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MSDS  
:
 PHENOL, LIQUEFIED
CAS  
:
 108-95-2
NAME  
:
 carbolic acid,phenic acid, phenylic acid, hydroxybenzene,
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[ PHENOL, LIQUEFIED 108-95-2 ]
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=====================  Product Identification  =====================

MSDS NAME:PHENOL, LIQUEFIED
Status Code:A
MSDS Number: CLSKG
=== Responsible Party ===
Company:MALLINCKRODT INC., SCIENCE PRODUCTS DIV
Box:M
City:PARIS
State:KY
ZIP:40361-0315
Country:US
Info Phone Num:314-982-5000
Emergency Phone Num:314-982-5000
CAGE:1BF21
=== Contractor Identification ===
Company:MALLINCKRODT INC., SCIENCE PRODUCTS DIV
Box:M
City:PARIS
State:KY
ZIP:40361-0315
Country:US
Phone:314-982-5000
CAGE:1BF21

=============  Composition/Information on Ingredients  =============

Name:CARBOLIC ACID,PHENIC ACID, PHENYLIC ACID, HYDROXYBENZENE,
    PHENOL LIQUIFIED
CAS:108-95-2
RTECS #:SJ3325000
= Wt:94.11
OSHA PEL:19 MG/M3;5 PPM
ACGIH TLV:19 MG/M3;5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL RAT LD50: 414MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Health Hazards Acute and Chronic:DANGER! MAY BE FATAL IS SWALLOWED,
    INHALED OR ABSORBED THROUGH SKIN. CAUSES SEVERE BURNS. EXPOSURE MAY
    PRODUCE LIVER, KIDNEY, AND NEUROLOGICAL DISORDERS. COMBUSTIBLE.
    INHALATION: DIGESTIVE DISTURBANCE S (VOMITING, DIFFICULTY
    SWALLOWING, DIARRHEA, LOSS OF APPETITE.) INGESTION: POISON. BURNING
    PAIN IN MOUTH AND THROAT, ABDOMINALL PAIN, HEADACHE, DIZZINESS,
    MUSCULAR WEAKNESS, IRREGULAR BREATHING, COMA , POSSIBLY DEATH.
    SKIN: CORROSIVE, MAY BE ABSORBED WITH SYSTEMATIC POISONING EFFECTS
    TO FOLLOW. DISCOLORATION AND SEVERE BURNS MAY OCCUR. EYE:
    CORROSIVE, REDNESS, PAIN, BLURRED VISION.
Effects of Overexposure:CHRONIC: SAME AS ACUTE POISONING AS WELL AS
    LIVER DAMAGE.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS OR EYE
    PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY BE MORE
    SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:IN ALL CASES CALL PHYSICIAN IMMEDIATELY. IF SWALLOWED, GET
    IMMEDIATE MEDICAL ATTENTION. GIVE LARGE QUANTITIES OF MILK OR
    WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF
    INHALED: REMOV E TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF
    CONTACT, IMMEDIATELY FLUSH SKIN/EYE WITH PLENTY OF WATER FOR  AT
    LEAST 15 MINUTES. LIF T EYELID. REMOVE CONTAMINATED CLOTHING AND
    WASH BEFORE REUSE.

=====================  Fire Fighting Measures  =====================

Flash Point:=78.3C, 173.F
Autoignition Temp:=605.C, 1121.F
Lower Limits:1.7
Upper Limits:8.6
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CARBON
    DIOXIDE.
Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE
    CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
    FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
    PRESSURE MODE.
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE
    EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. CONTACT WITH
    OXIDIZERS MAY GENERATE EXPLOSIVE MIXTURES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA OF SPILL. REMOVE ALL SOURCES OF
    IGNITION. CLEAN-UP PERSONNEL REQUIRE PROTECTIVE CLOTHING &
    RESPIRATORY PROTECTION FROM VAPORS. CONTAIN/RECOVER LIQUID WHEN
    POSSIBLE. COLLECT AS HAZARDOUS  WASTE & ATOMIZE IN A SUITABLE RCRA
    APPROVED COMBUSTION CHAMBER, OR ABSORB W/VERMICULITE/DRY
    SAND/EARTH/SIMILAR MATERIAL FOR DISPOSAL AS HAZARDOUS WASTE IN RCRA
    APPROVED FACILITY. DON'T FLUSH TO SEWER

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID BREATHING VAPORS, CONTACT
    W/EYES/SKIN/CLOTHING. KEEP CONTAINERS CLOSED. USE WITH ADEQUATE
    VENTILATION. WASH THOROUGHLY AFTER HANDLING. THIS SUBSTANCE IS
    CLASSIFIED AS POISON UNDER THE FEDERAL CA USTIC POISON ACT.
Other Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER. PROTECT FROM
    PHYSICAL DAMAGE. STORE IN A COOL, DRY, VENTILATED AREA AWAY FROM
    SOURCES OF HEAT, MOISTURE AND INCOMPATIBILITIES. OUTSIDE OR
    DETACHED STORAGE IS PERFER RED. SEPERATE FROM OTHER STORAGE. DO NOT
    ALLOW UNTRAINED WORKERS TO HANDLE PHENOL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF TLV IS EXCEEDED A FULL FACEPIECE CHEMICAL
    CARTRIDGE RESPIRATOR MAY BE WORN, IN GENERAL, UP TO 100 TIMES THE
    TLV OR THE MAX USE CONCENTRATION SPECIFIED BY THE RESPIRATOR
    SUPPLIER, WHICHEVER IS LESS.  ALTERNATIVELY, A SUPPLIED AIR FULL
    FACEPIECE REESPIRATOR OR AIRHOOD MAY BE WORN.
Ventilation:LOCAL AND/OR GENERAL EXHAUST RECOMMENDED. LOCAL PERFERRED
Protective Gloves:YES
Eye Protection:SAFETY GOGGLES AND/OR FULL FACE SHIELD WHERE SPLASHING
    POSSIBLE
Other Protective Equipment:DO NOT WEAR CONTACT LENSES. MAINTAIN EYE
    WASH AND QUICK-DRENCH FACILITIES IN WORK AREA. WEAR IMPERVIOUS
    PROTECTIVE CLOTHING, BOOTS, LAB COAT, APRON, COVERALLS TO PREVENT
    SKIN CONTACT.
Supplemental Safety and Health
VERY SOLUBLE IN ALCOHOL. CONGEALING POINT: (50.9-57.2F) 10.5-14C. 
    AIRBORNE EXPOSURE LIMITS: OSHA PEL: 5 PPM TWA SKIN. ACGIH TLV: 5
    PPM TWA

==================  Physical/Chemical Properties  ==================

Boiling Pt:=182.2C, 360.F
Vapor Pres:0.4
Vapor Density:3.2
Spec Gravity:1.06
Evaporation Rate & Reference:<0.01 (BUAC=1)
Solubility in Water:1.15G/15G
Appearance and Odor:COLORLESS TO LIGHT PINK LIQUID. SHARP MEDICIANL
    SWEET TARRY ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ALUMINUM CHLORIDE AND NITROBENZENE, CALCIUM HYPOCHLORITE
    BUTADIENE. HOT LIQUID PHENOL WILL ATTACK ALUMINUM, MAGNESIUM, LEAD,
    AND ZINC METALS.
Stability Condition to Avoid:HEAT WILL CONTRIBUTE TO INSTABILITY
Hazardous Decomposition Products:TOXIC GASES AND VAPORS MAY BE RELEASED
    IF INVOLVED IN A FIRE

===================  Toxicological Information	===================

Toxicological Information:SKIN RABBIT LD50: 850 MG/KG INHALATION RAT
    LC50: 316 MG/K3 IRRITATION DATA: SKIN RABBIT 500 MG/24H SEVERE EYE
    RABBIT 5 MG SEVERE MUTATION REFERENCES CITED. REPRODUCTIVE EFFECTS
    REFERENCES CITED. TUMOR IGENIC DATA REFERENCES CITED.

=====================  Ecological Information  =====================

Ecological:ENVIRON TOX: MATL IS EXPECTED TO BE TOX TO AQUATIC LIFE.
    LC50/96-HR VALUES FOR FISH ARE BETWEEN 10 & 100 MG/L. ENVIRON FATE:
    WHEN RELEASED INTO SOIL, MATL IS EXPECTED TO READILY BIODEGRADE,
    NOT EXPECT ED TO LEACH INTO GROUNDWATER, MAY EVAP TO MOD EXTENT, IS
    EXPECTED TO HAVE HALF-LIFE BETWEEN 1 & 10 DAYS. WHEN RELEASED INTO
    WATER, MATL IS EXPECTED TO READILY BIODEGRADE, IS NOT EXPECTED TO
    EVAP SIGNI FICANTLY, IS EXPECTED TO HAVE HALF-LIFE BETWEEN 10 & 30
    DAYS. MATL HAS ESTIMATED BIOCONC FACTOR (BCF) OF <100. MATL IS NOT
    EXPECTED TO SIGNIFICANTLY BIOACCUM. CONT NEHC FOR MORE COMPLETE
    INFO .

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
    FEDERAL REGULATIONS.

===================  MSDS Transport Information  ===================

Transport Information:DOT HAZARD CLASS: POISON -B

=====================  Regulatory Information  =====================

SARA Title III Information:PHENOL, LIQUEFIED (108-95-2) 88% SARA EHS
    SECT. 302 RQ: 1000 LBS, TPQ 500 LBS. SARA SECTION 313 CHEMICALS:
    NAME LIST: YES, CHEMICAL CATEGORY: NO
Federal Regulatory Information:REPORTABLE QUANTITY: 1000 LBS. RCRA SEC
    261.33 U188
State Regulatory Information:

=======================  Other Information  =======================

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***
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SOCK IT SHOCK TREATMENT & SUPERCHLORINATOR 471-34-1
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