===================== Product Identification =====================
MSDS NAME:ETHEX, 1796
Status Code:A
MSDS Number: CLCGQ
=== Responsible Party ===
Company:MADISON BIONICS DIV. OF SYSTEMS GENERAL
Box:152170
City:IRVING
State:TX
ZIP:75015
Country:US
Info Phone Num:972-438-1381
Emergency Phone Num:972-438-1381
Preparer's Name:G. MARSHALL
CAGE:TO697
=== Contractor Identification ===
Company:MADISON BIONICS DIV. OF SYSTEMS GENERAL
Box:152170
City:IRVING
State:TX
ZIP:75015
Country:US
Phone:972-438-1381
CAGE:TO697
============= Composition/Information on Ingredients =============
Name:1,1,1-TRICHLOROETHANE.
CAS:71-55-6
RTECS #:KJ2975000
OSHA PEL:350 PPM
OSHA STEL:450 PPM TWA
ACGIH TLV:350 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Name:DIMETHOXYMETHANE.
CAS:109-87-5
RTECS #:PA8750000
OSHA PEL:1000 PPM
OSHA STEL:NOT EST. TWA
ACGIH TLV:1000 PPM
Name:TERT-BUTYL ALCOHOL.
CAS:75-65-0
RTECS #:EO1925000
OSHA PEL:150 PPM
OSHA STEL:NOT EST. TWA
ACGIH TLV:100 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/P.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LABORATORY
ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS. THE USE OF
EPINEPHRINE MAY BE CONTRA-INDICATED EXCE PT FOR LIFE SUSTAINING
USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
ACUTE (SHORT TERM EXPOSURE): EYES: LIQUID AND VAPORS MAY CAUSE
IRRITATION WITH REDNESS, TEARING AND SLIGH T TEMPORARY CORNEAL
INJURY. SKIN CONTACT: MAY CAUSE IRRITATION SEEN AS ITCHING AND
REDNESS. PROLONGED OR REPEATED CONTACT MAY LEAD TO DERMATITIS.
PRODUCT MAY BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNT S WITH
EFFECTS (EFTS OF OVEREXPOS)
Effects of Overexposure:HEALTH HAZARDS (CONT'D): SIMILAR TO INHALATION.
INHALATION: AT LOW LEVELS MAY CAUSE HEADACHE, DIZZINESS, NAUSEA,
DROWSINESS, AND THROAT IRRITATION. HIGHER LEVELS OF CONCENTRATION
MAY CAUSE BLOOD PRESS URE DEPRESSION, CARDIAC SENSITIZATION,
VENTRICULAR ARYTHMIA, UNCONSCIOUSNESS AND POSSIBLY DEATH.
INGESTION: MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS
WEAKNESS, DIZZINESS, STAGGERING GAIT, HEADA CHE, NAUSEA, BLURRED
VISION & EXCITATION. MAY BE ABSORBED THROUGH THE GASTROINTESTINAL
TRACT. INGESTION AND SUBSEQUENT VOMITING OFTHIS PRODUCT CAN LEAD TO
ASPIRATION OF THE PRODUCT INTO THE LUNGS WHIC H CAN CAUSE DAMAGE
AND (DISPOSAL METHOD)
Medical Cond Aggravated by Exposure:PRE-EXISTING LIVER AND HEART
DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM AREA TO FRESH AIR. IF NOT BREATHING,
CLEAR THE AIRWAY AND START MOUTH TO MOUTH ARTIFICIAL RESPIRATION.
GET IMMEDIATE MEDICAL ATTENTION. EYE CONTACT: RINSE THE EYES WITH
WATER. REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING WITH PLENTY
OF WATER FOR SEVERAL MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION
DEVELOPS. SKIN CONTACT: WASH AFFECTED AREAS WITH PLENTY OF OF SOAP
AND WA TER FOR SEVERAL MINUTES. REMOVE AND CLEAN CONTAMINATED
CLOTHING AND SHOES. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INGESTION: GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE
VOMITING. IF VOMITI NG OCCURS, GIVE FLUIDS (SUPP SFTY)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:NON FLAM.
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT . COOL FIRE EXPOSED CONTAINERS WITH
WATER SPRAY TO PREVENT BURSTING.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
COLLECT IN LOW AREAS. DO NOT SPRAY A DIRECT STREAM OF WATER INTO
PRODUCT AS FROTHING AND SPATTERING MAY OCCUR. THERMAL
DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND P HOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE AND CONTAIN SPILL IF SAFE TO DO SO.
ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL MATERIAL INTO A
PROPERLY LABELED CONTAINER FOR DISPOSAL. WEAR APPROPRIATE
PROTECTIVE CLOTHING. PREVENT PRODUCT F ROM CONTAMINATING SOIL OR
FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS AND BODIES OF WATER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE TEMPERATURE INDOOR: MAX: 120F,
MIN: 30F. KEEP AWAY FROM IGNITION SOURCES. IF STORED OUTDOORS STORE
ON ITS SIDE TO PREVENT CONDENSATION AND SUBSEQUENT CONTAMINATION OF
PRODUCT. KEEP CONTAINER T IGHTLY CLOSED.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL AND PHOSGENE . KEEP OUT OF
REACH OF CHI LDREN. READ ENTIRE LABEL BEFORE USING PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:TYPICAL USE OF THIS PRODUCT DOES NOT REQUIRE THE
USE OF A RESPIRATOR. A NIOSH APPROVED RESPIRATOR IN POORLY
VENTILATED AREAS AND/OR FOR EXPOSURE ABOVE ACGIH TLV OR OSHA PEL OR
WHERE MISTING EXISTS.
Ventilation:LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM
OPERATIONS THAT CAN GENERATE MISTS OR VAPORS.
Protective Gloves:POLYVINYL ALCOHOL GLOVES IF REPEATED OR PROLONGED
SKIN CONTACT IS LIKELY.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES . SAFETY GLASSES
(WORK HYGIENE)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR A NEOPRENE OR POLYVINYL ALCOHOL APRON AND
BOOTS TO MINIMIZE CONTACT.
Work Hygienic Practices:N/P. EYE PROTECTION (CONT'D): WITH SIDE SHIELDS
IF THE METHOD OF USE PRESENTS THE LIKELIHOOD OF EYE CONTACT.
Supplemental Safety and Health
FIRST AID (CONT'D): AGAIN. GET IMMEDIATE MEDICAL ATTENTION IF
DISCOMFORT OCCURS. NOTES TO PHYSICIAN: INGESTION AND SUBSEQUENT
VOMITING OF THIS PRODUCT CAN LEAD TO ASPIRATION OF THE PRODUCT INTO
THE LU NGS WHICH CAN CAUSE DAMAGE AND MAY BE FATAL. DO NOT
ADMINISTER ADRENALIN.
================== Physical/Chemical Properties ==================
Boiling Pt:=73.9C, 165.F
Vapor Pres:(MM HG) 100.
Vapor Density:4.8.
Spec Gravity:(H2O=1) 1.338.
Viscosity:NON-VISCOUS.
Evaporation Rate & Reference:(BU A/C=1) 4.
Solubility in Water:INSOLUBLE.
Appearance and Odor:COLORLESS, TRANSPARENT LIQUID. CHLORINATED SOLVENT
ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALAIS, ACIDS, AMINES. AVOID CONTACT WITH ALUMINUM AND WATER EXPOSED
TO EXTREME HEAT AND PRESSURE.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:OXIDES OF CARBON, HYDROGEN CHLORIDE
AND PHOSGENE.
=================== Toxicological Information ===================
Toxicological Information:THRESHOLD LIMIT VALUE: NOT ESTABLISHED FOR
MIXTURE. REFER TO INGREDIENTS SECTION. 1,1,1 TRICHLOROETHANE:
ORL-RAT LD50: 10,300 MG/KG 3, SKN-RBT: 500 MG/24H MOD 3, EYE-RBT: 2
MG/24H SEV 3, IHL-RAT LC50: 14,250 PPM/7H 4. DIMETHOXYMETHANE:
IHL-RAT LC50: 15,000 PPM 3, ORL-RBT LD50: 5708 MG/KG 3. TERT-BUTYL
ALCOHOL: ORL-RAT LD50: 3500 MG/KG 3, ORL-RBT LD50: 3559 MG/KG 3.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL,
STATE, AND LOCAL REGULATIONS. (HEALTH HAZ/EXPOS CONT) MAY BE
FATAL. CHRONIC (LONG TERM EXPOSURE): PROLONGED EXPOSURE MAY LEAD TO
LIVER DISEASE AND RHYTHM D ISORDERS OF THE HEART. TARGET ORGANS:
CENTRAL NERVOUS SYSTEM, LIVER AND HEART.
=================== MSDS Transport Information ===================
Transport Information:SHORT-TERM EXPOSURE LIMIT (TWA) LISTED AS FINAL
RULE LIMITS PUBLISHED IN THE FEDERAL REGISTER/VOL. 54 NO. 12,
1-19-89.
===================== Regulatory Information =====================
SARA Title III Information:INGREDIENTS SUBJECT TO THE REPORTING
REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: 1,1,1-
TRICHLOROETHANE CAS 71-55-6,UPPER % LIMIT 95; TERT-BUTYL ALCOHOL
CAS 75-65-0, UPPER % LIMIT 5. INGREDIENTS WITH END USERS EXEMPT
FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR
ROUTINE JANITORAL WORK, OR THE PRODUCT IS USED AND LABELED FOR
FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES),
OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES:
NONE.
Federal Regulatory Information:N/P.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE (1) CANCER OR (2) BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM: ETHYLENE DICHL ORIDE (1) AS A TRACE CONTAMINANT.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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