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MSDS Material Safety Data Sheet
CAS

65997-18-4
7681-49-4

File Name: dentsply_com---Principlemsds.asp
                       MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information

PRINCIPLE鈩? Adhesive Ionomer Cement Powder
1.1 Product Trade Name:
1.2 Part (Item) Number: 674100-674150 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963 鈥? 0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 02/11/98 Date Revised: 02/02/01

SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Strontium aluminum fluorosilicate glass N. E. N. E. 65997-18-4 > 90 %
Sodium Fluoride N. E. N. E. 7681-49-4 <5%

SECTION III - Physical/Chemical Characteristics
3.6 Specific Gravity: >1.0 g/cm3
3.1 Boiling point: N. A.
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. A.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Not Soluble
3.5 Appearance and odor:Off white powder with characteristic odor.

SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. A.
4.2 Flammability (explosive limits): LEL: N.A. UEL: N.A.
4.3 Extinguishing media: N. A.
4.4 Special fire fighting procedures: N. A.
4.5 Unusual fire and explosion hazards: N. A.

SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Heat greater than 50掳C(122掳F).
5.3 Incompatibility (materials to avoid): Aqueous polycarboxylic acid.
5.4 Hazardous decomposition or byproducts: N. E.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): None

SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: No Skin?: No Ingestion?: Possible
6.2 Health hazards (acute and chronic):Powder is a heavy dust. Inhalation of material is not likely. May cause drying of the
skin.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated?: No
6.4 Signs and symptoms of exposure: Could cause mechanic irritation to the eye as any nuisance dust.
6.5 Medical conditions generally
aggravated by exposure: Open wounds or sores of the skin.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes and call
physician. Skin: Wash area with mild soap and water. Call physician if irritation
persists.
SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled:Spray powder with water to minimize dusting, and sweep up. Place in an appropriately
marked container for disposal.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local regulations.
7.3 Precautions to be taken in handling
and storage: Store at ambient temperatures, away from heat.
7.4 Other precautions: Observe normal warehouse handling procedures. Handling of this product should be by
trained dental healthcare professionals only.

SECTION VIII - Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product. In excessive quantities
treat as a nuisance dust.
8.2 Ventilation: Local exhaust is recommended.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Close fitting protective goggles.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Handling of this product
should be by trained dental healthcare professionals only.



NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA - National Fire Protection Association
Flammability 0 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information

PRINCIPLE庐 Adhesive Ionomer Cement Liquid
1.1 Product Trade Name:
1.2 Part (Item) Number: 674100 鈥? 674150 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information:(302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 2/11/98 Date Revised: 02/02/01

SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Dimethacrylate resin monomer N. E. N. E. 1565-94-2 & > than 70 %
7732-18-5 & 868-77-9
Acrylic monomer N. E. N. E. 87699-25-0 < than 15 %
Polymerizeable carboxylic acid dimethacrylate N. E. N. E. 159002-30-9 < than 15 %

SECTION III - Physical/Chemical Characteristics
3.6 Specific Gravity: >1.0 g/cm3
3.1 Boiling point: N. A.
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. A.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Slightly Soluble
3.5 Appearance and odor:Low viscosity, light yellow liquid with faint acidic odor.

SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. E.
4.2 Flammability (explosive limits): LEL: N.E. UEL: N.E.
4.3 Extinguishing media: Sand, foam, carbon dioxide, or dry chemical.
4.4 Special fire fighting procedures: Wear MSHA/NIOSH approved or equivalent, pressure demand self-contained
breathing apparatus. Fire fighters should wear full protective clothing including a
self-contained breathing apparatus.
4.5 Unusual fire and explosion hazards: During a fire, irritating gasses from the decomposition of the methacrylate monomers
may be present.

SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Exposure to strong oxidants, heat and light. Store at room temperature.
5.3 Incompatibility (materials to avoid): Peroxides.
5.4 Hazardous decomposition or byproducts: Acid fumes, carbon monoxide and/or carbon dioxide.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): Exposure to intense visible light, peroxides, or prolonged storage above 38掳C
(100掳F)
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Possible Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic): May cause eye irritation and possible corneal damage. Individuals susceptible to
methacrylates may develop allergic response. Ingestion may cause local irritation to
soft tissue.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated?: No
6.4 Signs and symptoms of exposure: Irritation and possible corneal damage. Dermal irritation or possible allergic response
including nausea. Redness or irritation of eyes or skin.
6.5 Medical conditions generally
aggravated by exposure: Known sensitivity to methacrylates. Open wounds or sores of the skin.
6.6 Emergency first aid procedures: In case of eye contact, flush with flowing water for 15 minutes and call physician.
Skin: Flush with flowing water for 15 minutes, then wash area with mild soap and
water. Call physician.

SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled:Eliminate ignition sources. Dike and absorb with inert materials (sand, soda ash, vermiculite)
and transfer to an appropriately marked container.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local regulations.
7.3 Precautions to be taken
in handling and storage: Store at ambient temperature out of direct sunlight and heat. Keep away from flame and sparks.
7.4 Other precautions: Store away from food and beverages. Observe normal warehouse handling procedures.
Handling of this product should be by trained dental healthcare professionals only.

SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product.
8.2 Ventilation: Local exhaust is recommended.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Close fitting protective goggles.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Handling of this product
should be by trained dental healthcare professionals only.



NFPA HAZARD
CLASSIFICATIONS
Health 1 NFPA 鈥? National Fire Protection Association
Flammability 1 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard COR

574898 (R-02/02/01)

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