World Headquarters Page 1
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00429
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Potassium Antimonyl Tartrate
Catalog Number: 254926
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00429
Chemical Name: Antimonate(2-), bis[碌-[2,3-dihydroxybutanediato(4-)-O1,O2:O3,O4]]di-, dipotassium, stereoisomer
Chemical Formula: C8H4K2O12Sb2 . 3H2O
Chemical Family: Substituted organic acid
Use of the substance/preparation: Laboratory Reagent
CAS No.: 28300-74-5
Hazard: Toxic. Experimental mutagen.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Potassium Antimonyl Tartrate
EEC Number: 2342933
CAS No.: 28300-74-5
Percent Range: > 99,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: T - TOXIC
Ingredient R phrase(s) (R phrase details given in Heading 16): R 20 R 25
TLV: 0,5 mg/m鲁 (as Sb)
PEL: 0,5 mg/m鲁 (as Sb)
EU Occupational Exposure Limits: 0,5 mg/m3 as Sb
Impurities
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established.
PEL: Not established.
EU Occupational Exposure Limits: Not established
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: White powder
Odor: None
World Headquarters Page 2
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00429
Loveland, CO USA 80539
(970) 669-3050
EU Symbols: T - TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 20: Harmful by inhalation. R 25: Toxic if swallowed. R 51/53: Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): Toxic May cause: salivation coughing metallic taste nausea vomiting bloody diarrhea dizziness
irritability muscle pains liver damage
Target Organs (Ing E): Liver
Inhalation: May cause: respiratory tract irritation coughing sore throat shortness of breath
Target Organs (Inh E): Liver
Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions
Chronic Effects: Chronic overexposure may cause dermatitis laryngitis headache weight loss anemia
Cancer / Reproductive Toxicity Information:
IARC Listed: No
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Ingestion (First Aid): Induce vomiting using syrup of ipecac or by sticking finger down throat. Never give anything by
mouth to an unconscious person. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combustion Products: Toxic fumes of: antimony
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Water. Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear. Evacuate area and fight fire from a safe distance.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Releases of this material may contaminate the environment. Stop spilled material from being
released to the environment.
Clean-up Technique: Sweep up material. Dispose of material in an E.P.A. approved hazardous waste facility.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan)
when: any quantity is spilled.
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7. HANDLING AND STORAGE
World Headquarters Page 3
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00429
Loveland, CO USA 80539
(970) 669-3050
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Use with
adequate ventilation. Maintain general industrial hygiene practices when using this product.
Storage: Keep container tightly closed when not in use. Protect from: heat moisture
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Laboratory Reagent
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain adequate ventilation to keep vapor level below TWA
for chemicals in this product. Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: laboratory fume hood
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Use with adequate ventilation.
TLV: 0,5 mg/m鲁 (as Sb)
PEL: 0,5 mg/m鲁 (as Sb)
EU Occupational Exposure Limits: 0,5 mg/m3 as Sb
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: None
pH: Aqueous solution is slightly acidic.
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: Loses water of hydration at 100掳C (212掳F).
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined.
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,6
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: 8 gm per 100 ml water @ 20掳C (68掳F).
Acid: Not determined.
Other: 1 gm per 15 ml of glycerol.
Metal Corrosivity:
Steel: Not determined.
Aluminum: Not determined.
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Heating to decomposition. Extreme temperatures Excess moisture
Reactivity / Incompatibility: Incompatible with: alkali metals alkali metal carbonates perchloric acid reducers
Reduction may form stilbene. Stilbene is highly toxic.
Hazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: antimony
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
World Headquarters Page 4
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00429
Loveland, CO USA 80539
(970) 669-3050
Product Toxicological Data:
LD50: Oral rat LD50 = 115 mg/kg; Oral human LDLo = 2 mg/kg.
LC50: None reported.
Dermal Toxicity Data: None reported.
Skin and Eye Irritation Data: None reported.
Mutation Data: Cytogenetic analysis on human fibroblasts @ 100 碌mol/l; Cytogenetic analysis on rat via
intraperitoneal route @ 2 mg/kg.
Reproductive Effects Data: None reported.
--
Ingredient Toxicological Data: --
Not applicable
IARC Listed: No
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
Not applicable
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Antimony Potassium Tartrate
--
ICAO Hazard Class: 6,1
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: UN1551
ICAO Packing Group: III
I.M.O.:
I.M.O. Proper Shipping Name: Antimony Potassium Tartrate
--
I.M.O. Hazard Class: 6,1
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: UN1551
I.M.O. Packing Group: III
A.D.R.:
A.D.R. Proper Shipping Name: Antimony Potassium Tartrate
--
A.D.R Hazard Class: 6,1
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: 1551
A.D.R. Packing Group: III
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
World Headquarters Page 5
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00429
Loveland, CO USA 80539
(970) 669-3050
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
EEC Number: 2342933
EEC LABEL COPY:
EU Symbols: T - TOXIC N - DANGEROUS FOR THE ENVIRONMENT
R PHRASES: R 20: Harmful by inhalation. R 25: Toxic if swallowed. R 51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
S PHRASES: S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible). S 61: Avoid release to the environment. Refer to special instructions/Safety data sheets.
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. Cassaret and Doull's Toxicology, 3rd Ed. New York: Macmillan
Publishing Co., Inc., 1986. CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario
Canada: 30 June 1993. IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans. World Health
Organization (Volumes 1-42) Supplement 7. France: 1987. List of Dangerous Substances Classified in Annex I of the
EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances, Amended July 1992. Sax, N.
Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Sixth Annual
Report on Carcinogens, 1991. U.S. Department of Health and Human Services. Rockville, MD: Technical Resources, Inc.
1991. Technical Judgment. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989. TLV's
Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial
Hygienists, 1992. Vendor Information.
R PHRASES: R 20: Harmful by inhalation. R 25: Toxic if swallowed. R 51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Use of the substance/preparation: Laboratory Reagent
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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