===================== Product Identification =====================
MSDS NAME:FORE FUNGICIDE,62440
NIIN:00N010725
MSDS Number: BHVHT
=== Responsible Party ===
Company:ROHM & HAAS CO.(CORP PROD INTEGRITY DEPARTMENT)
Address:INDEPENDENCE MALL WEST
City:PHILADELPHIA
State:PA
ZIP:19105
Info Phone Num:215-592-3000
Emergency Phone Num:215-592-3000;800-424-9300 CHEMTREC
CAGE:HO593
=== Contractor Identification ===
Company:ROHM & HAAS CO.(CORP PROD INTEGRITY DEPARTMENT)
Address:INDEPENDENCE MALL WEST
Box:City:PHILADELPHIA
State:PA
ZIP:19105
Phone:215-592-3000
CAGE:HO593
Company:ROHM AND HAAS CO
Address:100 INDEPENDENCE MALL WEST
Box:City:PHILADELPHIA
State:PA
ZIP:19106-2399
Country:US
Phone:215-592-2521/215-592-3000
CAGE:77902
============= Composition/Information on Ingredients =============
Name:MANCOZEB
CAS:8018-01-7
RTECS #:ZB3200000
Fraction by Wt: 80%
Other REC Limits:1 MG/M3
OSHA PEL:N/K
ACGIH TLV:N/K
Name:RELATED REACTION PRODUCTS
Fraction by Wt: 20%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:PHTHALOCYANINE PIGMENT
RTECS #:BD1430000
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT >5 G/KG;(SEE SUPP)
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:REPEATED OR PROLONGED CONTACT CAN
CAUSE DERMATITIS.DELAYED EFFECTS:DITHANE AT HIGH LEVEL (3000 TIMES
TWA) HAS CAUSED BIRTH DEFECTS IN TEST ANIMALS.ETHYLENETHIOUREA
(ETU),A TRACE CONTAMINANT & BREAKDOW N PRODUCT OF DITHANE HAS
CAUSED THYROIDEFFECTS,TUMORS,& BIRTH DEFECTS IN LABORATORY ANIMALS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:MODERATELY IRRITATING.SKIN:REPEATED OR
PROLONGED CONTACT CAN CAUSE IRRITATION OR DERMATITIS.INGESTION:N/K
.INHALATION:DUST CAN IRRITATE THE NOSE & THROAT.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
Eyes:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES.CONSULT A PHYSICIAN IF IRRITATION PERSISTS.SKIN:WASH
AFFECTED AREAS WITH SOAP & WATER.INGESTION:IF SWALLOWED DILUTE BY
GIVING 2 GLASSES O F WATER TO DRINK & CALL A PHYSICIAN.NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.INHALATION:MOVE SUBJECT
TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:146C,295F
Upper Limits:0.13 MG/M3
Extinguishing Media:CO*2,DRY CHEMICAL,WATER SPRAY,WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .USE WATER SPRAY TO COOL CONTAINERS.RUN-OFF
SHOULD BE CONTAINED.
Unusual Fire/Explosion Hazard:FIRE PRODUCES TOXIC & FLAM PROD:HYDROGEN
SULFIDE,CARBON DISULFIDE,& OXIDES OF SULFUR,NITROGEN,CARBON.DUST
CAN EXPLODE IF IGNITED.REMAIN UPWIND.AVOID SMOKE.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP/SHOVEL MATL INTO CONTR FOR
RECOVERY,DISPOSAL.KEEP DUST TO A MIN.FLUSH AREA W/ WATER TO
CONTAMINATED (CHEM) SEWER.KEEP SPILLS,CLEANING RUNOFF OUT OF
MUNICIPAL SEWERS,OPEN BODIES OF WATER.EBDC'S A RE SOLUBLE IN
ALKALIS,BACTERIOSTATIC,AND (SUP DA)
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE INDOORS <49C,120F IN
DRY,SHADED,WELL VENT AREA.STORE BAGS ON PALLETS W/ DENSITY <2
M3.PROVIDE ACCESS AISLES BETWEEN PALLET ROWS.
Other Precautions:DO NOT ALLOW TO GET WET,OVERHEATED AS DECOMP,IMPAIRED
ACTIVITY,FIRE MAY RESULT.PREVENT FIRE W/ PLENTY OF VENT.CHECK BAGS
FOR DECOMP SIGNS (FOUL ODOR & WARM BAGS).IF DETECTED,IMMED REMOVE
TO OPEN AREA FOR DISPOSAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW EXPOSURE OF CONCERN .
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH FACILITY,EMERGENCY SHOWER.WORKERS
SHOULD BE FURNISHED CLEAN OUTER CLOTHING & REQUIRED TO SHOWER AT
END OF SHIFT.
Work Hygienic Practices:REMOVE CONTAM CLOTHES PROMPTLY,WASH SKIN W/
SOAP & WATER.THOROUGHLY LAUNDER CLOTHES BEFORE REUSE;DO NOT TAKE
HOME.
Supplemental Safety and Health
MP:192-204C DECOMPOSES.VOLATILE BY WT:1% WATER.AUTOIGNIT TEMP DUST
CLOUD:310C,590F.LD50-LC50 MIX:LD50 DERMAL RABBIT >5 G/KG;LC50 INHAL
RAT >5.14 MG/L/4 HOURS.SPILL PROC:BIODEGRADEABLE AT LOW CONCENTRA
TIONS.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:SEE SUPP
Decomp Temp:Decomp Text:N/K
Spec Gravity:0.35-0.5,H*2O=1
Solubility in Water:DISPERSIBLE
Appearance and Odor:BLUE-GREEN POWDER;MUSTY ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS,ACIDS.
Stability Condition to Avoid:KEEP DRY AND AVOID EXCESSIVE HEAT
(49C,120F) AND IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN SULFIDE,CARBON DISULFIDE,&
OXIDES OF CARBON,NITROGEN,SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE
& LOCAL REGS .HAZ WASTE WHEN DISCARDED.RCRA #U-114;RQ 5000 LBS
(40CFR PART302).INCIN IN APPRVD EQUIP.CONTR DISPOSAL:TRIPLE RINSE
(OR EQUIVALENT),P UNCTURE & DISPOSE ACCORDING TO REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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