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PARTS CLEANING TECHNOLOGIES HMIS RATINGS NFPA
307 EMMETT AVE /\
BOWLING GREEN, KY 42101 HEALTH: 2 HEALTH / \ FIRE
FIRE: 2 2 / \ 2
EMERGENCY TELEPHONE NUMBER: (248) 799-7700 REACTIVITY: 0 / \
INFORMATION TELEPHONE NUMBER: (888) 746-0095 PERSONAL PROTECTION: H \ /
DATE PREPARED: 08/24/04 \ /
SUPERSEDES: 11/04/94 SPEC. HAZ. \ / REACT.
\/ 0
SECTION I PRODUCT IDENTIFICATION
TECHTRIDE庐-THPER-86
PRODUCT NAME:
NOT APPLICABLE
CAS NUMBER:
MIXTURE
CHEMICAL FAMILY:
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
CAS HAZARDOUS COMPONENT NTP IARC OSHA ACGIH OTHER SARA 313
NUMBER PEL TLV LIMITS PERCENT
(ppm) (ppm) (ppm)
127-18-4 TETRACHLOROETHYLENE Y Y 100 25 300 ST > 87 %
200 C 100 C
286-20-4 CYCLOHEXENE OXIDE S S N/E N/E N/E < 13 %
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
80-129 oC 1.49
BOILING POINT SPECIFIC GRAVITY (H2O = 1)
N/D N/D
VAPOR PRESSURE (mm Hg) MELTING POINT
>1 N/D
VAPOR DENSITY (AIR = 1) EVAPORATION RATE (Butyl Acetate = 1)
SOLUBILITY IN WATER: NOT DETERMINED APPEARANCE AND ODOR: WATER WHITE LIQUID
OTHER INFORMATION:
pH OF SOLUTION: 6.5-7.5
FORMULA: CCl2=CCl2 & C6H10O
% VOLATILE BY VOLUME: 100
SECTION IV - FIRE AND EXPLOSION HAZARD INFORMATION
> 60 oC
FLASH POINT: FLAMMABLE LIMITS: LEL: N/D UEL: N/D
EXTINGUISHING MEDIA:
Use water, dry chemical, foam, or carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES:
Firefighters should wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus for possible exposure
to toxic by-products of combustion as denoted in section v. Water may be used to keep containers cool.
UNUSUAL FIRE FIGHTING PROCEDURES:
This product may decompose when it comes in contact with open flames, heating elements, electrical arcs (such as electrical
motors) or combustion engines. Due to vapor density ignition sources distant from areas of handling material need to be
considered.
SECTION V - FIRST AID INFORMATION
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INHALATION:
Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult
administer oxygen. Seek medical attention.
EYE:
Immediately flush eyes with large amounts of water for at least 15 minutes. Consult a physician.
DERMAL:
Remove contaminated clothing. Immediately wash skin with soap and water for at least 15 minutes. If irritation occurs
consult a physician. Clean contaminated clothing prior to reuse, properly discard all leather soaked with product.
INGESTION:
If conscious, drink large amounts of water, DO NOT induce vomiting. Never administer anything by mouth to an
unconscious person. If vomiting occurs spontaneously keep individual's head below their hips to prevent aspiration of
material into the lungs. Seek medical attention; if unconscious or in convulsions take immediately to the hospital.
NOTE: consult a physician in all areas of exposure. First-aiders need to provide for their own safety before attempting to
provide assistance.
SECTION VI - HEALTH HAZARD INFORMATION
ROUTES OF ENTRY:
Inhalation, dermal, ingestion are the primary routes of entry, although other avenues should be considered.
INHALATION:
Moderately toxic. Inhalation can cause irritation of the respiratory tract, dizziness, conjunctiva irritation, general anesthesia,
hallucinations, distorted perceptions, pulmonary changes, nausea, headache, loss of coordination and equilibrium,
unconsciousness, coma, and in severe cases death. Perchloroethylene is a central nervous system (CNS) depressant and can
cause possible CNS damage with overexposure. May cause irritation of the upper respiratory tract. Fatalities following
severe acute exposure to various chlorinated solvents have been attributed to ventricular fibrillation.
EYE:
Eye irritant; eye contact may cause discomfort, pain, and irritation.
DERMAL:
Mildly irritating to the skin. Prolonged exposure involving the skin may cause dermatitis; problem may be accentuated by
trapping the liquid against the skin.
INGESTION:
Mildly toxic. Swallowing material may cause irritation to the mouth and upper GI tract along with other effects noted under
inhalation. Aspiration due to vomiting may lead to chemical pneumonia and pulmonary edema which is a potentially fatal
condition.
CYCLOHEXENE OXIDE:
Moderately toxic by skin contact, ingestion, intraperitioneal, and intermuscular routes. Mildly toxic by inhalation.
PERCHLOROETHYLENE
Prolonged exposure above the OSHA permissible exposure limits may result in liver and kidney damage. OSHA has
declared Perchloroethylene a potential carcinogen. This material has also been shown (experimentally) to have
reproductive effects and be Teratogen. Material is listed as an animal carcinogen under ACGIH with unknown relevance to
humans.
SECTION VI - HEALTH HAZARD INFORMATION
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
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Prolonged exposure above the PEL/TLV may result in liver and kidney damage.
OTHER HEALTH WARNINGS:
Never administer adrenaline following Perchloroethylene overexposure. Increased sensitivity of the heart to adrenaline may be caused by
overexposure to Detrex perk.
SECTION VII - PERSONAL PROTECTIVE EQUIPMENT
VENTILATION:
General ventilation is recommended. Local exhaust is recommended where vapors, dusts, or mists may be generated
due to work activities.
RESPIRATORY PROTECTION:
To limit employees鈥? exposure, OSHA requires that the use of administrative or engineering controls must first be developed
and implemented whenever feasible (29CFR1910.1000 (e)). When controls are not feasible, and exposure exceeds
established limits, then protective equipment such as respirators are recommended. Use only OSHA/NIOSH approved
respirators according to the manufacturer鈥檚 directions and OSHA requirements. Positive pressure, self-contained units
(i.e., SCBAs) are required whenever: there is insufficient oxygen, IDLH conditions exist, and when determined necessary
by surrounding environmental conditions.
EYE PROTECTION:
Splash proof goggles, face shields. Eyewash should be available in areas where this product is handled.
DERMAL PROTECTION:
Protect all exposed skin from liquid contact. Use chemically resistant equipment. Use gloves to prevent dermal contact.
Aprons should be used when there is a change for splashing. Use chemical boots as appropriate. Launder clothing prior
to reuse, properly discard contaminated leather products. Safety showers should be available in areas where this product
is handled.
SECTION VII - TOXICOLOGY
TOXICOLOGY STUDIES:
PERCHLOROETHYLENE CYCLOHEXENE OXIDE
34,200 mg/m3/8hr.
LC50 (INHALATION-RAT): 2,000 ppm/4H *
LD50 (DERMAL-RABBIT): N/D 630 mg/Kg
LD50 (INGESTION-RAT): 2629 mg/Kg 1,090 mg/Kg
AQUATIC LIFE (TOXICITY): LC50 (FISH) 96 HR. TLM 100-10 ppm N/D
*REPRESENTS LCLo OR LDLo VALUE
SECTION IX -REACTIVITY DATA
STABILITY:
Stable
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
Products of decomposition include: Hydrogen Chloride, Carbon Monoxide, Carbon Dioxide, Chlorine, possible traces of
Phosgene, and possibly other unidentified organic compounds.
SECTION IX -REACTIVITY DATA
HAZARDOUS POLYMERIZATION:
Hazardous polymerization may occur with Cyclohexene Oxide component.
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INCOMPATIBILITY:
CONDITIONS TO AVOID:
Avoid contact with open flames, electric arcs, hot glowing surfaces, or other sources of ignition.
MATERIALS TO AVOID:
Caustic Soda, Caustic Potash, and Oxidizers. Shock sensitive materials may be formed. Also avoid contact with
Barium, Lithium, Beryllium, and N2O4. Cyclohexene Oxide can react with oxidizers.
SECTION X - SPILL AND DISPOSAL INFORMATION
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Immediately evacuate the area and provide maximum ventilation. Unprotected personnel should move upwind of the spill.
Only personnel equipped with proper respiratory and skin/eye protection should be permitted in the area. Dike area to
contain the spill. Take precautions as necessary to prevent contamination of the ground and surface waters. Recover
spilled material on absorbents, such as sawdust or vermiculite, and sweep into closed containers for disposal. After all
visible traces, including vapors, have been removed, thoroughly wet vacuum the area. Do not flush to the sewer. If area is
porous, remove as much earth and gravel, etc., As necessary and place in closed containers for disposal.
WASTE DISPOSAL METHOD:
Contaminated sawdust, vermiculite or porous surface must be disposed of in a permitted hazardous waste management
facility. Recovered liquids may be reprocessed or incinerated, or must be treated in a permitted hazardous waste
management facility. Care must be taken when using or disposing of chemical materials and/or their containers in
accordance with the clean air act, the clean water act, the resource conservation and recovery act, the department of
transportation, as well as any other relevant federal, state, or local laws/regulations regarding disposal.
POSSIBLE WASTE DISPOSAL CODES: U210, F001, AND F002
SECTION XI - TRANSPORTATION DATA
DOT INFORMATION:
PROPER SHIPPING NAME: Tetrachloroethylene
HAZARD CLASS: 6.1
IDENTIFICATION NUMBER: UN 1897
PACKING GROUP: PG III
REQUIRED LABELS: Keep Away From Food
REPORTABLE QUANTITY: 45.4 Kg (100 Lbs.)
OTHER Marine Pollutant
SECTION XII - PRECAUTIONS FOR SAFE HANDLING AND USE
鈥? Store in the original, closed, properly sealed and labeled container.
鈥? Do not use cutting or welding torches on containers that contain product, unless, the containers are properly purged and
cleaned.
鈥? Ventilation must be sufficient to limit employees鈥? exposure
鈥? Avoid contact with eyes and skin. Do not ingest.
鈥? Wear PPE when handling this material. Wash exposed body areas with soap and water prior to using lavatory
facilities, consuming food or beverages or applying cosmetics.
鈥? Do not eat, drink or smoke in work areas.
SECTION XII - PRECAUTIONS FOR SAFE HANDLING AND USE
鈥? This material or its vapors when in contact with flames, hot glowing surfaces or electric arcs can decompose to form hydrogen
chloride, chlorine, carbon dioxide, carbon monoxide, and other toxic by-products including possibly phosgene.
鈥? avoid contamination of water supplies. Handling, storage, and use procedures must be carefully monitored to avoid spills or leaks.
Any spill or leak has the potential to cause underground water contamination which may, if sufficiently severe, render a drinking
water source unfit for human consumption. Contamination which occurs can not be easily corrected.
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SECTION XIII - REGULATORY DATA
OSHA
This product is subject to the Hazard Communication Standard under 29 CFR 19190.1200 based on the ingredients found
in Section II.
RCRA
Refer to Section X for information
SARA
Section 302 (40 CFR 搂 355) : this material does not contain materials found under the extremely hazardous substances list.
鈥?
Sections 311/312 (40 CFR 搂 370) this material meets the following EPA hazard categories:
鈥?
X acute health hazard X chronic health hazard
fire hazard reactive hazard
Sudden release of pressure hazard
Section 313 (40 CFR 搂 372): this product contains Perchloroethylene which could trigger reporting under the toxic release
鈥?
inventory (Form R鈥檚)
TSCA
All materials in this product are listed in Inventory List.
Parts Cleaning Technologies believes the information and recommendations contained herein (including data and statements) are
accurate as of the date hereof. No warranty of fitness for any particular purpose, warranty of merchantability, or any other warranty,
expressed or implied, is made concerning the information provided herein. The information provided herein relates only to the
specific product designed and may not be valid where such product is used in combination with any other materials or in any process.
Further, since the conditions and methods of use of the product and of the information referred to herein are beyond the control of
Parts Cleaning Technologies, PCT expressly disclaims any and all liability as to any results obtained or arising from any use of the
product or reliance on such information.
N/A = NOT APPLICABLE
N/D = NOT DETERMINED
N/E = NOT ESTABLISHED
C = CEILING
S = SUSPECTED
ST = SHORT TERM EXPOSURE LIMIT (TETRACHLOROETHYLENE: 5 MINUTES IN ANY 3 HRS.)
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