===================== Product Identification =====================
MSDS NAME:443NS
NIIN:01-380-4214
Status Code:A
MSDS Number: CLNPL
=== Responsible Party ===
Company:SULZER METCO (US) INC
Address:1101 PROSPECT AVENUE
Box:1006
City:WESTBURY
State:NY
ZIP:11590-0201
Country:US
Info Phone Num:516-334-1300
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:MSDS-NO: 50-173
Chemtrec Ind/Phone:(800)424-9300
CAGE:NO615
=== Contractor Identification ===
Company:SULZER METCO (US) INC
Address:1101 PROSPECT AVENUE
Box:1006
City:WESTBURY
State:NY
ZIP:11590-0201
Country:US
Phone:516-334-1300
CAGE:NO615
============= Composition/Information on Ingredients =============
Name:NICKEL
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 73.00%
OSHA PEL:1 MG/M3
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:CHROMIUM
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 18.00%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ALUMINIUM
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 5%
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
Fraction by Wt: 1%
OSHA PEL:10 MG/M3 TWA FE2O3
ACGIH TLV:5 MG/M3 TWA FE2O3
Name:MANGANESE
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: 1%
OSHA PEL:C5 MG/M3
ACGIH TLV:5 MG/M3
Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: 1%
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:ORGANIC BINDER
Fraction by Wt: 1%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:INHALATION:IRRITATION TO THE
RESPIRATORY SYSTEM,CNS,CANCER OF THE LUNGS,STOMACH AND SINUSES,MAY
CAUSE PNEUMOCONIOSIS AND MUCOUS MEMBRANE IRRITATION OR
ULCERATION,SIDEROSIS,MAY CAUSE MANGANISM CHARACTE RIZED BY
PSYCHOSIS AND NEUROLOGICAL
IMPAIRMENT,DIZZINESS,VOMITIMG,CONVULSION,SILICOSIS.REPEATED
INHALATION MAY LIVER,KIDNEY DAMAGE.INGESTION:IRRITATION TO
GASTROINTESTINAL TRACT,LOSS OF MUSCULAR COOR
DINATION,CONFUSION&CONVULSION.SKIN:CONTACT MAY CAUSE
DERMATITIS,SENSITIZATION TO CHROME LESIONS,SKIN IRRITATION AND
BURNS,EYES:CONTACT MAY CAUSE IRRITATION.TARGET ORGAN: RESPIRATORY
SYSTEM,EYES,SKIN,G ASTROINTESTINAL TRACT,CNS,LIVER,KIDNEYS.
Explanation of Carcinogenicity:HEXAVALENT CHROMIUM IS ACGIH CLASSIFIED
A1 CONFIRMED HUMAN CARCINOGEN AND IARC CLASSIFICATION GROUP 1
CARCINOGEN TO HUMANS. NTP CLASSIFIES HEXAVALALENT CHROMIUM AS KNOWN
TO BE CARCINOGEN.
Effects of Overexposure:EYE: POSSIBLE CONJUNCTIVAL IRRITATION,
LACRIMATION, BURNS, SKIN: POSSIBLE IRRITATION, DERMATITIS, EXZEMA,
SENSITIZATION OR CHROME LESIONS, DISCOLORATION, BURNS. INHALATION:
POSSIBLE IRRITATION TO THE RESPIRATORY SYSTEM, NUCOUS MEMBRANE
IRRITATION OR ULCERATION, SHORTNESS OF BREATH, COUGH, DECREASED
CHEST EXPANSION, LESSENED CAPACITY FOR WORK, BURNING SENSATIONS,
DIZZINESS, VOMITING. INGESTION: PO SSIBLE IRRITATION TO THE
RESPIRATORY SYSTEM AND GASTROINTESTINAL TRACT, LOSS OF MUSCULAR
COORDINATION, CONFUSION AND CONVULSIONS.
Medical Cond Aggravated by Exposure:CONSULT A PHYSICIAN.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH EYE WITH WATER FOR AT LEAST 15-20 MINUTES WHILE
HOLDING EYELID OPEN. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN.
SKIN: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONSULT A
PHYSICIAN . INHALATION: EXPOSE TO FRESH AIR. CONSULT A PHYSICIAN IF
IRRITAITON OR RESPIRATORY DISTRESS PERSISTS. INGESTION: CONSULT A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NOT PROVIDED BY
Extinguishing Media:USE CLASS D FIRE EXTINGUISHER
Fire Fighting Procedures:TREAT AS A METALLIC FIRE. USE NIOSH/MSHA
APPROVED SELF CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
CLOTHING IF INVOLVED IN A FIRE.
Unusual Fire/Explosion Hazard:FINE METAL DUSTA ARE FLAMMABLE AND MAY
EXPLODE WHEN EXPOSED TO HEAT, FLAME OR OXIDIZERS. CHROMIUM AND IRON
MAY IGNITE IF AIRBORNE IN THE PRESENCE OF AN IGNITION SOURCE.
ALUMINUM IS A FLAMMABLE SOLID, DO NOT EXPOSE TO WATER OR
MOISTURE.THE ORGANIC BINDER BURNING OR AT ELEVATED TEMP MAY PRODUCE
CO2,CO AND PHENOL.
================== Accidental Release Measures ==================
Spill Release Procedures:APPROVED RESPIRATORY EQUIPMENT,PROTECTIVE
CLOTHING,GLOVES AND SAFEY GLASSES SHOULD BE WORN TO PREVENT CONTACT
OR INHALATION DURING THE CLEANUP OF PRODUCT SPILLS.COLLECT MATERIAL
BY WET SWEEPING,DRY SW EEPING WITH A SWEEPING COMPOUND OR BY VACUUM
CLEANING WITH AN EXPLOSION PROOF APPARATUS EQUIPPED WITH A HIGH
EFFIEIENCY PARTICULATE AIR FILTER. SALVAGE MATERIAL FOR ON-SITE
REUSE OR(OTHER INFO)
Neutralizing Agent:NOT PROVIDED BY MFR
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLES. STORE
PRODUCT CONTAINERS IN A WELL-VENTILATED, CLEAN, COOL AND DRY AREA.
STORE IN A MINNER TO MINIMIZE PUNCTURES AND BREAKAGE OF CONTAINERS.
Other Precautions:AVOID INGESTION, INHALATION AND EXCESSIVE SKIN
CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATOR APPROVED BY NIOSH WITH FILTER
CARTRIDGES APPROVED FOR DUST/FUMES/MISTS SHOULD BE WORN AT ALL
TIMES. DURING THE THERMAL SPRAY PROCESS TO PROTECT THE OPERATOR
FROM EXPOSURE TO DUST AND FUME S. RESPIRATORS MAY ALSO BE WORN WHEN
PRODUCT HANDLING GENERATES DUST.
Ventilation:PRODUCT SHOULD BE USED WITH THE APPROPRIATE LOCAL EXHAUST
VENTILATION PROVIDED.
Protective Gloves:ALUMINIZED GLOVES TO BE WORN DURING PLASMA SPRAY
PROCESS.RUBBER(SEE SUPP DATA)
Eye Protection:THE FOLLOWING LENSES ARE RECOMMENDED:COMBUSTION SPRAYING
SHADE # 5(SEE SUPP DAT
Other Protective Equipment:EYE WASH STATION(S) IS/ARE RECOMMENDED. WASH
FACILITIES ARE RECOMMENDED. EAR PROTECTION MUST BE WORN WHEN THE
OPERATOR IS SUBJECTED TO EXCESSIVE NOISE LEVELS. (REFER TO THE
APPROPRIATE REGULATORY
Work Hygienic Practices:NOT PROVIDED BY MFR
Supplemental Safety and Health
OR OTHER APPROPRIATE GLOVES MAY BE WORN AS NECESSARY DURING OTHER
PHASES OF PRODUCT HANDLING TO AVOID EXCESSIVE SKIN CONTACT.EYE
PROTECT:, PLASMA SPRAYING UP TO 40 KW SHADE #9, 40-60 KW SHADE # 10
AND GREATER THAN 60 KW SHADE # 11. GOGGLES MAY BE APPROPRIATE
DURING OTHER PHASES OF PRODUCT HANDLING.
================== Physical/Chemical Properties ==================
HCC:T6
Decomp Temp:Decomp Text:NOT PROVIDED BY MFR
Viscosity:NOT PROVIDED BY MFR
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY POWDER, NO ODOR
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED BY MFR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NICKEL IS INCOMPATIBLE WITH ACIDS,SULFUR,SELENIUM,WOOD,OTHER
COMBUSTIBLES AND NICKEL NITRATE.CHROMIUM IS INCOMPATIBLE WITH
STRONG OXIDIZERS.ALUMINUM IS INCOMPATIBLE WITH STRONG
OXIDIZERS,ACIDS&HALONGENATED HYDROCARBONS,IRON
Stability Condition to Avoid:NOT PROVIDED BY MFR
Hazardous Decomposition Products:OZONE AND NITRIC OXIDE ARE FORMED BY
PLASMA FLAME (DIMILAR TO WELDING FUME). THIS ACTION IS INDEPENTENT
OF METAL POWDER.
Conditions to Avoid Polymerization:WILL NOT OCCUR
==================== Disposal Considerations ====================
Waste Disposal Methods:EMPTY PRODUCT CONTAINERS, PRODUCT WASTE AND
CLEANING MEDIA SHOULD BE STORED AND DISPOSED OF ACCORDING TO THE
APPROPRIATE LOCAL, STATE AND FEDERAL REGULATORY GUIDELINES.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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