===================== Product Identification =====================
MSDS NAME:IP860207P222.7.5, P222 BLEACH
NIIN:01-429-3782
Status Code:A
MSDS Number: CLSKN
=== Responsible Party ===
Company:ILFORD IMAGING USA INC
Address:W 70 CENTURY RD
City:PARAMUS
State:NJ
ZIP:07652-1490
Country:US
Info Phone Num:201-265-6000 /FAX: 201-265-0894
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:10208-P222 BLEACH
Preparer's Name:DR. D. W. BUTCHER
Chemtrec Ind/Phone:(800)424-9300
CAGE:0LT87
=== Contractor Identification ===
Company:ILFORD IMAGING USA INC
Address:33 LEWIS RD
Box:City:BINGHAMTON
State:NY
ZIP:13905
Country:US
Phone:607-766-3153/ FAX 201-225-3514
CAGE:0LT87
============= Composition/Information on Ingredients =============
Name:SODIUM 3-NITROBENZENESULFONATE
CAS:127-68-4
RTECS #:DB7195000
Fraction by Wt: 0-1%
Name:POLYGLYCOL ETHER
Fraction by Wt: 0-1%
Name:QUINOXALINE DERIVATIVE
CAS:17635-21-1
Fraction by Wt: 0-1%
Name:3-MERCAPTO-1-PROPANESULPHONIC ACID
CAS:17636-10-1
Fraction by Wt: 0-1%
Name:POTASSIUM IODIDE
CAS:7681-11-0
RTECS #:TT2975000
Fraction by Wt: 1-5%
Name:SULPHURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 1-5%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:NOT REGARDED AS A HEALTH HAZARD UNDER
CURRENT LEGISLATION. INHALATION: NO SPECIFIC HEALTH WARNINGS NOTED.
INGESTION: NO SPECIFIC HEALTH WARNINGS NOTED. SKIN: NO SPECIFIC
HEALTH WARNINGS NOTED. EYES: IRRITATING TO EYES. NO SPECIFIC
HEALTH WARNING NOTED. SPRAY AND VAPOR MAY RESULT IN IRRITAION AND
ITCHING OF THE EYES.
Explanation of Carcinogenicity:SUPHURIC ACID MIST ACGIH A2 1 IARC INT.
AGENCY FOR RESEARCH CANCER. SUSPECT CANCER HAZARD.
Effects of Overexposure:NOT REGARDED AS A HEALTH HAZARD UNDER CURRENT
LEGISLATION. INHALATION: NO SPECIFIC HEALTH WARNINGS NOTED.
INGESTION: NO SPECIFIC HEALTH WARNINGS NOTED. SKIN: NO SPECIFIC
HEALTH WARNINGS NOTED. EYES: IRRITATING TO EYES. NO SPECIFIC
HEALTH WARNING NOTED. SPRAY AND VAPOR MAY RESULT IN IRRITAION AND
ITCHING OF THE EYES. IRRITATING TO EYES.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING:
PRE-EXISTING EYE PROBLEMS.
======================= First Aid Measures =======================
First Aid:INHALATION: NO RECOMMENDATION GIVEN, BUT FIRST AID MAY STILL
BE RQUIRED IN CASE OF ACCIDENTAL EXPOSURE, INHALATION OR INGESTION
OF THIS CHEMICAL. IF IN DOUBT, GET MEDICAL ATTENTION PROPMPTLY!
INGESTIO N: RINSE MOUTH THOROUGHLY. ADMINISTER LARGE AMOUNTS OF
WATER. GET MEDICAL ATTENTION IF ANY DISCOMFORT CONTINUES. SKIN:
RINSE WITH WATER. EYES: MAKE SURE TO REMOVE ANY CONTACT LENSES FROM
THE EYES BEFO RE RINSING. PROMPTLY WASH EYES WITH LOTS OF WATER
WHILE LIFTING THE EYE LIDS, CONTINUE TO RINSE FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION IF ANY DISCOMFORT CONTINUES.
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:THIS MATERIAL IS NOT FLAMMABLE. USE EXTINGUISHING
MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:MAY DEVELOP HIGHLY TOXIC OR CORROSIVE
FUMES IF HEATED. FIRE CREATES: CORROSIVE GASES/VAPORS/FUMES.
SULFUROUS GASES (SOX).
================== Accidental Release Measures ==================
Spill Release Procedures:USE APPROPRIATE PROTECIVE CLOTHING. DO NOT
CONTAIMINATE DRAINAGE OR WATERWAYS. NEUTRALIZE WITH SODIUM
BICARBONATE (BAKING SODA), SODIUM CARBONATE (SODA ASH) OR ILFORD
BL/NE NEUTRALIZER. ABSORB SPILL W ITH NON-REACTIVE ABSORBENT AND
PLACE IN NON-REACTIVE CONTAINERS FOR DISPOSAL.USE LARGE QUANTITIES
OF WATER TO FLUSH SPILLS TO SANITARY IF LOCAL REGULATIONS PERMIT.
DO NOT FLUSH TO SEPTIC TANK.
Neutralizing Agent:SODIUM BICARBONATE (BAKING SODA), SODIUM CARBONATE
(SODA ASH) OR ILFORD BL/NE NEUTRALIZER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID SPILLING, SKIN AND EYE CONTACT.
READ AND FOLLOW MANUFACTURER'S RECOMMENDATIONS. PROVIDE GOOD
VENTILATION. KEEP IN COOL, DRY, VENILATED STORAGE AND CLOSED
CONTAINERS. KEEP IN ORIGINAL CONTAINER.S TORAGE CRITERIA: CORROSIVE
STORAGE.
Other Precautions:AVOID SPILLING, SKIN AND EYE CONTACT. READ AND FOLLOW
MANUFACTURER'S RECOMMENDATIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATORY PROTECTION MUST BE USED IF AIR
CONCENTRATION EXCEEDS ACCEPTABLE LEVEL. AN ACID GAS/ORGANIC VAPOR
CARTRIDGE SHOULD BE USED.
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION.
MUST NOT BE HANDLED IN CONFINED SPACES WITHOUT ADEQUATE
VENTILATION. (SEE SUPPLEMENTAL DATA).
Protective Gloves:NEOPRENE, NITRILE, POLYETHYLENE BUTYL RUBBER. *(SEE
SUPPLEMENTAL DATA).
Eye Protection:WEAR APPROVED SAFETY GOGGLES.
Other Protective Equipment:PROVIDE EYEWASH STATION AND IT IS
RECOMMENDED THAT A SAFETY SHOWER IS ALSO AVAILABLE. WEAR
APPROPRIATE CLOTHING TO PREVENT ANY POSSIBOILITY OF SKIN CONTACT.
Supplemental Safety and Health
GENERAL ROOM VENTILATION SHOULD PROVIDE FOR 10-15 ROOM AIR CHANGES PER
HOUR. *USE THIN COTTON GLOVES INSIDE THE RUBBER GLOVES IF ALLERGY
RISK.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:>37.8C, 100.F
Melt/Freeze Pt:<-17.6C, 0.F
Vapor Density:1.05
Spec Gravity:20
pH:<1
Evaporation Rate & Reference:1 H2O (WATER)=1
Appearance and Odor:YELLOWISH LIQUID. WATER SOLUBLE. SLIGHT, SOLVENT
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTAT WITH OTHER PHOTOGRAPHIC SOLUTIONS AND/OR CLEANING
COMPOUNDS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT FOR PROLONGED PERIODS
OF TIME.
Hazardous Decomposition Products:IRRITATING GASES/VAPORS/FUMES OF:
SULFUROUS GASES (SOX0
Conditions to Avoid Polymerization:WILL NOT POLYMERIZE.
=================== Toxicological Information ===================
Toxicological Information:TOXIC DOSE-LD 50: SULPHURIC ACID 2140; SODIUM
3-NITROBENZENESULPHONATE 11000 MG/KG (ORAL RAT). TOXICOLOGICAL
INFORMATION: THIS CHEMICAL FORMAULATION HAS NOT BEEN TESTED FOR
HEALTH EFFECTS. EXPOSURE EF FECTS LISTED ARE BASED ON EXISTING
HEALTH DATA FOR THE INDIVIDUAL COMPONENTS WHICH COMPRIST THE
MIXTURE.
===================== Ecological Information =====================
Ecological:LC 59, 96 HRS, FISH, MG/L: 1990 SULPHURIC ACID. EC 50, 48
HRS, DAPHNIA, MG/L; 8665 SODIUM 3-NITROBENZESULPHONATE. ECOLOGICAL
INFORMATION: NOT REGARDED AS DANGEROUS FOR THE ENVIRONMENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:BLEACH SOLUTION, BOTH UNUSED AND SPENT, ARE RCRA
AND CEPA HAZARDOUS WASTE UNLESS NEUTRALIZED BEFORE DISPOSAL.
NEUTRALIZED BLEACH SOLUTION MAY BE ALLOWED TO BE DISCHARGED TO
SANITARY SEWER BY PERMIT IF ALLOWED BY LOCAL REGULATIONS. CONSULT
YOUR LOCAL AUTHORITY FOR ADVICE. DO NOT DISCHARGE TO SEPTIC S
YSTEMS.
=================== MSDS Transport Information ===================
Transport Information:UN/NA NO.: 2796. U.S. DOT HAZARD LABEL: CORROSIVE
(BLACK/WHITE DIAM.) DOT17. U.S. DOT CLASS: CORROSIVE MATERIAL. U.S.
DOT PACKING GROUP: II, UN NO. SEA: 2796. IMDG CLASS: 8, IMDG PAGE
NO.: 8230, IMDG PACK GR.: II, EMS NO.: 8-06, MFAG TABLE NO.: 700,
UN NO., AIR: 2796, ICAO CLASS: 8, AIR PACK GR.: II. INFORMATION ON
IAR TRANSPORT: SHIP BY CARGO AIRCRAFT ONLY.
===================== Regulatory Information =====================
SARA Title III Information:SULFURIC ACID: CERCLA (EPA
SUPERFUNG)-COMPREHENSIVE ENVIRONM. RESPONSE, COMP. LIABILITY ACT.
CLEAN WATER ACT, S311 (FED.REG.-EPA). DOT HAZARDOUS MAT. TRANSP.
ACT (49 CFR). NIOSH CRITERIA DOCUMENTS. OS HA CHEMICAL HAZARD
COMMUNIC. STD.-AIR CONTAMINANTS (29CFR1910). ACGIH THRESHOLD LIMIT
VALUES. EPA REPORTABLE & THRESHOLD QUANTITIES. SARA SECTION 302,
EXTREMELY HAZARDOUS SUBSTANCES. SARA SECTIOON 313 , TOXIC
CHEMICALS. SARA TITLE III CONSOLIDATED CHEMICAL LIST (302, CERCLA,
313, RCRA).
Federal Regulatory Information:TSCA: THE INGREDIENTS OF THIS PRODUCT
ARE ON THE TSCA INVENTORY. SODIUM 3-NITR (127-68-4), QUIOXALINE
(17635-21-1), 3-MERCAPTO-1 (17636-10-1).
State Regulatory Information:FLORIDA HAZAROUS SUBSTANCE LIST
MASSACHUSETTS RIGHT-TO-KNOW. MASSACHUSETTS EXTRAORDINARILY
HAZARDOUS SUBSTANCES LIST NEW JERSEY RIGHT-TO-KNOW. NJ
EVVIRONMENTAL HAZARDOUS SUBSTANCES LIST NJ SPECIAL HAZ ARDOUS
SUBSTANCES LIST PENNSYLVANIA RIGHT-TO-KNOW.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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