May 18, 2004
Material safety data shet
-- -
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENT F CA O
-- -
Catalog Numbers: 67042
Catalog Name: Potasium hexacyanoferate(I) trihydrate
Company Identif cation:
Junsei Chemical Co., Ltd.
4-16, 4-Chome, Nihonbashi-Honc, Chuo-k
Tokyo, 103-0023 Japan
Phone: +81-3-3270-5411 FAX: +81-3-3241-8298
Web: htp://ww.junseicop/
E-mail: eihon@ju s .c p
EMERG NCY TEL PHON NUMBER: Busine Headquarte s, Scien sec.
Phone: +81-3-3270-5413
FAX: +81-3-3270-5461 E-mail: shiyaku@jnsei.cop
CREATION DATE: May 18, 2004
-- -
SECTION 2 COMPOSIT N, INFORMATION ON INGRED TS
-- -
COMPONET: Potasium hexacyanoferate(I) trihydrate
SYNOMS: Potasium ferocyanide trihydrate
CAS NUMBER: 14459-95-1
US TSCA: unlisted
EC NUMBER (EIN CS): unlisted
JAPN NUMBER (ENCS): 1-815
PERC NTAG : (GR)9 .5+% (EP) 9 .0+%
-- -
SECTION 3 HAZ RDS IDENT F CA O
-- -
EMERG NCY OVER I W
Light sen it v .
Poten ial Health Ef ects
Eye:
May cause eye irtation.
Skin:
May cause skin irtation.
Ingestio :
May cause gastroineal irtation with nausea, vom itng and
diarhea. May cause efcts simlar to those of acute inhalation.
1/1
May 18, 2004
Inhalation:
May cause respiatory tract irtation. May cause anox ia,
characteriz d by weaknes , headache, diz nes , confus ion, cyanosi,
weak and iregular heart beat, colapse, uncosie s,
convulsi, coma and death.
Chronic:
Prol nged or rep ated skin contact may cause dermati s.
-- -
SECTION 4 FIRST AID MEASURE
-- -
Eyes:
Flush eyes with plenty of water for at least 15 minute s,
ocasionaly liftng the uper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and wa ter for at
least 15 minutes while removing contaminated clothing and shoe.
Ingestio :
If victm is consiu and alert, give 2-4 cupfls of milk or water.
Nevr give anything by mouth to an uncosi person. Get medical
aid imedately. Induce vomitng by givn one teaspo n of Syrup of
Ipecac.
Inhalation:
Get medical aid imedately. Remov from exposur to f resh air
imedately. If not breathing, give artifcal respia tion. If
breathing is dif cult, give oxygen.
Notes to Physic an:
-- -
SECTION 5 FIRE FIGHTN MEASURE
-- -
Gen ral Information:
As in any fire, wear a self-contained breathing appara tus in
presu-dmand, MSHA/NIOSH (aproved or equivalent), and ful
protec iv gear. Combusti n gen rates toxic fumes. Sub stance is
no c mbusti le.
Extingush Media:
Use extingush media most approiate for the suro undi g fire.
-- -
SECTION 6 ACIDENTL RELAS MEASURE
-- -
Gen ral Information: Use pro e personal protec iv equipm nt as indcated
in Section 8.
Spil s/Leaks:
Vacum or swep up material and place into a suitable dispo al
container.
2/2
May 18, 2004
-- -
SECTION 7 HANDLI G AND STORAGE
-- -
Handli g:
Avoid breathing dust, vapor, mist, or gas. Avoid conta ct with skin
and eyes. Use only in a chemial fume hod.
Storage:
Store in a co l, dry place. Do not store in direct sun light. Store
in a tigh ly closed container.
-- -
SECTION 8 EXPOSUR CONTR LS, PERSONAL PROTEC I N
-- -
Engi e r Contr ls:
Facil t es storing or util z ng this material should b e equip d
with an eyewash facilty and a safety shower. Use adeq uate gen ral or
local exhaust ventilation to kep airbone conetrati ons below the
permis bl exposur lim ts.
Personal Protec iv Equipment
Eyes:
Wear approiate proteciv eyeglase or chemi al
safety goles as describ by OSHA's eye and face
protecin regulations in 29 CFR 1910.133 or European
Standard EN16 .
Skin:
Wear approiate proteciv gloves to pre vent skin
exposur .
Clothing:
Wear approiate proteciv clothing to p rev nt skin
exposur .
Respirators:
Fol w the OSHA respi ator regulations fo und in 29CFR
1910.134 or European Standard EN 149. Alw ays use a
NIOSH or European Standard EN 149 approve d respi ator
when nec s ary.
-- -
SECTION 9 PHYSICAL AND CHEMICAL PRO E TI S
-- -
Physical State: Crystal ine powder
Ap earance: yelow
Odor: Not available
pH: Not available.
Vapor Pres u : Neglib
Visco ty: Not available.
3/3
May 18, 2004
Boil ng Point: Not available.
Frezing/Melting Point: 70 deg C
Autoign Temprature: Not available.
Flash Point: Not available.
Explosin Limts, lower: Not available.
Explosin Limts, uper: Not available.
Decomp sit n Temp rature: >70 deg C
Solubi ty in water: insolube in alcohl
Specif Gravity/Density: 1.8500g/cm3
Molecuar Formula: C6FeK4N6.3H2O
Molecuar Weight: 422.39
-- -
SECTION 10 STABIL Y AND REACTIV Y
-- -
Chemical Stabil ty:
Stable under normal tempratures and presu.
Condit s to Avoid:
Incompatible materials, light.
Incompatibles with Other Materials:
Strong oxidzng agents, strong acids, nitrc acid.
Hazardous Decomp sit n Products:
Hydrogen cyanide, nitroge oxides, carbon monxide, ca rbon diox e.
Hazardous Polymerization: Wil not oc ur.
-- -
SECTION 11 TOXIC L G A INFORMATION
-- -
RTECS#:
CAS# 14459-95-1 unlisted.
LD50/LC50:
Not available.
Carcinoge ty:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Se actual entry in RTECS for complet information.
-- -
SECTION 12 ECOL GI A INFORMATION
-- -
Ecot xi y:
Fish toxicy: LC50/96 hr for fathead minow: GT 100
mg/L
Invertbate toxicy: LC50/96hr for water flea: 80 mg/L.
THOD:
1.32 g/g
COD: 0.26 g/g
BOD5: 0.0 g/g
4/4
May 18, 2004
-- -
SECTION 13 DISPO AL CONSIDERAT
-- -
Dispoe of in a maner consite with fedral, state, and local regulations.
-- -
SECTION 14 TRANSPO INFORMATION
-- -
IAT
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
-- -
SECTION 15 REGULATO Y INFORMATION
-- -
European/Inter ational Regulations
European Labeling in Ac ordance with EC Direct v s
Hazard Symbols: Not available.
Risk Phrase :
Safety Phrase :
S 24/25 Avoid contact with skin and eyes .
WGK (Water Danger/Protec i n)
CAS# 14459-95-1: 2
United Kingdom Oc upational Exposure Lim ts
Canada
None of the chemials in this product are listed on th e DSL/NDSL list.
CAS# 14459-95-1 is not listed on Canada's Ingredit D isclo ure List.
Exposure Lim ts
US FED RAL
TSCA
CAS# 14459-95-1 is not on the TSCA Invetory. It is a hydrate and
exmpt from TSCA Invetory requimnts (40CFR720.3(u) (2) .
-- -
SECTION 16 OTHER INFORMATION
-- -
5/5
|