===================== Product Identification =====================
MSDS NAME:IP990331FX/FXR3., P3 FIXER/REP
NIIN:01-464-0265
Status Code:A
MSDS Number: CLSJT
=== Responsible Party ===
Company:ILFORD IMAGING USA INC
Address:W 70 CENTURY RD
City:PARAMUS
State:NJ
ZIP:07652-1490
Country:US
Info Phone Num:201-265-6000 /FAX: 201-265-0894
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:10032-P3 FIXER/REP
Preparer's Name:DR. D. W. BUTCHER
Chemtrec Ind/Phone:(800)424-9300
CAGE:0LT87
=== Contractor Identification ===
Company:ILFORD IMAGING USA INC
Address:33 LEWIS RD
Box:City:BINGHAMTON
State:NY
ZIP:13905
Country:US
Phone:607-766-3153/ FAX 201-225-3514
CAGE:0LT87
============= Composition/Information on Ingredients =============
Name:NITRILOTRIACETIC ACID
CAS:139-13-9
RTECS #:AJ0175000
Fraction by Wt: 0-1%
Name:AMMONIUM SULFITE
CAS:10196-04-0
Fraction by Wt: 5-10%
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM THIOSULPHATE
CAS:7783-18-8
RTECS #:XN6465000
Fraction by Wt: 30-60%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:NOT REGARDED AS A HEALTH HAZARD UNDER
CURRENT LEGISLATION. INHALATION: NO SPECIFIC HEALTH WARNINGS NOTED.
INGESTION: NO SPECIFIC HEALTH WARNINGS NOTED. SKIN: NO SPECIFIC
HEALTH WARNINGS NOTED. EYES: IRRITATING TO EYESHEALTH WARNING: NO
SPECIFIC HEALTH WARNING NOTED. SPRAY AND VAPOR MAY RESULT IN
IRRITATION AND ITCHING TO THE EYES..
Explanation of Carcinogenicity:NITRILOTRIACETIC ACID: NTP CARCINOGENS
(DHHS). IARAC 2B IARC ANIMAL CARCINOGEN LIST.INT. AGENCY FOR
RESEARCH CANCER.
Effects of Overexposure:IRRITATING TO EYES.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING:
PRE-EXISTING EYE PROBLEMS.
======================= First Aid Measures =======================
First Aid:INHALATION: NO RECOMMENDATION GIVEN, BUT FIRST AID MAY STILL
BE RQUIRED IN CASE OF ACCIDENTAL EXPOSURE, INHALATION OR INGESTION
OF THIS CHEMICAL. IF IN DOUBT, GET MEDICAL ATTENTION PROPMPTLY!
INGESTIO N: RINSE MOUTH THOROUGHLY. ADMINISTER LARGE AMOUNTS OF
WATER. GET MEDICAL ATTENTION IF ANY DISCOMFORT CONTINUES. SKIN:
RINSE WITH WATER. EYES: MAKE SURE TO REMOVE ANY CONTACT LENSES FROM
THE EYES BEFO RE RINSING. PROMPLY WASH EYES WITH LOTS OF WATER
WHILE LIFTING THE EYE LIDS, CONTINUE TO RINSE FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION IF ANY DISCOMFORT CONTINUES.
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:THIS MATERIAL IS NOT FLAMMABLE. USE EXTINGUISHING
MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:NONE NOTED.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT CONTAIMINATE DRAINAGE OR WATERWAYS.
ABSORB SPILL WITH NON-REACTIVE ABSORBENT AND PLACE IN NON-REACTIVE
CONTAINERS FOR DISPOSAL. CONTAIN SPILL. USE LARGE QUANTITIES OF
WATER TO FLUSH SMALL SPILL S TO SANITARY SEWER IF LOCAL REGULATIONS
PERMIT. DO NOT FLUSH TO SEPTIC TANK.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID SPILLING, SKIN AND EYE CONTACT.
READ AND FOLLOW MANUFACTURER'S RECOMMENDATIONS. PROVIDE GOOD
VENTILATION. KEEP IN COOL, DRY, VENILATED STORAGE AND CLOSED
CONTAINERS. KEEP IN ORIGINAL CONTAINER.
Other Precautions:WASTE THAT CANNOT BE DISCHARGED TO SEWER MAY HAVE TO
BE HANDLED BY A LICENSED HAZARDOUS WASTE CONTRACTOR.AVOID SPILLING,
SKIN AND EYE CONTACT. READ AND FOLLOW MANUFACTURER'S
RECOMMENDATIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT RELEVANT.
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION.
MUST NOT BE HANDLED IN CONFINED SPACES WITHOUT ADEQUATE
VENTILATION. (SEE SUPPLEMENTAL DATA).
Protective Gloves:NEOPRENE, NITRILE, POLYETHYLENE BUTYL RUBBER. *(SEE
SUPPLEMENTAL DATA).
Eye Protection:WEAR APPROVED SAFETY GOGGLES.
Other Protective Equipment:PROVIDE EYEWASH STATION AND IT IS
RECOMMENDED THAT A SAFETY SHOWER IS ALSO AVAILABLE. WEAR
APPROPRIATE CLOTHING TO PREVENT ANY POSSIBILITY OF SKIN CONTACT.
Supplemental Safety and Health
GENERAL ROOM VENTILATION SHOULD PROVIDE FOR 10-15 ROOM AIR CHANGES PER
HOUR. *USE THIN COTTON GLOVES INSIDE THE RUBBER GLOVES IF ALLERGY
RISK.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:>37.8C, 100.F
Melt/Freeze Pt:<-17.6C, 0.F
Vapor Density:1.31
Spec Gravity:20
pH:7.1
Evaporation Rate & Reference:1 H2O (WATER)=1
Solubility in Water:SOLUBLE
Appearance and Odor:YELLOWISH LIQUID. WATER SOLUBLE. SLIGHT, AMMONIA
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTAT WITH OTHER PHOTOGRAPHIC SOLUTIONS AND/OR CLEANING
COMPOUNDS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT FOR PROLONGED PERIODS
OF TIME. AVOID CONTACT WITH ACIDS AND ALKALIS.
Hazardous Decomposition Products:IRRITATING GASES/VAPORS/FUMES OF:
AMMONIA OR AMINES. SULFUR DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT POLYMERIZE.
=================== Toxicological Information ===================
Toxicological Information:TOXIC DOSE-LD 50: AMMONIUM THIOSULPHATE 2890;
NITRILOTRIACETIC ACID 1100; ETHYLDIGLYCOL 5500. TOXICOLOGICAL
INFORMATION: THIS CHEMICAL FORMULATION HAS NOT BEEN TESTED FOR
HEALTH EFFECTS. EXPOSURE EFFE CTS LISTED ARE BASED ON EXISTING
HEALTH DATA FOR THE INDIVIDUAL COMPONENTS WHICH COMPRISE THE
MIXTURE.
===================== Ecological Information =====================
Ecological:LC 50, 96 HRS, FISH, MG/L: 200 AMMONIUM THIOSULPHATE;>1000
NITRILOTRIACETIC ACID. EC 50, 48 HRS, DAPHNIA, MG/L: >100
NITRILOTRIACETIC ACID. ECOLOGICAL INFORMATION: NOT REGARDED AS
DANGEROUS FOR THE EN VIRONMENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNUSED AND SPENT SOLUTIONS MAY BE ALLOWED TO BE
DISCHARGED TO SANITARY SEWER BY PERMIT IF ALLOWED BY LOCAL
REGULATIONS. CONSULT YOUR LOCL AUTHORITY FOR ADVICE. WASTE MAY HAVE
TO BE PRETREATED BEFORE D ISCHARGE. CONSULT LOCAL AUTHORITIES
BEFORE DISCHARGING ANY WASTE TO SEWER. DO NOT DISCHARGE TO SEPTI C
SYSTEM. (SEE OTHER PRECAUTIONS).
=================== MSDS Transport Information ===================
Transport Information:UN/NA NO.: 0. U.S. DOT HAZARD LABEL: NO DOT LABEL
REQUIEMENT NOTED. US.S DOT CLASS: NO CLASSIFICATION NOTED.
INFORMATION ON ROAD TRANSPROT: NOT CLASSIFIED FOR ROAD TRANSPORT.
INFORMATION ON SEA TRANSP ORT: NOT CLASSIFIED FOR SEA TRANSPORT.
INFORMATION ON AIR TRANSPORT: NOT CLASSIFIED FOR AIR TRANSPORT.
===================== Regulatory Information =====================
SARA Title III Information:NITRILOTRIACETIC ACID: NTP-CARCINOGEN
(DHHS). SARA SECTION 302, EXTREMELY HAZARDOUS SUBSTANCES. SARA
SECTION 313, TOXIC CHEMICALS. SARA TITLE III CONSOLIDATED CHERMICAL
LIST (302, CERCLA, 313, RCRA). IARC-ANIMAL CARCINOGEN. IARC-INT.
AGENCY FOR CANCER RESEARCH.
Federal Regulatory Information:TSCA: THE INGREDIENTS OF THIS PRODUCT
ARE ON THE TSCA INVENTORY.
State Regulatory Information:PROPROSISTION 65: THIS PRODUCT CONTAINS
THE FOLLOWING CHEMICAL(S) CONSIDERED BY THE STATE OF CALIFORNIA A
SAFE DRINGKIN WATER AND TOXIC ENFORCEMENT ACT OF 1986 AS CAUSING
CANCE OR REPRODUCTIVE TOXICIT Y, AND FOR WHICH WARNINGS ARE NOW
REQUIRED: NITRILOTRIACETIC ACID. FLORIDA HAZARDOUS SUBSTANCE LIST
MASSCHUESETTS EXTRAORDINARILY HAZARDOUS SUBSTANCES LIST
MASSACHUSETTS RIGHT-TO-KNOW . NEW JERSEY RIG HT-TO-KNOW. NU
ENVIRONMENTAL HAZARDOUS SUBSTANCES LIST NU SPECIAL HAZARDOUS
SUBSTANCES LIST PENNSYLV ANIA SPECIAL HAZARDOUS SUBSTANCE LIST.
PENNSYLVANIA RIGHT-TO-KNOW.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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