===================== Product Identification =====================
MSDS NAME:IP920327D22.15, P22 DEVELOPER-B
NIIN:01-313-1956
Status Code:A
MSDS Number: CLSJY
=== Responsible Party ===
Company:ILFORD IMAGING USA INC
Address:W 70 CENTURY RD
City:PARAMUS
State:NJ
ZIP:07652-1490
Country:US
Info Phone Num:201-265-6000 /FAX: 201-265-0894
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:10135-P22 DEVELOPER-B
Preparer's Name:DR. D. W. BUTCHER
Chemtrec Ind/Phone:(800)424-9300
CAGE:0LT87
=== Contractor Identification ===
Company:ILFORD IMAGING USA INC
Address:33 LEWIS RD
Box:City:BINGHAMTON
State:NY
ZIP:13905
Country:US
Phone:607-766-3153/ FAX 201-225-3514
CAGE:0LT87
============= Composition/Information on Ingredients =============
Name:1-PHENYL-4-METHYL-3-PYRAZOLIDINONE
CAS:2654-57-1
Fraction by Wt: 1-5%
Name:BENZOTRIAZOLE
CAS:95-14-7
Fraction by Wt: 0-1%
Name:STILBENE DISULFONATE
CAS:68155-70-4
Fraction by Wt: 1-5%
Name:ETHYLDIGLYCOL
CAS:111-90-0
Code:F
RTECS #:KK8750000
Fraction by Wt: 30-60%
Name:HYDROQUINONE
CAS:123-31-9
RTECS #:MX3500000
Fraction by Wt: 10-30%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
RISK OF SERIOUS DAMAGE TO EYES. MAY CAUSE SENSITISATION BY SKIN.
CARCINOGEN CATEGORY 3. MUTAGEN CATEGORY 3. INHALATION: MAY CAUSE
IRRITATION TO THE RESPIRATORY SYSTEM. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE DISCOMFORT IF SWALLOWED. SKIN: MAY CAUSE
SENSITISATION BY SKIN CONTACT. MAY CAUSE ALLERGIC CONTACT ECZEMA.
EYES: IRRITATION OF EYES AND MUCOUS MEMBRA NES. REPEATED EXPOSURE
MAY CAUSE CHRONIC EYE IRRITATION.
Explanation of Carcinogenicity:HYDROQUINONE: CARCINOGEN CATEGORY 3
MUTAGEN CATEGORY 3. ACGIH A3 IARC 3 IARC ANIMAL CARCINOGEN LIST.
IARC INT. AGENCY FOR RESEARCH CANCER. BENZOTRIAZOLE SUSPECT CANCER
HAZARD.
Effects of Overexposure:SEVERLY IRRITATING BY PROLONGED OR REPEATED
EXPOSURE. CAN CAUSE IRRITATION ECZEMA. CAN CAUSE CONTACT ALLERGY.
MAY CAUSE ALLERGY. MAY CAUSE HYPERSENSITIVITY. INHALATION: MAY
CAUSE IRRITATION TO THE RE SPIRATORY SYSTEM. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE DISCOMFORT IF SWALLOWED. SKIN: MAY CAUSE
SENSITISATION BY SKIN CONTACT. MAY CAUSE ALLERGIC CONTACT ECZEMA.
EYES: IRRITATION OF EYES AND MUC OUS MEMBRANES. REPEATED EXPOSURE
MAY CAUSE CHRONIC EYE IRRITATION.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING: SKIN
DISORDERS AND ALLERGIES.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE.
PROVIDE REST, WARMTH AND FRESH AIR. GET MEDICAL ATTENTION IF ANY
DISCOMFORT CONTINUES. INGESTION: DO NOT INDUCE VOMITING! REMOVE
VICTIM IMMEDI ATELY FROM SOURCE OF EXPOSURE. RINSE MOUTH
THOROUGHLY. GET MEDICAL ATTENTION IMMEDIATELY! IMMEDIATELY GIVE A
COUPLE GLASSES OF WATER, PROVIDED THE VICTIM IS FULLY CONSCIOUS.
SKIN: REMOVE AFFECTED PERS ON FROM SOURCE OF CONTAMINATION. REMOVE
CONTAMINATED CLOTHING. WASH THE SKIN WITH SOAP AND WATER. GET
MEDICAL ATTENTION IMMEDIATELY (SEE OTHER INFORMATION).
===================== Fire Fighting Measures =====================
Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:THIS MATERIAL IS NOT FLAMMABLE. USE EXTINGUISHING
MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS
NOTED.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT CONTAMINATE DRAINGAE OR WATERWAYS.
ABSORB SPILL WITH NON-REACTIVE ABSORBENT AND PLACE IN NON-REACTIVE
CONTAINERS FOR DISPOSAL. CONTAIN SPILL. USE LARGE QUANTITIES OF
WATER TO FLUSH SMALL SPILL S TO SANITARY SEWER IF LOCAL REGULATIONS
PERMIT. DO NOT FLUSH TO SEPTIC TANK.DO NOT LET WASHING DOWN WATER
CONTAMINATE PONDS OR WATERWAYS. INFORM AUTHORITIES IF LARGE AMOUNTS
ARE INVOLVED.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID SPILLING, SKIN AND EYE CONTACT.
READ AND FOLLOW MANUFACTURER'S RECOMMENDATIONS. PROVIDE GOOD
VENTILATION. KEEP IN COOL, DRY, VENILATED STORAGE AND CLOSED
CONTAINERS. KEEP IN ORIGINAL CONTAINER.
Other Precautions:DO NOT DISCHARGE TO SEPTIC SYSTEM. WASTE THAT CANNOT
BE DISCHARGE TO SEWER MAY HAVE TO BE HANDLED BY A LICENSED
HAZARDOUS WASTE CONTRACTOR.AVOID SPILLING, SKIN AND EYE CONTACT.
READ AND FOLLOW MANUFAC TURER'S RECOMMENDATIONS
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATORY PROTECTION MUST BE USED IF AIR
CONCENTRATION EXCEEDS ACCEPTABLE LEVEL. AN ACID GAS/ORGAINC VAPOR
CARTRIDGE SHOULD BE USED.
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION.
MUST NOT BE HANDLED IN CONFINED SPACES WITHOUT ADEQUATE
VENTILATION. (SEE SUPPLEMENTAL DATA).
Protective Gloves:NEOPRENE, NITRILE, POLYETHYLENE BUTYL RUBBER. *(SEE
SUPPLEMENTAL DATA).
Eye Protection:WEAR APPROVED SAFETY GOGGLES.
Other Protective Equipment:PROVIDE EYEWASH STATION AND IT IS
RECOMMENDED THAT A SAFETY SHOWER IS ALSO AVAILABLE. WEAR
APPROPRIATE CLOTHING TO PREVENT ANY POSSIBOILITY OF SKIN CONTACT.
Supplemental Safety and Health
GENERAL ROOM VENTILATION SHOULD PROVIDE FOR 10-15 ROOM AIR CHANGES PER
HOUR. *USE THIN COTTON GLOVES INSIDE THE RUBBER GLOVES IF ALLERGY
RISK.
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:>37.8C, 100.F
Melt/Freeze Pt:<-17.6C, 0.F
Vapor Density:1.05
Spec Gravity:20
pH:7
Evaporation Rate & Reference:1 H2O (WATER)=1
Solubility in Water:SOLUBLE IN WATER
Appearance and Odor:COLORLESS LIQUID. WATER SOLUBLE. SLIGHT SOLVENT
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTAT WITH OTHER PHOTOGRAPHIC SOLUTIONS AND/OR CLEANING
COMPOUNDS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT FOR PROLONGED PERIODS
OF TIME.
Hazardous Decomposition Products:NO SPECIFIC HAZARDOUS DECOPOSITION
PRODUCTS NOTED..
Conditions to Avoid Polymerization:WILL NOT POLYMERIZE.
=================== Toxicological Information ===================
Toxicological Information:TOXIC DOSE-LC 50: HYDROQUINONE 320; PHENIDONE
Z 512; BENZOTRIAZOLE 700 MG/KG (ORAL RAT). TOXICOLOGICAL
INFORMATION: THIS CHEMICAL FORMULATION HAS BNOT BEEN TESTED FOR
HEALTH EFFECTS. EXPOSURE EFFECTS LISTED ARE BASED ON EXISTING
HEALTH DATA FOR THE INDIVIDUAL COMPONENTS WHICH COMPRISE THE
MIXTURE.
===================== Ecological Information =====================
Ecological:LC 50, 96 HRS, FISH, MG/L; 0.1 HYDROQUINONE; 130
BENZOTRIAZOLE. EC 50, 48 HRS, DAPHNIA, MG/L; 20 BENZOTRIAZOLE. IC
50, 72 HRS, ALGAE, MG/L; 1.0 HYDROQUINONE; 15.4 BENSZOTRIAZOLE.
EXOLOGICAL INFORMATIO N: NOT REGARDED AS DANGEROUS FOR THE
ENVIRONMENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL AUTHORITY
REQUIRMENTS. UNUSED AND SPENT SOLUTIONS MAY BE ALLOWED TO BE
DISCHARGED TO SANITARY SEWER BY PERMIT IF ALLOWED BY LOCAL
REGULATIONS. CONSULT YOUR LOCAL AU THORITY FOR ADVICE. WASTE MAY
HAVE TO BE PRETREATED BEFORE DISCHARGE. CONSULT LOCAL AUTORITIES
BEFOR E DISCHARGING ANY WASTE TO SEWER.(SEE OTHER).
=================== MSDS Transport Information ===================
Transport Information:UN/NA NO.: 0, U.S. DOT HAZARD LABEL: NO DOT LABEL
REQUIREMENT NOTED. U.S. DOT CLASS: NO CLASSIFICATION NOTED.
INFORMATION ON ROAD TRANSPORT: NOT CLASSIFIED FOR ROAD TRANSPORT.
INFORMATION ON SEA TRANS PORT: NOT CLASSIFIED FOR SEA TRANSPORT.
INFORMATION ON IAR TRANSPORT: NOT CLASSIFIED FOR AIR TRANSPORT.
===================== Regulatory Information =====================
Federal Regulatory Information:TSCA: THE INGREDIENTS OF THIS PRODUCT
ARE ON THE TSCA INVENTORY. . BENZOTRIAZO 95-14-7, ETHYLDIGLYC
111-90-0, STILBENE DISU 68155-70-4, HYDROQUION 123-31-9,
1-PHENYL-4-ME 2654-57-1.CANADIAN WHMIS CLAS SIFICATION
State Regulatory Information:FLORIDA HAZARDOUS SUBSTANCE LIST
MASSACHUESETTS EXTRAORDINARILY HAZARDOUS SUBSTANCES LIST
MASSACHUSETTS RIGHT-TO-KNOW. NEW JERSY RIGHT-TO-KNOW. NJ
ENVIRONMENTAL HAZARDOUS SUBSTANCES LIST NJ SPECIAL HA ZARDOUS
SUBSTANCES LIST PENNSYLVANIA RIGHT-TO-KNOW.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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