Search    ENTER KEYWORD
MSDS Material Safety Data Sheet
CAS

65997-18-4
7681-49-4

File Name: dentsply_com---Principlemsds.asp
                       MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information

PRINCIPLE鈩? Adhesive Ionomer Cement Powder
1.1 Product Trade Name:
1.2 Part (Item) Number: 674100-674150 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963 鈥? 0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 02/11/98 Date Revised: 02/02/01

SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Strontium aluminum fluorosilicate glass N. E. N. E. 65997-18-4 > 90 %
Sodium Fluoride N. E. N. E. 7681-49-4 <5%

SECTION III - Physical/Chemical Characteristics
3.6 Specific Gravity: >1.0 g/cm3
3.1 Boiling point: N. A.
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. A.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Not Soluble
3.5 Appearance and odor:Off white powder with characteristic odor.

SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. A.
4.2 Flammability (explosive limits): LEL: N.A. UEL: N.A.
4.3 Extinguishing media: N. A.
4.4 Special fire fighting procedures: N. A.
4.5 Unusual fire and explosion hazards: N. A.

SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Heat greater than 50掳C(122掳F).
5.3 Incompatibility (materials to avoid): Aqueous polycarboxylic acid.
5.4 Hazardous decomposition or byproducts: N. E.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): None

SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: No Skin?: No Ingestion?: Possible
6.2 Health hazards (acute and chronic):Powder is a heavy dust. Inhalation of material is not likely. May cause drying of the
skin.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated?: No
6.4 Signs and symptoms of exposure: Could cause mechanic irritation to the eye as any nuisance dust.
6.5 Medical conditions generally
aggravated by exposure: Open wounds or sores of the skin.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes and call
physician. Skin: Wash area with mild soap and water. Call physician if irritation
persists.
SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled:Spray powder with water to minimize dusting, and sweep up. Place in an appropriately
marked container for disposal.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local regulations.
7.3 Precautions to be taken in handling
and storage: Store at ambient temperatures, away from heat.
7.4 Other precautions: Observe normal warehouse handling procedures. Handling of this product should be by
trained dental healthcare professionals only.

SECTION VIII - Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product. In excessive quantities
treat as a nuisance dust.
8.2 Ventilation: Local exhaust is recommended.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Close fitting protective goggles.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Handling of this product
should be by trained dental healthcare professionals only.



NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA - National Fire Protection Association
Flammability 0 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information

PRINCIPLE庐 Adhesive Ionomer Cement Liquid
1.1 Product Trade Name:
1.2 Part (Item) Number: 674100 鈥? 674150 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information:(302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 2/11/98 Date Revised: 02/02/01

SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Dimethacrylate resin monomer N. E. N. E. 1565-94-2 & > than 70 %
7732-18-5 & 868-77-9
Acrylic monomer N. E. N. E. 87699-25-0 < than 15 %
Polymerizeable carboxylic acid dimethacrylate N. E. N. E. 159002-30-9 < than 15 %

SECTION III - Physical/Chemical Characteristics
3.6 Specific Gravity: >1.0 g/cm3
3.1 Boiling point: N. A.
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. A.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Slightly Soluble
3.5 Appearance and odor:Low viscosity, light yellow liquid with faint acidic odor.

SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. E.
4.2 Flammability (explosive limits): LEL: N.E. UEL: N.E.
4.3 Extinguishing media: Sand, foam, carbon dioxide, or dry chemical.
4.4 Special fire fighting procedures: Wear MSHA/NIOSH approved or equivalent, pressure demand self-contained
breathing apparatus. Fire fighters should wear full protective clothing including a
self-contained breathing apparatus.
4.5 Unusual fire and explosion hazards: During a fire, irritating gasses from the decomposition of the methacrylate monomers
may be present.

SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Exposure to strong oxidants, heat and light. Store at room temperature.
5.3 Incompatibility (materials to avoid): Peroxides.
5.4 Hazardous decomposition or byproducts: Acid fumes, carbon monoxide and/or carbon dioxide.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): Exposure to intense visible light, peroxides, or prolonged storage above 38掳C
(100掳F)
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Possible Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic): May cause eye irritation and possible corneal damage. Individuals susceptible to
methacrylates may develop allergic response. Ingestion may cause local irritation to
soft tissue.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated?: No
6.4 Signs and symptoms of exposure: Irritation and possible corneal damage. Dermal irritation or possible allergic response
including nausea. Redness or irritation of eyes or skin.
6.5 Medical conditions generally
aggravated by exposure: Known sensitivity to methacrylates. Open wounds or sores of the skin.
6.6 Emergency first aid procedures: In case of eye contact, flush with flowing water for 15 minutes and call physician.
Skin: Flush with flowing water for 15 minutes, then wash area with mild soap and
water. Call physician.

SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled:Eliminate ignition sources. Dike and absorb with inert materials (sand, soda ash, vermiculite)
and transfer to an appropriately marked container.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local regulations.
7.3 Precautions to be taken
in handling and storage: Store at ambient temperature out of direct sunlight and heat. Keep away from flame and sparks.
7.4 Other precautions: Store away from food and beverages. Observe normal warehouse handling procedures.
Handling of this product should be by trained dental healthcare professionals only.

SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product.
8.2 Ventilation: Local exhaust is recommended.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Close fitting protective goggles.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Handling of this product
should be by trained dental healthcare professionals only.



NFPA HAZARD
CLASSIFICATIONS
Health 1 NFPA 鈥? National Fire Protection Association
Flammability 1 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard COR

574898 (R-02/02/01)

Search    ENTER KEYWORD
ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
NAMECAS
country-vet_com---346206CV.asp 476-86-8 136-45-8 67-63-0 113-48-4 9016-45-9 51-03-6 8003-34-7 532-32-1
crcind_com_au---MSDS.asp 8006-61-9 60-29-7 64-17-5 124-38-9
crsonesource_com---301311.asp 10-16-0 6834-92-0 2893-78-9 497-19-8 7758-29-4
csp_co_kr---MSDS-CSPE-5927_SEA_GRANDPRIX_CF-10_M.asp 1314-13-2 1309-37-1 13463-67-7 13463-41-7 971-66-4 1330-20-7 100-41-4 64742-94-5 71-36-3 107-98-2
csp_co_kr---MSDS-CSP-5917D__SEA_GRANDPRIX_CF-ACE_.asp N/A
ctint_org---humate_msds.asp 7647-14-5 68-04-2 56-40-6 7732-18-5
culligancorp_com---BIO_909MSDS.asp 7647-15-6
culligancorp_com---BWT_610MSDS.asp 100-37-8
daetwyler_com---15670_e_mdc_cupro_ballard.asp 59-50-7 22-41-4
daetwyler_com---165789_e_mdc_lp_brightener.asp 7681-57-4 123-11-5
daicel_co_jp---1_apd.asp 616-30-8 534-03-2
daicel_co_jp---aly.asp 107-18-6
daicel_co_jp---mapd.asp 40137-22-2
daicel_co_jp---pal.asp 123-63-7 75-07-0
daicel_co_jp---pmda.asp 89-32-7
daigger_com---EF5676.asp 64-17-5 68458-88-8 24634-61-5 8001-54-5 5949-29-1 7732-18-5
dakotagas_com---taroilmsds.asp 7732-18-5 67-64-1 78-93-3 111-84-2 124-18-5 1120-21-4 112-40-3 629-50-5 629-59-4 629-62-9 544-76-3 629-78-7 593-45-3 112-95-8 629-94-7 629-97-0 638-67-5 95-13-6 6351-10-6 108-95-2 108-39-4 106-44-5 95-48-7 108-68-9 105-67-9 95-87-4
davidson_com_au---CSM-2_DEGREASER.asp 106-94-5 106-88-7 124-38-9
davidson_com_au---M-BOND-AE-RESIN.asp 25068-38-6 122-60-1 108-46-3 106-89-8
davidson_com_au---M-BOND-CURING-AGENT-600610.asp 109-99-9 89-32-7 89-05-4
dawginc_com---neu211-212-msds.asp 57-55-6 67-63-0 12125-02-9 10025-77-1 7758-98-7
daycon_com---1746-tech.asp N/A
dead-planet_net---phosphorusoxychloride.asp 10025-87-3
deep-software_com---Deep_Log_Analyzer_Documentation.asp N/A
deftfinishes_com---Clear_Wood_Finish_Gloss.asp 8052-41-3 97-85-8 64742-89-8 110-43-0 111-76-2 9004-70-0 71-36-3 1330-20-7 67-63-0 112-07-2 100-41-4 78-83-1
degussa-aj_com---MSDS_sps.asp 7775-27-1
dels_nas_edu---Toxicity_Testing_final.asp N/A
delta-education_com---020-5567.asp 76-59-5 1310-73-2 7732-18-5
dentsply_com---Principlemsds.asp 65997-18-4 7681-49-4
depingchem_com---msds_matt_hardener_mb68.asp 936-49-2
dhs_gov---chemsec_appendixa-chemicalofinterestlist.asp N/A
diamondproductsinc_com---CHLORBRT.asp 87-90-1 6834-92-0
disupply_com---KleenScreen.msds.asp 7790-28-5
ditchwitch_com---214911.asp 7791-25-5 7439-93-2 7782-50-5 1333-86-4
dixiechemical_com---3-Ethoxypropionitrile_EOPN_DIXIE_MSDS.asp 2141-62-0
dixiechemical_com---3-Methoxypropionitrile_MOPN_DIXIE_MSDS.asp 110-67-8
dixiechemical_com---Glutaric_Anhydride_GAN_DIXIE_MSDS.asp 108-55-4
dmapcatalyst_com---MSDS.asp 1122-58-3
doc_state_nc_us---10-0050-00.asp 12-16-2 1317-65-3 9004-62-0 25265-77-4 57-55-6 112926-00-8 14808-60-7 13463-67-7 7732-18-5 1314-13-2 13464-41-7
doc_state_nc_us---55-030msds.asp 1317-65-3 10101-89-0 7778-54-3 9016-45-9
doc_state_nc_us---55-210msds.asp 61789-19-3 111-42-2 147-14-8 7758-29-4 77-32-1
dojindo_com---MSDSA007Alfusone.asp 81-96-2
dojindo_com---MSDSA012Arsemate.asp 81-96-2 1470-61-7
dojindo_com---MSDSA016ABD-F.asp 81-96-2 91366-65-3
dojindo_com---MSDSA296AB-NTA.asp 81-96-2
dojindo_com---MSDSA305ARP.asp 81-96-2 139585-03-8
dojindo_com---MSDSA375TMA-PTIO.asp 81-96-2 160940-18-1
dojindo_com---MSDSA407ARII.asp 81-96-2
dojindo_com---MSDSA42311-Amino-1-undecanethiol.asp 81-96-2 142229-58-6
dojindo_com---MSDSA4248-Amino-1-octanethiol.asp 81-96-2

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com