Page 1/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
* 1 Identification of substance:
路 Product details: Coloured Standard Solution for calibration purposes
路 Product name: Reference Standard Chlorine 4 mg/l
路 Catalog number: 205697, 215697, 205600
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8a-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
* 2 Composition/Data on components:
路 Description: Solvent mixture.
路 Dangerous components:
CAS: 67-63-0 propan-2-ol @ Xi, @ F; R 11-36-67 90-100%
G C
EINECS: 200-661-7
EC Number: 603-117-00-0
CAS: 67-68-5 dimethyl sulfoxide 2.5-5%
EINECS: 200-664-3
路 Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
路 Hazard designation:
G@
@C Xi Irritant
F Highly flammable
路 Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the
EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
Vapours of the product are heavier than air and may accumulate on the ground, in mines, drains or cellars with higher
concentration.
Has a narcotizing effect.
R 11 Highly flammable.
R 36 Irritating to eyes.
R 67 Vapours may cause drowsiness and dizziness.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
GB
(Contd. on page 2)
DR
Page 2/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
Product name: Reference Standard Chlorine 4 mg/l
(Contd. of page 1)
* 4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air and call for doctor for safety reasons.
路 After skin contact Instantly wash with water and soap and rinse thoroughly.
路 After eye contact
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
路 After swallowing
Seek medical treatment.
Rinse out mouth and then drink plenty of water.
路 The following symptoms may occur:
after inhalation:
irritation
dazed
coughing
dizziness
after swallowing:
unconsciousness
breathing difficulty
headache
* 5 Fire fighting measures
路 Suitable extinguishing agents
Alcohol-resistant foam
Carbon dioxide
路 Special hazards caused by the material, its products of combustion or resulting gases:
Can form explosive gas-air mixtures.
Formation of toxic gases is possible during heating or in case of fire.
路 Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
路 Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter drains.
* 6 Accidental release measures
路 Person-related safety precautions:
Put on breathing apparatus.
Wear protective equipment. Keep unprotected persons away.
路 Measures for environmental protection:
Do not allow product to reach sewage system or water bodies.
Prevent material from reaching sewage system, holes and cellars.
Damp down gases/fumes/haze with water spray jet.
路 Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, universal binders).
Ensure adequate ventilation.
Dispose of contaminated material as waste according to item 13.
* 7 Handling and storage
路 Handling
路 Information for safe handling: Use only in well ventilated areas.
路 Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
(Contd. on page 3)
GB
DR
Page 3/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
Product name: Reference Standard Chlorine 4 mg/l
(Contd. of page 2)
Protect from heat.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
路 Storage
路 Requirements to be met by storerooms and containers:
Store in cool location.
Do not use light alloy containers.
路 Further information about storage conditions:
Keep container tightly sealed.
Store under dry conditions.
Protect from heat and direct sunlight.
Protect from humidity and keep away from water.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
67-63-0 propan-2-ol
WEL (Great Britain) Short-term value: 1250 mg/m鲁, 500 ppm
Long-term value: 999 mg/m鲁, 400 ppm
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
Apply solvent resistant clothing before beginning work.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter A
路 Protection of hands:
Solvent resistant gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
nitrile rubber, NBR
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Value for the permeation: Level 鈮? 6 (480 min)
路 Eye protection: Tightly sealed safety glasses.
路 Body protection: Solvent resistant protective clothing
* 9 Physical and chemical properties:
Fluid
路 Form:
Pink
路 Colour:
Alcohol-like
路 Odour:
路 Melting point/Melting range: -89.5掳C
(Contd. on page 4)
GB
DR
Page 4/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
Product name: Reference Standard Chlorine 4 mg/l
(Contd. of page 3)
82掳C
路 Boiling point/Boiling range:
13掳C
路 Flash point:
Product is not explosive. However, formation of explosive air/steam mixtures is possible.
路 Danger of explosion:
路 Critical values for explosion:
2 Vol %
Lower:
12 Vol %
Upper:
43 hPa
路 Vapour pressure at 20掳C:
0.785 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
1.000 g/l
Water at 20掳C:
5.2
路 pH-value at 20掳C:
路 Solvent content:
< 100 %
Organic solvents:
< 0.5 %
路 Solids content:
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
路 Materials to be avoided:
alkali metals
acids
oxidizing agents
路 Dangerous reactions
Forms peroxides
Forms explosive gas mixture with air
路 Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
see chapter 5
* 11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
67-63-0 propan-2-ol
Oral LD50 4570 mg/kg (rat)
LDLo 3570 mg/kg (human)
Dermal LD50 12800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
67-68-5 dimethyl sulfoxide
Oral LD50 14500 mg/kg (rat)
Dermal LD50 40000 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Irritant effect.
路 Sensitization: No sensitizing effect known.
路 Additional toxicological information:
Vapours have anaesthetic effect.
(Contd. on page 5)
GB
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
Product name: Reference Standard Chlorine 4 mg/l
(Contd. of page 4)
In addition to local irritant manifestations, there is a narcotic effect when inhaling high concentrations, with the danger of
central respiratory arrest.
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and headache, dizziness, etc.
Danger by skin resorption.
* 12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information:
Quantitative data on the ecological effect of this product are not available.
CAS 67-63-0: 95% / 21 d (MERCK OECD Screening Test)
3.1 % / 14 d
路 Behaviour in environmental systems:
67-63-0 propan-2-ol
log P(o/w) 0.05 (.)
67-68-5 dimethyl sulfoxide
log P(o/w) - 1.35 (.)
路 Mobility and bioaccumulation potential: Does not accumulate in organisms
路 Ecotoxical effects:
路 Acquatic toxicity:
67-63-0 propan-2-ol
EC50 13299 mg/l/48h (Daphnia magna)
LC50 9640 mg/l/96h (Pimephales promelas)
67-68-5 dimethyl sulfoxide
LC50 33500 mg/l/48h (Lepomis macrochirus)
路 Remark:
路 Algeal toxicity: CAS-No. 67-63-0: Desmodesmus subspicatus IC50: > 1000 mg/l/72 h
路 Bacterial toxicity: CAS-No. 67-63-0: Photobacterium phosphoreum EC50: 22000 mg/l/15 min Microtox-Test MERCK
路 Protozoa: CAS-No. 67-63-0: Entosiphon sulcatum EC5:4930 mg/l/72 h
路 General notes:
Water hazard class 1 (German Regulation) (Self-assessment acc. VwVwS Annex 4): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
* 13 Disposal considerations
路 Product:
路 Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
路 European waste catalogue
14 06 03 other solvents and solvent mixtures
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
GB
(Contd. on page 6)
DR
Page 6/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
Product name: Reference Standard Chlorine 4 mg/l
(Contd. of page 5)
* 14 Transport information
路 Land transport ADR/RID (cross-border)
x
g
c
路 ADR/RID-GGVS/E Class: 3 (F1) Flammable liquids.
33
路 Kemler Number:
1219
路 UN-Number:
II
路 Packaging group:
3
路 Label
1219 ISOPROPANOL (ISOPROPYL ALCOHOL)
路 Designation of goods:
路 Maritime transport IMDG:
g
x
c
3
路 IMDG Class:
1219
路 UN Number:
3
路 Label
II
路 Packaging group:
F-E,S-D
路 EMS Number:
No
路 Marine pollutant:
ISOPROPANOL (ISOPROPYL ALCOHOL)
路 Correct technical name:
路 Air transport ICAO-TI and IATA-DGR:
g
c
x
3
路 ICAO/IATA Class:
1219
路 UN/ID Number:
3
路 Label
II
路 Packaging group:
ISOPROPANOL (ISOPROPYL ALCOHOL)
路 Correct technical name:
* 15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xi Irritant
F Highly flammable
路 Risk phrases:
11 Highly flammable.
36 Irritating to eyes.
67 Vapours may cause drowsiness and dizziness.
路 Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe fumes/aerosol.
24/25 Avoid contact with skin and eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
60 This material and its container must be disposed of as hazardous waste.
(Contd. on page 7)
GB
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 23.11.2005 Reviewed on 23.11.2005
Product name: Reference Standard Chlorine 4 mg/l
(Contd. of page 6)
路 National regulations
路 Information about limitation of use: Employment restrictions concerning young persons must be observed.
路 VOC-value EC: 789.2 g/l
* 16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
11 Highly flammable.
36 Irritating to eyes.
67 Vapours may cause drowsiness and dizziness.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
GB
DR
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