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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : BUEHLER PLASTIC LIQUID& KIT, VARIDUR LIQUID & KIT
IDENTIFICATION NUMBER: 20-3550, 20-3554, 20-3570, 20-3574, 20-3578
PRODUCT USE/CLASS : Acrylic
SUPPLIER:
Buehler, Ltd.
41 Waukegan Road
Lake Bluff, IL 60044
EMERGENCY: 800-424-9300
INFORMATION: 847-295-6500
PREPARER: Technical Department, PHONE: 847-295-6500,
PREPARE DATE: 05/22/06; 22 May 06
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER WT/WT%
---------------------------------------------------------------------------
01 Ethyl-2-cyano-3,3-diphenyl acrylate 5232-99-5 1.0-5.0
02 Methyl methacrylate 80-62-6 60.0-100.0
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 N.E. N.E. N.E. N.E. 10 mg/m3 NO
02 100 ppm N.E. 100 ppm N.E. N.E. NO
(See Section 16 for abbreviation legend)
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: Harmful if inhaled or swallowed. Causes skin and eye irritation.
Inhalation of vapors may cause respiratory irritation. Potential skin sensitizer.
ACUTE EFFECTS - EYE CONTACT: Moderately irritating to the eyes.
ACUTE EFFECTS - SKIN CONTACT: Contact causes skin irritation. Repeated orprolonged
overexposure may cause allergic response.
ACUTE EFFECTS - INHALATION: May cause headaches and dizziness. High vapor
concentrations are irritating to the eyes, nose, throat and lungs.
ACUTE EFFECTS - INGESTION: This material may be harmful or fatal if swallowed.
Irritating to mouth, throat and stomach, with nausea.
Ingestion of significant amounts may cause kidney damage.
CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological
disorders may be aggravated by exposure to hazardous components.
OTHER INFORMATION: *Overexposure to hazardous components may aggravate
preexisting skin, lung, or kidney disorders. *Repeated and prolonged
overexposure may cause damage to the liver or kidneys.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT,
Continued on Page 2)
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9107495
Product: 20-3554, 20-3550,20-3572,20-3570,20-3576
Preparation Date: 05/22/06; 22 May 06 Page 2
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and
water. Get medical attention.
INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention.
INGESTION: If swallowed, do NOT induce vomiting. Give victim a glass of
water or milk. Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
NOTES TO PHYSICIAN: Not Applicable.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 50 F LOWER EXPLOSIVE LIMIT: 2.1 %
(TAGLIABUE CLOSED CUP) UPPER EXPLOSIVE LIMIT: 12.5 %
AUTOIGNITION TEMPERATURE: No data
EXTINGUISHING MEDIA:ALCOHOL FOAM,CO2,DRY CHEMICAL,FOAM,WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or
explode (due to pressure build-up) when exposed to extreme heat. Vapors
are heavier than air, and may travel along the ground to be reignited at
locations distant from the source; flashback of flame may occur. Store
full and empty containers away from heat, sparks, flame, and other sources
of ignition. Observe all labeled precautions until containers are cleaned
and/or reconditioned. Irritating and/or toxic gases or fumes may be
generated by thermal decomposition or combustion.
SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained
breathing apparatus and full protective clothing. Use water to cool
exposed containers. Water stream directed into fire may cause frothing
with subsequent spread of flame.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove sources
of ignition. Keep away from drains and sewers. Use non-sparking tools.
Wear appropriate protective equipment during cleanup. Absorb with
inert material, such as clay. Sweep or shovel into loosely-covered waste
container and remove to appropriate waste area. Dispose of in accordance
with federal, state, and local regulations.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING: Use with adequate ventilation. Follow all MSDS/label
precautions even after container is emptied because it may retain product
residues. Ground and bond containers when transferring material. Avoid
contact with eyes, skin, and clothing. FOR INDUSTRIAL USE ONLY.
Continued on Page 3)
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9107495
Product: 20-3554, 20-3550,20-3572,20-3570,20-3576
Preparation Date: 05/22/06; 22 May 06 Page 3
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| SECTION 7 - HANDLING AND STORAGE |
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STORAGE: Keep away from heat, sparks and flame. Store in a cool, dry
area away from heat and direct sunlight. Keep container closed when not
in use.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Local exhaust as needed to control vapor or dust
levels to below lowest component TLV.
RESPIRATORY PROTECTION: If TLV/PEL is exceeded, if use is performed in a
poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved
vapor cartridge respirator in accordance with applicable health and safety
regulations and manufacturer's recommendations.
SKIN PROTECTION: Clean clothing to cover skin. PVA gloves.
EYE PROTECTION: Chemical splash goggles.
OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.
HYGIENIC PRACTICES: Follow good general industrial safety practices during
use. Do not smoke or eat during use. DO NOT reuse empty containers
without commercial clean or recondition.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 214 - 214 F VAPOR DENSITY : Is heavier than air
ODOR : sweet sharp ODOR THRESHOLD : < 1 ppm
APPEARANCE : Clear EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Insoluble Acetate
FREEZE POINT : No data SPECIFIC GRAVITY: 0.939
VAPOR PRESSURE : 50mmHg @30degC pH @ 0.0 % : N/A
PHYSICAL STATE : Liquid VISCOSITY : Low
COEFFICIENT OF WATER/OIL DISTRIBUTION: No data
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Heat. Direct sunlight.
INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants.
Peroxides, surface active compounds, under uncontrolled conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Aromatic and
aliphatic hydrocarbons.
HAZARDOUS POLYMERIZATION: Could occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
Ethyl-2-cyano-3,3-diphenyl acrylate No information No information
Methyl methacrylate Oral-rat=8.4 g/kg Not Applicable
Continued on Page 4)
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9107495
Product: 20-3554, 20-3550,20-3572,20-3570,20-3576
Preparation Date: 05/22/06; 22 May 06 Page 4
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| SECTION 12 - ECOLOGICAL INFORMATION |
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ECOLOGICAL TEST DATA: Not Available
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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DISPOSAL METHOD: Review all current federal, state, and local regulations
regarding health and disposal for appropriate disposal procedures.
Incineration preferred. Product is considered a hazardous waste under
Federal RCRA regulations if disposed of 鈥渁s sold.鈥? Cured kit is inert and
non-hazardous and may be disposed of in landfill if regulations permit.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Resin solution
DOT TECHNICAL NAME: N/A
DOT HAZARD CLASS: 3 HAZARD SUBCLASS: N/A
DOT UN/NA NUMBER: UN1866 PACKING GROUP: II RESP. GUIDE PAGE: 126
INTERNATIONAL SHIPPING NAME: Resin solution
INTERNATIONAL ID NUMBER: UN1866
IMDG CLASS (1酶,2酶): 3.3, none IMDG PAGE NUMBER: II
IMDG EMS: 305 IATA CLASS (1酶,2酶): 3, none
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| SECTION 15 - REGULATORY INFORMATION |
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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed, and is considered, under applicable
definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD FIRE HAZARD REACTION HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 and 40 CFR part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
The chemical substances in this product are on the TSCA Section 8
Inventory.
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No components found.
Continued on Page 5)
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9107495
Product: 20-3554, 20-3550,20-3572,20-3570,20-3576
Preparation Date: 05/22/06; 22 May 06 Page 5
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| SECTION 15 - REGULATORY INFORMATION |
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U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
CALIFORNIA PROPOSITION 65:
No Proposition 65 chemicals known to exist in this product.
VOLATILE ORGANIC COMPOUNDS (VOCS): >90% by weight
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: D2B, B2
COMPONENT RCRA CLASSIFICATIONS: Ignitable. Reactive
COMPONENT RCRA CODES: D001, U162
CERCLA RQ VALUE (MINIMUM): 100
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 3 REACTIVITY: 1
PREVIOUS MSDS REVISION DATE: 12/07/99
REASON FOR REVISION: revised Section(s): 3,6,9,14
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
ABBREVIATIONS: ACGIH = American Conference of Governmental Industrial
Hygienists; OSHA = US Occupational Health and Safety Administration; UK =
United Kingdom; TLV-TWA = Threshold Limit Value-Time Weighted Average (8
hrs); STEL = Short-Term Exposure Limit (15 min); C = Ceiling Value; PEL =
Permissible Exposure Limit
DISCLAIMER: To the best of our knowledge, the information contained in
this MSDS is accurate or is obtained from sources believed to be accurate.
However, no liability, expressed or implied, is assumed for the accuracy or
completeness of the information contained herein. Buyer assumes liability
in its use of the material.
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9107495
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