===================== Product Identification =====================
MSDS NAME:ALP2422, CYCLOHEXYLAMINE
NIIN:00-805-9798
Status Code:A
MSDS Number: CLNRC
=== Responsible Party ===
Company:BUCKLEY OIL COMPANY
Address:1809 ROCK ISLAND STREET
City:DALLAS
State:TX
ZIP:75207
Country:US
Info Phone Num:214-421-4147
Emergency Phone Num:214-421-4147
Preparer's Name:NOT PROVIDED
Chemtrec Ind/Phone:(800)424-9300
CAGE:UO722
=== Contractor Identification ===
Company:ALLIANCE CHEMICAL INC
Address:3 OAKMOOR
Box:79
City:ROUND ROCK
State:TX
ZIP:78680
Country:US
Phone:512-365-6838
Contract Num:SP0450-02-M-M050
CAGE:1LT50
Company:BUCKLEY OIL COMPANY
Address:1809 ROCK ISLAND STREET
Box:City:DALLAS
State:TX
ZIP:75207
Country:US
Phone:214-421-4147
CAGE:UO722
============= Composition/Information on Ingredients =============
Name:CYCLOHEXYLAMINE
CAS:108-91-8
RTECS #:GX0700000
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT LISTED
ACGIH TLV:41 MG/M3;10 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 156 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES BURNS, CHEMICAL
CONJUNCTIVITIS, CORNEAL DAMAGE. SKIN: HARMFUL IF ABSORBED THROUGH
SKIN. CAUSES BURNS, CYANOSIS, SKIN RASH AND COLD AND CLAMMY SKIN
WITH CYANOSIS OR PALE COLOR. INGESTION: HARMFUL IF SWALLOWED. MAY
CAUSE SEVERE AND PERMANENT DAMAGE TO DIGESTIVE TRACT, GI
IRRITATION, NAUSEA, VOMITING, DIARRHEA, GI TRACT BURNS. MAY CAUSE
PERFORATION OF DIGESTIVE TRACT. INGESTION OF LARGE AMOUNTS MAY
CAUSE CNS DEPRESSION, SYSTEMIC EFFECTS. INHALATION: HARMFUL IF
INHALED. CAUSES BURNS, SPASM, INFLAMMATION, EDEMA, DIZZINESS OR
SUFFOCATION. CHRONIC: MAY CAUSE DERMATITIS, CANCER IN HUMANS ,
REPRODUCTIVE AND FETAL EFFECTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE: CAUSES BURNS. SKIN: CAUSES BURNS, SKIN
RASH. INGESTION: GI IRRITATION, NAUSEA, VOMITING, DIARRHEA, GI
TRACT BURNS. MAY CAUSE PERFORATION OF DIGESTIVE TRACT. INGESTION OF
LARGE AMOUNTS MAY CAUSE C NS DEPRESSION, SYSTEMIC EFFECTS.
INHALATION: CAUSES BURNS, SPASM, INFLAMMATION, EDEMA, DIZZINESS OR
SUFFOCATION.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST
15 MINUTES, OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. GET
MEDICAL AID IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES
CLOSED. SKI N: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH WITH
PLENTY OF SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING. IF
VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER.
NEVER GIVE ANYT HING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
AID IMMEDIATELY. INHALATION: GET MEDICAL AID IMMEDIATELY. REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION (NOT
MOUTH-TO-MOUTH). I F BREATHING IS DIFFICULT, GIVE OXYGEN.
===================== Fire Fighting Measures =====================
Flash Point:=21.1C, 70.F
Autoignition Temp:=293.3C, 560.F
Lower Limits:1.5
Upper Limits:9.4
Extinguishing Media:SMALL FIRES: DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY/ALCOHOL-RESISTANT FOAM. LARGE FIRES: WATER SPRAY,
FOG/ALCOHOL-RESISTANT FOAM. USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SLEF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR. VAPORS MAY FORM AN EXPLOSIVE
MIXTURE WITH AIR. WATER MAY BE INEF FECTIVE. DO NOT USE STRAIGHT
STREAM OF WATER.
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND HIGHLY
TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION. CONTAINER MAY EXPLODE IN THE HEAT OF A FIRE. FLAMMABLE
LIQUID.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
ABSORB SPILL WITH INERT MATERIAL. (E.G. DRY SAND OR EARTH) THEN
PLACE INTO A CHEMICAL WASTE CONTAINER. USE WATER SPRAY TO DILUTE
SPILL TO A NON-FLAMMABLE MIXT URE. CLEAN UP SPILLS IMMEDIATELY.
SCOOP UP WITH A NONSPARKING TOOL, THEN PLACE INTO A SUITABLE
CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE GAS/VAPOR.
REMOVE ALL SORUCES OF IGNITION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT AND IGNIITION
SOURCES. KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN TIGHTLY
CLOSED CONTAINERS IN A COOL, DRY AREA, AWAY FROM OXIDIZERS AND
ACIDS. USE IN WELL VENTILATED AREA. GR OUND AND BOND CONTAINERS
WHEN TRANSFERRING. USE SPARK-PROOF TOOLS AND EXPLOSION PROOF
EQUIPMENT.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED
CLOTHING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. EMPTY
CONTAINER RETAINS PRODUCT RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE
DANGEROUS. DO NOT PR ESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OPEN
FLAMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS
OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS/EUROPEAN
STANDARD EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE. FOLLO W OSHA RESPIRATOR REGULATIONS
FOUND IN 29CFR 1910.134/EUROPEAN STANDARD EN 149. ALWAYS USE A
NIOSH/EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW. USE ADEQUATE GENERAL/LOCAL EXPLOSION-PROOF VENTILATION TO KEEP
AIRBORNE LEVELS ACCEPTABLE.
Protective Gloves:WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT SKIN
EXPOSURE.
Eye Protection:PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY GOGGLES
Other Protective Equipment:FACILITIES STORING OR UTILIZING THIS
MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITIY AND A SAFETY
SHOWER.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI
= GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS.
================== Physical/Chemical Properties ==================
HCC:F7
NRC/State Lic Num:NOT PROVIDED
Boiling Pt:=57.2C, 135.F
Melt/Freeze Pt:=-27.6C, -18.F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:10 MMHG@20C
Vapor Density:3.42
Spec Gravity:0.865
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:MISCIBLE IN WATER.
Appearance and Odor:CLEAR, COLORLESS LIQUID, STRONG, FISHY ODOR.
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ORGANIC ANHYDRIDES, ISOCYANATES, VINYL ACETATE, ACRYIATES,
SUBSTITUED ALKYLS, ALKYLENE OXIDES, EPICHLOROHYDRIN, KETONES,
ALDEHYDES, ALCOHOLS, GLYCOLS, PHENOLS, CRESOL, CAPROLACTAM
SOLUTION, STRONG OXIDIZERS, COPPER A
Stability Condition to Avoid:HIGH TEMPERATURES, MECHANICAL SHOCK,
INCOMPATIBLE MATERIALS, IGNITION SOURCES, EXCESS HEAT.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
IRRITATING AND TOXIC FUMS AND GASES.
=================== Toxicological Information ===================
Toxicological Information:INHALATION: MOUSE: LC50=1070 MG/M3; RAT:
LC50=7500 MG/M3; ORAL MOUSE: LD50=224 MG/KG. ORAL RAT: LD50=156
MG/KG. SKIN RABBIT: LD50=277 MG/KG.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: FISH RAINBOW TROUT: LC50=90 MG/L; 96 HR; STATIC
CONDITION, 15C FISH. RAINBOW TROUT: LC50=44 MG/L; 96 HR; 20.0 MG/L
CACO3 WATER FLEA DAPHNIA: EC50=80 MG/L, 24 HR; 70.0 MG/L CA CO3
ALGAE; E C50=20 MG/L 96 HR, UNSPECIFIED.
==================== Disposal Considerations ====================
Waste Disposal Methods:CHEMICAL WASTE GENERATORS MUST DETERMINE WHETHER
A DISCARDED CHEMICAL IS CLASSIFIED AS A HAZARDOUS WASTE. US EPA
GUIDELINES FOR THE CLASSIFICATION DETERMINATION ARE LISTED IN 40
CFR. ADDITIONALLY, WAS TE GENERATORS MUST CONSULT STATE AND LOCAL
HAZARDOUS WASTE REGULATIONS TO ENSURE COMPLETE AND ACCURA TE
CLASSIFICATION.
=================== MSDS Transport Information ===================
Transport Information:US DOT SHIPPING NAME: CYCLOHEXYLAMINE. HAZARD
CLASS: 8. UN NUMBER: UN2357. PACKING GROUP: II
===================== Regulatory Information =====================
SARA Title III Information:SARA SECTION 302: TPQ=10,000 LBS; RQ=10,000
LBS. SARA CODES: ACUTE, CHRONIC, FLAMMABLE. SECTION 313: NOT
REPORTABLE.
Federal Regulatory Information:TSCA: LISTED.
State Regulatory Information:CYCLOHEXYLAMINE CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHEM ICALS IN THIS PRODUCT ARE
LISTED.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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