===================== Product Identification =====================
MSDS NAME:070 ENDURA-SHIELD (GLOSS)
NIIN:00N010088
MSDS Number: BHNPC
=== Responsible Party ===
Company:TNEMEC COMPANY,INC
Address:123 WEST 23RD AVENUE
City:NORTH KANSAS CITY
State:MO
ZIP:64116-3064
Info Phone Num:816-474-3400
Emergency Phone Num:816-474-1425
CAGE:HO523
=== Contractor Identification ===
Company:TNEMEC COMPANY INC
Address:123 WEST 23RD AVENUE
Box:City:NORTH KANSAS CITY
State:MO
ZIP:64116-3064
Country:US
Phone:816-474-3400
CAGE:16031
Company:TNEMEC COMPANY,INC.
Address:123 WEST 23RD AVENUE
Box:City:NORTH KANSAS CITY
State:MO
ZIP:64116-3064
Phone:816-474-3400
CAGE:HO523
============= Composition/Information on Ingredients =============
Name:1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)
CAS:822-06-0
RTECS #:MO1740000
Fraction by Wt: 1.30%
Other REC Limits:N/K
ACGIH TLV:0.005 PPM; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 13.93%
Other REC Limits:N/K
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 13.77%
Other REC Limits:N/K
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:HEXAMETHYLENE DIISOCYANATE (HDI) POLYMER
CAS:28182-81-2
RTECS #:NQ9170000
Fraction by Wt: 75%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:VOLATILE ORGANIC COMPOUND:2.203 LBS/GAL.
RTECS #:9999999VO
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRLNG/RPTD SKIN CONT MAY CAUSE
ALLERGIC SKIN RESPONSES,POSS DERMAT.PRLNG/PRTD EXPOS TO ISOCYANATE
CONC >TLV MAY CAUSE PERM RESP/SKIN SENSIT.ONCE DIAGNOSED AS
ISOCYANATE SENSIT,PERMIT NO MORE EXPOS.RPT S ASSOC RPTD/PRLNG
OCCUPATIONAL SOLV EXPOS W/ PERM BRAIN/NERV SYS DMG.INTENTIONAL
MISUSE BY CONC/INHAL VAP MAY (SEE SUP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:REDNESS,TEARING,BLURRED VISION,SEV
IRRIT.SKIN:PRLNG/RPTD CONTACT MAY CAUSE MOD IRRIT,DRYING,DEFAT &
POSS DERMAT.INGEST:GI IRRIT,NAUS,VOMIT,DIARR,DEATH,ASPIR INTO LUNGS
WHICH CAN BE FATAL.INHAL:VA P/SPRAY MIST-NASAL/RESP IRRIT,ANESTH
EFTS,DIZZ,POSS UNCONSCIOUSNESS &
ASPHYXIATION,STUPOR,WEAKNESS,FATG,NAUSEA,HEADACHE.
Medical Cond Aggravated by Exposure:EXPOSURE TO ISOCYANATE PRODUCTS MAY
AGGRAVATE PERSONS WITH ASTHMATIC TYPE CONDITIONS,CHRONIC
BRONCHITIS,OTHER CHRONIC RESPIRATORY DISEASES,SKIN ECZEMA,OR SKIN
SENSITIZATION.
======================= First Aid Measures =======================
Eyes:FLUSH IMMED W/ LRG AMTS OF H*2O UNDER LOW PRESS FOR @
LEAST 15 MIN.CONSULT MD.SKIN:WASH W/ SOAP/WATER.REMOVE CONTAM
CLTHG.LAUNDER OR DISPOSE OF.CONSULT MD IF IRRIT
PERSISTS.INGEST:DRINK 1-2 GLASS ES OF H*2O TO DILUTE.DO NOT INDUCE
VOMIT.CONSULT MD OR POISON CONTROL CENTER IMMED.TREAT
SYMP.INHAL:REMOVE TO FRESH AIR.TREAT SYMP.IF BRTHG DIFFICULT GIVE
O*2,IF STOPPED GIVE ARTF RESP.CONSULT MD.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:91F,32.78C
Lower Limits:N/K
Upper Limits:1.00
Extinguishing Media:FOAM,CARBON DIOXIDE,DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP
.WATER MAY BE USE TO COOL UNRUPTURED CONTRS.USE APPROP EXTING
MEDIA.WATER MAY CAUSE VIOLENT (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:SM AMT HCN MAY EVOLVE UNDER FIRE
CONDTNS.KEEP FROM HEAT,OPEN FLAMES,SPARKS,STATIC CHARGES.DO NOT
APPLY TO HOT SURF DUE TO FIRE/EXPLO HAZ.CLOSED CONTRS (SEE SUP)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNIT SOURCES.COLLECT W/
INERT,ABSORB MATL FOR DISP.USE NON-SPARKING TOOLS,PROT
GLOVES,GOGG,CLTHG,ADEQ VENT.AVOID BRTHG VAPS,USE RESP PROT.TRANSFER
ABSORB MATL TO CONTR.PUT CONTR IN SAFE PL ACE COVERED LOOSELY UNTIL
CO*2 FINISHESEVOLVING.
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY AREA.KEEP CLOSURES TIGHT
& UPRIGHT TO PREV LEAKS.DO NOT STORE IN HIGH TEMP AREAS OR NEAR
FIRE/OPEN FLAME.USE APPROVED GROUNDING PROCS.
Other Precautions:PREV PRLNG BRTHG OF VAP/SPRAY MIST.PREV CONT W/
SKIN/EYES.DO NOT TAKE INTERNALLY.KEEP OUT OF REACH OF CHILDREN.DO
NOT REUSE/ALTER CONTRS W/O PROPER INDUSTRIAL CLEANING.DO NOT
WELD/FLAME CUT EMPTY,UNCL EANED CONTRS DUE TO FIRE/EXPLO POTNTL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:WEAR CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR CHEMICAL RESISTANT COVERALLS OR APRON
TO PROTECT AGAINST SKIN AND CLOTHING CONTAMINATION.
Work Hygienic Practices:WASH HANDS AND OTHER CONTAMINATED SKIN AREAS
WITH SOAP AND WARM WATER BEFORE EATING.
Supplemental Safety and Health
% SOLIDS BY WEIGHT:75.006.EXPLO HAZ:MAY EXPLODE FROM PRESS BUILDUP IN
HIGH HEAT.SOLV VAPS ARE HEAVIER THAN AIR & MAY TRAVEL TO DISTANT
INGIT SOURCE & FLASH BACK.HAZ DECOMP PROD:CO,CO*2,HYDROCARBON FRA
GMENTS,NO,NO*2,POSS HCN.FIRE FIGHT PROC:FROTHING IF SPRAYED INTO
CONTRS OF BURNIING LIQ.HLTH HAZ:BE HARMFUL OR FATAL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:244-288F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:>1 (AIR=1)
Spec Gravity:1.06 (WATER=1)
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:N/K
Appearance and Odor:LIQUID
Percent Volatiles by Volume:29.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER,ALCOHOLS,AMINES,STRONG BASES,METAL COMPONENTS,SURFACE ACTIVE
MATERIALS.
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAMES,STATIC
CHARGES.AMINE COMPOUNDS UNDER UNCONTROLLED CONDITIONS.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON
DIOXIDE,HYDROCARBON FRAGMENTS,NITROGEN MONOXIDE,NITROGEN
DIOXIDE,POSS HCN TRACES IN FIRE CNDTNS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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