Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico, Brazil).
Material Safety Data Sheet
ROYCO 46, 46TF
1 . Product and company identification
Common name : ROYCO 46, 46TF
MSDS# : AC1087 Supplier/Manufacturer
MILSPEC# : Mil-L-46000;Mil-L-46150 Anderol Canada Corp.
700 Third Line
Material use : Lubricant.
Oakville, ONT
In case of emergency : CANUTEC (613) 996-6666 (Canada)
Canada L6J 5A3
CHEMTREC: 800-424-9300 (United States)
Tel: (905) 827-9087
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475
Fax: (905) 827-2862
: 03/31/2006
Date of issue
2 . Hazards identification
Physical state : Liquid.
Odor : Slight.
Color : Beige.
Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada, the NOM-018-STPS-2000 in Mexico
and Brazil NBR 14725:2001.
Emergency overview : WARNING!
CAUSES SEVERE EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
Do not ingest. Avoid contact with skin and clothing. Wash thoroughly after handling.
Routes of entry : Skin contact. Eye contact. Ingestion.
Potential acute health effects
Eyes :
Severely irritating to eyes.
Skin :
Irritating to skin.
No known significant effects or critical hazards.
Inhalation :
:
May be harmful if swallowed.
Ingestion
Potential chronic health :
Carcinogenic effects: Not applicable.
effects Mutagenic effects: Not applicable.
Teratogenic effects: Not applicable.
Medical conditions : Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or
aggravated by over- prolonged contact with spray or mist may produce chronic eye irritation and severe skin
exposure irritation.
See toxicological information (section 11)
3 . Composition/information on ingredients
United States
Name CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester 1809-20-7 1-5
Canada
Name CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester 1809-20-7 1-5
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ROYCO 46, 46TF
Mexico
Classification
Name UN number IDLH H F R Special CAS number %
Phosphonic Acid, Bis Not - 1 2 0 1809-20-7 1-5
(1-Methylethyl) Ester regulated.
Brazil
Name CAS number %
Phosphonic Acid, Bis(1-Methylethyl) Ester 1809-20-7 1-5
See Sections 8, 11 and 14 for details.
4 . First aid measures
Eye contact : Check for and remove any contact lenses. In case of contact, immediately flush skin with
plenty of water for at least 20 minutes while removing contaminated clothing and shoes.
Get medical attention if irritation occurs.
Skin contact : Wash with soap and water. Get medical attention if irritation occurs.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical
attention if symptoms appear.
Ingestion : Do not induce vomiting. Never give anything by mouth to an unconscious person. Get
medical attention if symptoms appear.
Notes to physician : Not available.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
5 . Fire-fighting measures
Flammability of the product : May be combustible at high temperature.
Products of combustion : The final products of combustion are carbon oxides and water. Nitrogen, sulfur and metal
oxides may also be produced in some cases.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : No specific hazard.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
6 . Accidental release measures
Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Methods for cleaning up : If emergency personnel are unavailable, contain spilled material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Place spilled material in an appropriate container for disposal.
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ROYCO 46, 46TF
7 . Handling and storage
Handling : Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly after
handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
8 . Exposure controls/personal protection
Consult local authorities for acceptable exposure limits.
Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to
control airborne levels. If this product contains ingredients with exposure limits, use
process enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure below any recommended or statutory limits.
Personal protection
Eye protection : Safety glasses with side shields.
Skin protection/Body : Not applicable.
Respiratory protection : Not applicable.
Hand protection. : Natural rubber (latex).
HMIS Code/Personal :B
protective equipment
Personal protection in case : Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-
of a large spill approved self-contained breathing apparatus or equivalent and full protective gear.
Wash hands, forearms and face thoroughly after handling compounds and before eating,
smoking and using the lavatory and at the end of the day. Follow good industrial hygiene
practice.
9 . Physical and chemical properties
Physical state : Liquid.
Color : Beige.
Odor : Slight.
Specific gravity : 0.92 (Water = 1)
Flash point : Open cup: >145掳C (293掳F)(Cleveland.).
10 . Stability and reactivity
Stability and reactivity : The product is stable.
Conditions of instability : None known.
Incompatibility with various : Reactive with oxidizing materials.
substances
Hazardous polymerization : Will not occur.
Conditions of reactivity : None known.
11 . Toxicological information
Toxicity data
Product/ingredient name Test Result Route Species
Phosphonic Acid, Bis(1-Methylethyl) Ester LD50 1700 mg/kg Oral Rat
LD50 1590 mg/kg Oral Mouse
LD50 5700 mg/kg Dermal Rabbit
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ROYCO 46, 46TF
Acute Effects
Eyes : Severely irritating to eyes.
Skin : Irritating to skin.
No known significant effects or critical hazards.
Inhalation :
: May be harmful if swallowed.
Ingestion
Potential chronic health : Carcinogenic effects: Not applicable.
effects Mutagenic effects: Not applicable.
Teratogenic effects: Not applicable.
12 . Ecological information
Environmental precautions : No known significant effects or critical hazards.
Octanol/water partition : The product is more soluble in octanol.
coefficient
Bioconcentration factor : Not available.
Products of degradation : The final products of biodegradation are carbon oxides and water. Nitrogen and sulfur
oxides and metal salts may also be produced in some cases.
Toxicity of the products of : The products of degradation are less toxic than the product itself.
biodegradation
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
14 . Transport information
: Not applicable.
NAERG
Regulatory information
UN/ IMDG/ IATA DOT/ TDG : Not regulated by any transport mode.
15 . Regulatory information
United States
HCS Classification : Irritating material
U.S. Federal regulations : TSCA 8(b) inventory: All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products
were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
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ROYCO 46, 46TF
State regulations : Pennsylvania RTK: Naphthalenesulfonic Acid, Dinonyl-, Barium Salt: (environmental
hazard, generic environmental hazard); 2,6-Ditert-butyl-p-cresol: (generic environmental
hazard); N,N-bis(2-Ethylhexyl)-ar-methyl-1H-Benzotriazole-1-methanamine; Di(2-
Ethyhexyl) Amine: (generic environmental hazard)
Massachusetts RTK: 2,6-Ditert-butyl-p-cresol; Di(2-Ethyhexyl) Amine
New Jersey: Naphthalenesulfonic Acid, Dinonyl-, Barium Salt; 2,6-Ditert-butyl-p-cresol;
N,N-bis(2-Ethylhexyl)-ar-methyl-1H-Benzotriazole-1-methanamine; Di(2-Ethyhexyl)
Amine
California prop. 65: No products were found.
Canada
WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic).
CEPA DSL: All components listed.
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United States
OSHA, the Mexican NOM -018-STPS-2000 and the Brazilian NBR 14725:2001. This MSDS contains all the information
required by the CPR, OSHA, the American National Standard Institute (ANSI) Z400.1, NOM -018-STPS-2000 and NBR
14725:2001.
Mexico
HAZARD RATINGS
Classification :
1 Flammability 4- Extreme
Health 1 0 Reactivity 3- Serious
2- Moderate
Special 1- Slight
0- Minimal
International lists : This product, (and its ingredients) is (are) listed on national inventories, or is (are)
exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea
(TCCL), in Japan (METI), in the Philippines (RA6969).
16 . Other information
Label requirements (U.S.A.) : CAUSES SEVERE EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
Hazardous Material : HMIS RATING HAZARD RATINGS
Information System (U.S.A.) 4- Extreme
1
Health 3- Serious
1 2- Moderate
Fire hazard
1- Slight
0
Physical Hazard 0- Minimal
See section 8 for more detailed
C
Personal protection information on personal protection.
National Fire Protection :
Flammability
1
Association (U.S.A.)
1 0
Health Reactivity
Special
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References : ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -
29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous
Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.
Registration SOR/88-64, 31 December 1987. Hazardous Products Act "Ingredient
Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,
Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 and
NOM-004-SCT2-1994. Brazil NBR 14725:2001.
Responsible name : Mr. Max Naggar
: 03/31/2006
Date of issue
Date of previous issue : 07/31/2005
Version :4
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the user.
All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.
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