MATERIAL SAFETY DATA SHEET
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
Pecora 890NST Non-Staining TechnologyTM
TRADE NAME (AS LABELED):
PRODUCT DESCRIPTION: Non-Staining, Ultra Low-Modulus Silicone Sealant
CHEMICAL NAME/CLASS: Non-staining silicone sealant
SYNONYM: 890NST
Pecora Corporation
SUPPLIER/MANUFACTURER'S NAME:
165 Wambold Road, Harleysville, PA 19438
ADDRESS:
EMERGENCY PHONE: (800) 424-9300 (CHEMTREC , 24 hours)
BUSINESS PHONE: (215) 723-6051 (Mon - Fri, 8 am - 5 pm ET)
EFFECTIVE DATE: July 13, 2007
This product is sold for commercial use. This MSDS has been developed to address safety concerns of those individuals working with bulk quantities of this
material, as well as those of potential users of this product in industrial/occupational settings. All pertinent health, safety and environmental information has been
presented based on ANSI Z400.1-2003, the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian Workplace Hazardous Materials
Information System (WHMIS) and Controlled Products Regulations (CPR).
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL DESCRIPTION: This product is a smooth paste with a mild medicinal odor and is available in a variety of standard and
custom colors including Limestone, Black, Tru-White, Aluminum Stone, Beige, and Bronze.
WARNINGS (per ANSI Z129.1): CAUTION! EYE, SKIN, AND RESPIRATORY TRACT IRRITANT. MAY CAUSE
ALLERGIC SKIN REACTION.
PRECAUTIONS (per ANSI Z129.1): Contact with uncured sealant or with vapors generated during curing may cause respiratory
tract irritation. Do not breathe fumes, dusts, vapors or mist. Do not swallow or take internally. Do not get in eyes, on skin, or on
clothing. Wash thoroughly after handling. Keep container closed. Use only in a well-ventilated area. Keep away from heat,
sparks and flame.
HAZARD SYMBOLS:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS庐)
Health 1* See Section 16 for definitions of ratings
0 = Minimal 3 = Serious
Flammability 1
1 = Slight 4 = Severe
Physical Hazard 1 2 = Moderate
HMIS庐 is a registered trademark of the National Paint and Coatings Association.
Pecora 890NST Non-Staining TechnologyTM Page 1 of 12 July 13, 2007
2. HAZARDS IDENTIFICATION (Continued)
CANADIAN WHMIS SYMBOLS:
D2A
D2B - Poisonous and infectious material - Other effects 鈥? Toxic
This product has been classified in accordance with the hazard criteria of the Canadian Controlled
Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
OSHA REGULATORY STATUS
NFPA RATING
This material is classified as hazardous under OSHA regulations. It is an irritant and
FLAMMABILITY
may cause an allergic skin reaction.
POTENTIAL HEALTH EFFECTS
1
1
1
The most significant routes of occupational overexposure are inhalation and contact
HEALTH REACTIVITY
with skin and eyes. The symptoms of overexposure to this product are as follows:
CONTACT WITH SKIN or EYES: Contact can cause eye or skin irritation.
Prolonged skin contact can result in dermatitis or an allergic reaction. Prolonged
OTHER
eye exposure may include redness, pain, and tearing.
See Section 16 for
definitions of ratings
SKIN ABSORPTION: No component of this product is reported to be absorbed
through intact skin.
INGESTION: If the product is swallowed, irritation of the mouth, throat, and other tissues of the gastro-intestinal system can
occur.
INHALATION: Overexposure to vapors of this product generated during curing, or dusts of this product can cause irritation to the
respiratory tract. Methyl ethyl ketoxime (2-butanone oxime, CAS # 96-29-7) is slowly formed when this product comes into contact
with water or moisture in the air. Provide adequate ventilation to control exposures to less than the suggested exposure guideline of 2
ppm. Crystalline Silicon dioxide dust can cause a chronic degenerative pulmonary disease called silicosis. Crystalline Silicon
dioxide dust is also suspected to be a cause of lung cancer, and is a suspect carcinogen.
INJECTION: Accidental injection of this product can cause burning, reddening, and swelling in addition to the wound. Symptoms
of such exposure can include those described under 鈥淚nhalation鈥?, 鈥淐ontact with Skin or Eyes,鈥? and 鈥淚ngestion鈥?.
TARGET ORGANS: Skin, eyes, mucous membranes, respiratory tract.
CHRONIC EFFECTS: Long-term skin or eye contact can result in dermatitis or an allergic reaction or eye irritation. Titanium
dioxide and Carbon Black have been classified as 鈥?2B鈥? (sufficient evidence in animals and inadequate evidence in humans) cancer-
causing agents by the International Agency for Research on Cancer.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye and skin irritation (redness or swelling); allergic reaction. See Section
11: TOXICOLOGICAL INFORMATION.
POTENTIAL ENVIRONMENTAL EFFECTS
This product does not normally present a significant hazard to aquatic or terrestrial life in small quantities. Do not discharge effluent
containing this product into streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National
Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do
not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority.
For guidance, contact your State Water Board or Regional Office of the EPA. See Section 12: ECOLOGICAL INFORMATION.
Pecora 890NST Non-Staining TechnologyTM Page 2 of 12 July 13, 2007
3. MATERIAL IDENTIFICATION
CHEMICAL NAME CAS # Weight %
polydimethyl siloxane diol 70131-67-8 30 鈥? 90
calcium carbonate 1317-65-3 0 鈥? 50
silicon dioxide 112945-52-5 0 鈥? 30
phenyl oximino silane 34036-80-1 0鈥?9
glass, oxide 65997-17-3 0鈥?8
mineral spirits 64741-65-7 or 8052-41-3 0鈥?5
polyamino silane 35141-30-1 0鈥?2
mullite 1302-93-8 0鈥?2
titanium dioxide 13463-67-7 0鈥?2
aluminum 7429-90-5 0鈥?2
carbon black 1333-86-4 0鈥?1
quartz 14464-46-1, 14808-60-7 0.1-1.0
The ingredients in the balance of this product do not contribute significant hazards beyond those described in this
document. Methyl ethyl ketoxime (MEKO) is generated during curing. See Section 8.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to
physician or health professional with victim.
FIRST AID PROCEDURES
SKIN EXPOSURE: If this product contaminates the skin, remove material and rinse with running water. Remove exposed or
contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure
symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.
INHALATION: If vapors of this product are inhaled, remove victim to fresh air. Victim must seek immediate medical attention if
any adverse exposure symptoms develop. If necessary, use artificial respiration to support vital functions.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water, if
conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to
swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, or impaired
respiratory system function can be more susceptible to health effects associated with overexposures to this product.
NOTE TO PHYSICIANS
Treat symptoms and eliminate overexposure.
Pecora 890NST Non-Staining TechnologyTM Page 3 of 12 July 13, 2007
5. FIRE-FIGHTING MEASURES
FLAMMABLE PROPERTIES
This product is not readily combustible. This material will not significantly contribute to the intensity of a fire. Use extinguishing
material suitable to the surrounding fire. Not sensitive to mechanical impact under normal conditions. Not sensitive to static discharge
under normal conditions.
EXTINGUISHING MEDIA
SUITABLE EXTINGUISHING MEDIA:
Water Spray: OK Carbon Dioxide: OK
Foam: OK Dry Chemical: OK
Halon: OK Other Any 鈥淎BC鈥? Class
UNSUITABLE EXTINGUISHING MEDIA: None.
PROTECTION OF FIREFIGHTERS
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: None.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS: Incipient fire responders should wear eye
protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move containers
from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of
water, or other environmentally sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Responders should wear the level of protection appropriate to the type of chemical released, the amount of the material spilled, and the
location where the incident has occurred. For releases of 1 drum or less, Level D Protective Equipment (gloves, chemical resistant
apron, boots, and eye protection) should be adequate.
ENVIRONMENTAL PRECAUTIONS
Minimize use of water to prevent environmental contamination. Prevent spill or rinsate from contamination of storm drains, sewers,
soil or groundwater. Place all spill residues in a suitable container and seal. Dispose of in accordance with applicable U.S. Federal,
State, or local procedures or appropriate standards of Canada (see Section 13, Disposal Considerations)
METHODS FOR CONTAINMENT
SPILL AND LEAK RESPONSE: Trained personnel using pre-planned procedures should respond to uncontrolled releases. Proper
protective equipment should be used. In case of a spill, clear the affected area and protect people.
RESPONSE TO INCIDENTAL RELEASES: Personnel who have received basic chemical safety training can generally handle
small-scale releases, such as 1 container of this product. Respond to incidental chemical releases by wearing gloves, eye
protection, and appropriate body protection.
RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the
simultaneous puncturing of several drums, by clearing the impacted area and contacting appropriate emergency personnel. Clean
up should only be done by qualified personnel.
METHODS FOR CLEAN-UP
Mechanically remove the spilled product. Wipe up residues with a small amount of mineral spirits on a rag following appropriate safety
precautions on the supplier鈥檚 MSDS or allow residues to cure and remove mechanically to decontaminate the area thoroughly.
OTHER INFORMATION
US regulations may require reporting of spills of this material that reach surface waters if a sheen is formed. If necessary, the toll-free
phone number for the US Coast Guard National Response Center is 1-800-424-8802.
Pecora 890NST Non-Staining TechnologyTM Page 4 of 12 July 13, 2007
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
HANDLING
As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after using this product. Do not eat or drink
while using this material. Avoid generating dusts, mists or sprays of this product. Remove contaminated clothing immediately. Do not
breathe (dust, vapor, mist, gas). Avoid contact with skin, eyes or clothing. In the event of a spill, follow practices indicated in Section
6 (Accidental Release Measures).
STORAGE
This product is stable under ordinary conditions of handling, use and storage. Store containers in a cool, dry location, away from direct
sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and
Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage, to ensure containers are
properly labeled and not damaged. To prolong shelf life, store at temperatures below 80掳F.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE GUIDELINES
CHEMICAL NAME CAS # Guideline Value
Polydimethyl siloxane diol 70131-67-8 NE NE
Mineral spirits 64741-65-7 TLV 100 ppm
PEL 500 ppm
NIOSH REL 350
1800 mg/m3 15
NIOSH STEL (C)
minutes
10 mg/m3
Calcium carbonate 1317-65-3 TLV
15 mg/m3, total dust
PEL
5 mg/m3 respirable
NIOSH REL dust
15 mg/m3, total dust
5 mg/m3 respirable
dust
3.5 mg/m3
Carbon black 1333-86-4 TLV
3.5 mg/m3
PEL
Methyl ethyl ketoxime 96-29-7 Suggested TWA 2 ppm
10 mg/m3, total dust
Glass, oxide 65997-17-3 TLV
3 mg/m3 respirable
15 mg/m3, total dust
PEL
5 mg/m3 respirable
Phenyl oximino silane 34036-80-1 NE NE
Polyamino silane 35141-30-1 NE NE
10 mg/m3
Silicon dioxide 112945-52-5 TLV
PEL 20 mppcf
6 mg/m3
NIOSH REL
3000 mg/m3
NIOSH IDLH
10 mg/m3
Titanium dioxide 13463-67-7 TLV
15 mg/m3 total dust
PEL
NIOSH REL NE
1.5 mg/m3
DFG MAK
10 mg/m3
Aluminum 7429-90-5 TLV
15 mg/m3 total dust
PEL
5 mg/m3 respirable
dust
15 mg/m3 total dust
NIOSH REL
5 mg/m3 respirable
dust
1.5 mg/m3
DFG MAK
TM
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8. EXPOSURE CONTROLS - PERSONAL PROTECTION (continued)
0.025 mg/m3
Quartz 14464-46-1, 14808-60-7 TLV
30 mg/m3/(%SiO2)
PEL
total dust
30 mg/m3/(%SiO2)
respirable dust
0.05 mg/m3
NIOSH REL
respirable dust
15 mg/m3, total dust
Mullite 1302-93-8 PEL
5 mg/m3 respirable
NE = Not Established. See Section 16 for Definitions of Terms Used.
ENGINEERING CONTROLS
Use with adequate ventilation to ensure exposure levels are maintained below the limits provided above.
PERSONAL PROTECTIVE EQUIPMENT (PPE)
EYE/FACE PROTECTION: For specific industrial applications, enhanced eye protection can be necessary. Use approved safety
goggles or safety glasses, as described in OSHA 29 CFR 1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or
appropriate Canadian standards.
SKIN PROTECTION: Wear chemical impervious gloves (e.g., Nitrile or Neoprene). If necessary, refer to U.S. OSHA 29 CFR
1910.138 or the appropriate standards of Canada.
BODY PROTECTION: For general industrial applications, chemically protective clothing is not normally needed. If a hazard of
injury to the feet exists due to falling objects, rolling objects, where objects can pierce the soles of the feet or where employee鈥檚 feet
can be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
RESPIRATORY PROTECTION: None needed under normal conditions of use or handling. Use NIOSH approved respirators if
ventilation is inadequate to control dusts, mists, fumes or vapors. Maintain airborne contaminate concentrations below guidelines
listed above. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres use of a full-face-piece
pressure/demand SCBA or a full face-piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA鈥檚
Respiratory Protection Standard (29 CFR 1910.134).
GENERAL HYGIENE CONSIDERATIONS
Contact with uncured sealant or with vapors generated during curing MAY CAUSE RESPIRATORY TRACT IRRITATION. Avoid
breathing vapor, mist, or dust. Keep container closed when not in use. Use only with adequate ventilation or wear an appropriate
NIOSH-approved respirator. MAY CAUSE SKIN AND EYE IRRITATION OR ALLERGIC REACTION. Avoid contact with eyes,
skin, and clothing. Wash thoroughly after handling. HARMFUL IF SWALLOWED. Do not taste or swallow.
9. PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Heavier than air EVAPORATION RATE (BuAc =1): <1
SPECIFIC GRAVITY: 1.1 - 1.3 MELTING/FREEZING POINT: Not Available
SOLUBILITY IN WATER: Negligible BOILING POINT: Not Available
VAPOR PRESSURE, mm Hg @ 20掳C: Not Available pH: Not Applicable
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT) Not Available
PHYSICAL STATE, APPEARANCE AND This product is a smooth paste with a mild medicinal odor and is available in a
COLOR variety of standard and custom colors including Black, Tru-White, Aluminum Stone,
Translucent, and Bronze.
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HOW TO DETECT THIS SUBSTANCE (WARNING PROPERTIES)
The appearance and odor of this product can act as warning properties in the event of an accidental release
CHEMICAL PROPERTIES
ODOR THRESHOLD: Not Available
VOC, less water and exempt: <100 g/L
Weight % VOC: (approx) 10%
o o
FLASH POINT: 3>300 F (>140 C) AUTOIGNITION TEMPERATURE: Not established
FLAMMABLE LIMITS (in air by volume, %):
Lower: NA Upper: NA
10. STABILITY and REACTIVITY
CHEMICAL STABILITY
Stable under normal circumstances of use and handling. Product slowly cures upon contact with moisture in air.
CONDITIONS TO AVOID
Avoid contact with incompatible chemicals and exposure to extreme temperatures.
INCOMPATIBLE MATERIALS
This product is not compatible with strong bases, strong acids, and powerful oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition of this product can generate dusts, irritating fumes, and toxic gases (e.g., Carbon monoxide, Carbon dioxide).
POSSIBILITY OF HAZARDOUS REACTIONS
This product is not expected to undergo hazardous polymerization, decomposition, condensation or self-reactivity. Product slowly
cures upon contact with moisture in air.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA
There are currently no toxicity data available for this product; the following toxicology information is available for components greater
than 1% in concentration.
The following data are available for Carbon black:
LD50 (rat), > 8000 mg/kg
skin (rabbit), non-irritative, index score 0.6/8 (4.0 = severe edema) Mouse, oral, duration 2 years
eye (rabbit), non-irritative, Draize score 10-17/110 (100 maximally irritating) Effect: no tumors
Rat, inhalation, duration 90 days Mouse, dermal, duration 18 months
Target organ: lungs Effect: no skin tumors
Effect: inflammation, hyperplasia, fibrosis Rat, inhalation, duration 2 years
NOEL = 1.1 mg/m3 Target organ: lungs.
Rat, oral, duration 2 years Effect: inflammation, fibrosis, tumors
Effect: no tumors
Tumors in the rat lung are related to the fine particle overload phenomenon rather than to a specific chemical effect
of the dust particles in the lung. These effects in rats have been reported in studies on other inorganic insoluble
particles and appear to be species specific. Tumors have not been observed in other species (i.e., mouse and
hamster) for carbon black under similar circumstances and study conditions.
The following data are available for Silicon dioxide:
Unscheduled DNA Synthesis-Rat-Intratracheal 120 mg/kg Intraperitoneal-Rat LDLo:50 mg/kg
Body Fluid Assay-Rat:lung 120 mg/kg Intravenous-Rat LD50:15 mg/kg
Inhalation-Rat TCLo:50 mg/m3:Carcinogenic effects Intratracheal-Rat LDLo:10 mg/kg
Oral-Rat LD50:3160 mg/kg Intraperitoneal-Guinea Pig, adult LDLo:120 mg/kg
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11. TOXICOLOGICAL INFORMATION (Continued)
The following data are available for Limestone:
Oral-Rat: LD50: 6450 mg/kg
The following data are available for Methyl ethyl ketoxime:
Inhalation-Rat, male: liver tumorogen Dermal-Rabbit LD50: 200 碌L/kg
Intraperitoneal-Rat LD50 200 mg/kg Irritancy, eye, Draize test, rabbit: 100 uL, Severe
Subcutaneous-Rat LD50 2702 mg/kg Oral-mouse: LD50 = 1000 mm/kg
Oral-Rat LD50: 930 mg/kg
SUSPECTED CANCER AGENT
The following table summarizes the carcinogenicity listing for the components of this product. 鈥淣O鈥? indicates that the substance is
not considered to be, or suspected to be, a carcinogen by the listed agency, see section 16 for definition of other ratings.
CHEMICAL IARC NTP NIOSH ACGIH OSHA PROP 65
Polydimethyl siloxane diol No No No No No No
Mineral spirits No No No No No No
Calcium carbonate No No No No No No
Carbon black 2B No No No No Yes
Methyl ethyl ketoxime No No No No No No
Mullite No No No No No No
Polyamino silane No No No No No No
Phenyl oximino silane No No No No No No
Silicon dioxide 3, inadequate No No No No No
evidence
Titanium dioxide 2B No No A4 No No
Aluminum No No No No No No
Quartz 1 Yes Carcinogen A2 No Yes
IARC Group 2B: Sufficient evidence in animals and inadequate evidence in humans. IARC Group 3: Unclassifiable as to carcinogenicity in humans. ACGIH A2: Sufficient
evidence in animals and inadequate evidence in humans . A4: Not Classifiable as a Human Carcinogen.
IRRITANCY OF PRODUCT
This product can be irritating to contaminated tissue. Prolonged exposure can lead to tissue damage.
SENSITIZATION TO THE PRODUCT
Prolonged contact with this product may cause skin sensitization.
TOXICOLOGICAL SYNERGISTIC PRODUCTS
None.
REPRODUCTIVE TOXICITY INFORMATION
Listed below is information concerning the effects of this product and its components on the human reproductive system.
MUTAGENICITY: When used as directed, this product is not expected to produce mutagenic effects in humans.
EMBRYOTOXICITY: When used as directed, this product is not expected to produce embryotoxic effects in humans.
TERATOGENICITY: When used as directed, this product is not expected to produce teratogenic effects in humans.
REPRODUCTIVE TOXICITY: When used as directed, this product is not expected to produce reproductive toxicity in humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An
embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not
propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across
generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs)
There are no BEI鈥檚 established for any component of this product at this time.
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12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY
This product can be harmful to terrestrial plant and animal life if large volumes of it are released into the environment. Refer to Section
11, 鈥淭oxicological Information鈥?, for specific animal data. This product can be harmful to animal life if large volumes of it are released
into an aquatic environment. The following aquatic toxicity data is available for components of this product:
Carbon black
Acute algae toxicity: EC 50 (72 h) > 10,000 mg/l, NOEC 50 > 10,000 mg/l (Scenedesmus subspicatus),
(OECD Guideline 201).
12.1.2 Acute fish toxicity: LC50 (96 h) > 1000mg/l, Brachydanio rerio (zebrafish), (OECD Guideline 203).
12.1.3 Acute water flea toxicity: EC50 (24 h) > 5600 mg/l, Daphnia magna (waterflea), (OECD Guideline 202).
Activated sludge, EC0 (3 h) > 800 mg/l.
DEV L3 (TTC test)
PERSISTENCE/DEGRADABILITY
The following environmental data is available for components of this product:
Carbon black and Titanium dioxide can be persistent in the environment.
BIOACCUMULATION/ACCUMULATION
There is no accumulation data for any component of this product at this time.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL
Recover or recycle if possible. Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with
regulations of Canada.
EPA WASTE NUMBER
As supplied, this product would not be a hazardous waste as defined by U.S. federal regulation (40 CFR 261) if discarded or disposed.
State and local regulations may differ from federal regulations. The generator of the waste is responsible for proper waste determination
and management.
14. TRANSPORTATION INFORMATION
BASIC SHIPPING DESCRIPTION
This product is not hazardous per 49 CFR 172.101, the U.S. Department of Transportation or Transport Canada Transportation of
Dangerous Goods Regulations or International Air Transport Association (IATA) Regulations or International Maritime Organization
Regulations (IMO) or International Civil Aviation Organization (ICAO) .
Pecora 890NST Non-Staining TechnologyTM July 13, 2007
Page 9 of 12
14. TRANSPORTATION INFORMATION (Continued)
PROPER SHIPPING NAME: Not Regulated
HAZARD CLASS NUMBER and DESCRIPTION: Not Regulated
UN IDENTIFICATION NUMBER: Not Regulated
DOT LABEL(S) REQUIRED: Not Regulated
PACKAGING GROUP: Not Regulated
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): Not Regulated
MARINE POLLUTANT: No component is designated as a DOT
Marine Pollutant.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS - EPA REPORTING REQUIREMENTS
The following reporting requirements are applicable to components of this product:
CHEMICAL SECTION 302 EHS (TPQ) SECTION 304 RQ SECTION 313 TRI (threshold)
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Polydimethyl siloxane diol No No No
Mineral spirits No No No
Calcium carbonate No No No
Carbon black No No No
Glass, oxide No No No
Methyl ethyl ketoxime No No No
Mullite No No No
Phenyl oximino silane No No No
Polyamino silane No No No
Silicon dioxide No No No
Titanium dioxide No No No
Aluminum No No No
Quartz No No No
U.S. SARA SECTION 311/312 FOR PRODUCT:
Acute health effects; chronic health effects.
U.S. TSCA INVENTORY STATUS:
The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS:
Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
Components of this product are found on either the Proposition 65 Carcinogen List or the Adverse Reproductive Effects List.
Carbon black: Carbon black (airborne, unbound particles of respirable size). Quartz.
WARNING: This product contains chemicals known to the State of California to cause cancer.
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Page 10 of 12
15. REGULATORY INFORMATION (Continued)
GLOBAL HARMONIZATION SYSTEM WARNINGS
Risk Phrases: R23/24 Toxic by inhalation and in contact with skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R42 May cause sensitization by inhalation.
Safety Phrases: S7 Keep container tightly closed.
S13 Keep away from food, drink and animal feeding stuffs.
S15 Keep away from heat.
S20/21 When using do not eat, drink or smoke.
S23 Do not breathe fumes generated during curing
S24/25 Avoid contact with skin and eyes.
S26/28 In case of contact with skin or eyes, rinse thoroughly with water. Seek medical assistance
if irritation persists.
Symbols:
ADDITIONAL CANADIAN REGULATIONS
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL or NDSL Inventory.
16. OTHER INFORMATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information presented in this Material Safety Data Sheet is presented in good faith based on data believed to be accurate as of
the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS
FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED
REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO
BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR
THE HAZARDS RELATED TO ITS USE. In no case shall the descriptions, information, data or designs provided be considered
a part of our terms and conditions of sale.
All materials may present hazards and should be used with caution. Because many factors may affect processing or
application/use, we recommend that you make tests to determine the suitability of a product for your particular purpose prior to
use. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to
recommended practices or applicable federal, state, or local laws or regulations. The information provided above, and the
product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of
the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is
given nor implied to practice any patented invention without a license.
DATE OF PRINTING July 13, 2007
Pecora 890NST Non-Staining TechnologyTM July 13, 2007
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DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
KEY ACRONYMS: FLAMMABILITY LIMITS IN AIR:
CHEMTREC 鈥? Chemical Transportation Emergency Center, a 24-hour Much of the information related to fire and explosion is derived from the
emergency information and/or emergency assistance to emergency responders. National Fire Protection Association (NFPA). Flash Point - Minimum
CAS # - This is the Chemical Abstract Service Number that uniquely identifies temperature at which a liquid gives off sufficient vapors to form an ignitable
each compound. mixture with air. Autoignition Temperature: The minimum temperature
ACGIH - American Conference of Governmental Industrial Hygienists, a required to initiate combustion in air with no other source of ignition. LEL - the
professional association which establishes exposure limits. lowest percent of vapor in air, by volume, that will explode or ignite in the
TLV - Threshold Limit Value - an airborne concentration of a substance that presence of an ignition source. UEL - the highest percent of vapor in air, by
represents conditions under which it is generally believed that nearly all workers volume, that will explode or ignite in the presence of an ignition source.
can be repeatedly exposed without adverse effect. The duration must be
considered, including the 8-hour Time Weighted Average (TWA), the 15- TOXICOLOGICAL INFORMATION:
minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Possible health hazards as derived from human data, animal studies, or from the
Skin absorption effects must also be considered. results of studies with similar compounds are presented. Definitions of some
OSHA - U.S. Occupational Safety and Health Administration. terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills
PEL - Permissible Exposure Limit - This exposure value means exactly the 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills
same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible 50% of the exposed animals; ppm concentration expressed in parts of material
per million parts of air or water; mg/m3 concentration expressed in weight of
Exposure Limits are based in the 1989 PELs and the June, 1993 Air
Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both substance per volume of air; mg/kg quantity of material, by weight,
the current PELs and the vacated PELs are indicated. The phrase, 鈥淰acated administered to a test subject, based on their body weight in kg. Other measures
1989 PEL,鈥? is placed next to the PEL that was vacated by Court Order. of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the
IDLH - Immediately Dangerous to Life and Health - This level represents a lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo,
concentration from which one can escape within 30-minutes without suffering and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI
escape-preventing or permanent injury. The DFG - MAK is the Republic of - Biological Exposure Indices, represent the levels of determinants which are
Germany鈥檚 Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the most likely to be observed in specimens collected from a healthy worker who
National Institute of Occupational Safety and Health, which is the research arm has been exposed to chemicals to the same extent as a worker with inhalation
of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH exposure to the TLV. Ecological Information: EC is the effect concentration in
issues exposure guidelines called Recommended Exposure Levels (RELs). water.
When no exposure guidelines are established, an entry of NE is made for Data from several sources are used to evaluate the cancer-causing potential of
reference. the material. The sources and ratings are: IARC - the International Agency for
OEL 鈥? Occupational Exposure Level 鈥? In some cases, specific exposure Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably
guidelines have been assigned by industry. These are referred to as carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and
鈥淥ccupational Exposure Levels.鈥? 4 = Probably not carcinogenic to humans. NTP - the National Toxicology
Program; K =Known to be a human carcinogen, and R = Reasonably anticipated
to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical
HAZARD RATINGS:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS庐): Substances. OSHA - Occupational Safety and Health Administration and
Health Hazard: 0 (minimal acute exposure hazard); 1 (slight acute exposure CAL/OSHA - California鈥檚 subunit of the Occupational Safety and Health
hazard); 2 (moderate acute exposure hazard); 3 (serious acute exposure hazard; Administration; Ca = Carcinogen defined with no further categorization.
onetime overexposure can require medical treatment and cause permanent ACGIH 鈥? American Conference of Governmental Industrial Hygienists; A1 =
injury); 4 (severe acute exposure hazard; onetime overexposure can be fatal). Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 =
An 鈥?*鈥? indicates that the health hazard is chronic. Flammability Hazard: 0 Confirmed animal carcinogen with unknown relevance to humans, A4 = Not
(minimal hazard); 1 (materials that require substantial pre-heating before classifiable as a human carcinogen, and A5 = Not suspected as a human
carcinogen. NIOSH 鈥? U.S. National Institute for Occupational Safety and
burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93掳C
Health; Ca = Potential occupational carcinogen, with no further categorization.
[100-200掳F]); 3 (Class IB and IC flammable liquids with flash points below 38掳
EPA 鈥? U.S. Environmental Protection; A = Human carcinogen, B = Probable
C [100掳F]); 4 (Class IA flammable liquids with flash points below 23掳C [73掳F]
human carcinogen, C = Possible human carcinogen, D = Not classifiable as to
and boiling points below 38掳C [100掳F]. Physical/ Reactivity Hazard: 0
human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K =
(normally stable); 1 (material that can become unstable at elevated temperatures
Known human carcinogen, L = Likely to produce cancer in humans, CBD =
or which can react slightly with water); 2 (materials that are unstable but do not
Cannot be determined, NL = Not likely to be carcinogenic in humans, and I =
detonate or which can react violently with water); 3 (materials that can detonate
Data are inadequate for an assessment of human carcinogenic potential.
when initiated or which can react explosively with water); 4 (materials that can
detonate at normal temperatures or pressures).
REGULATORY INFORMATION:
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
This section explains the impact of various laws and regulations on the material.
(material that on exposure under fire conditions would offer no hazard beyond
EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian
that of ordinary combustible materials); 1 (materials that on exposure under fire
Workplace Hazardous Materials Information System. DOT and TC are the U.S.
conditions could cause irritation or minor residual injury); 2 (materials that on
Department of Transportation and the Transport Canada, respectively.
intense or continued exposure under fire conditions could cause temporary
Superfund Amendments and Reauthorization Act (SARA); the Canadian
incapacitation or possible residual injury); 3 (materials that can on short
Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic
exposure could cause serious temporary or residual injury); 4 (materials that
Substance Control Act (TSCA); Marine Pollutant status according to the DOT;
under very short exposure could cause death or major residual injury).
the Comprehensive Environmental Response, Compensation, and Liability Act
Flammability Hazard and Reactivity Hazard: Refer to definitions for
(CERCLA or Superfund); and various state regulations. This section also
鈥淗azardous Materials Identification System鈥?.
includes information on the precautionary warnings that appear on a material鈥檚
industrial package label.
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