96 HR - 20 MG/L.
SLIGHTLY TOXIC. TOXICITY TO BACTERIA - 54 MG/L. TEST RATING NOT
FOUND. BIOLOGIC AL OXYGEN DEMAND, 5 DAY - 1880 MG 0.2/G. TEST
RATING NOT FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR BURY IN A RCRA LICENSED FACILITY.
DO NOT DISCHARGE INTO WATERWAYS OR SEWER SYSTEMS WITHOUT PROPER
AUTHORITY.
=================== MSDS Transport Information ===================
Transport Information:CYCLOHEXYLAMINE, 8, (3), UN2357, PGII.
===================== Regulatory Information =====================
Federal Regulatory Information:TSCA INVENTORY STATUS- LISTED ON
INVENTORY: YES. RCRA HAZ. WASTE NO.:D001. CERCLA: YES, REPORTABLE
QTY.: 10000 LBS. THE RCRA HAZARDOUS WASTE NUMBER D001 REFERS TO
THIS MATERIAL'S RCRA HAZARDOUS WAS TE CHARACTERISTIC OF
IGNITIBILITY. PRODUCT ALSO HAS RCRA HAZARDOUS WASTE NO OF D003.
State Regulatory Information:CYCLOHEXYLAMINE (CAS # 108-91-8) ON THE
NJ, PA, & MA RIGHT TO KNOWN.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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