ISO9001:2000 Certified
Material Safety Data Sheet
Manganous sulfate solutions
Section 1 - Chemical Product and Company Identification
MSDS Name:
Manganous sulfate solutions
Catalog Numbers:
Q06561, Q07561
Synonyms:
Company Identification:
Qorpak
1195 Washington Pike
Bridgeville, PA 15017
Company Phone Number:
(412) 257-3100
Emergency Phone Number:
(800) 424-9300
CHEMTREC Phone Number:
(800) 424-9300
Section 2 - Composition, Information on Ingredients
Percent
CAS# Chemical Name:
7732-18-5 Water balance
10034-96-5 Manganese sulfate monohydrate 0.05-36.4
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: Pink
Caution! May cause eye and skin irritation.
Target Organs: none known.
Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
May cause mild skin irritation.
Ingestion:
Manganese salts are poorly absorbed, but may cause gastritis, nausea, diarrhea, and hypoglycemia.
Material Safety Data Sheet
Manganous sulfate solutions
Inhalation:
Inhalation may cause respiratory tract, cough, muscular twitchings.
Chronic:
May cause conjunctivitis. Inhalation may lead to bronchitis, pneumonia, headache,numbness of extremities,
dermatitis, liver enlargement. Ingestion may cause symptoms of severe central nervous system disturbances.
Section 4 - First Aid Measures
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence
of chemical remains. Get medical aid at once.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing
contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
Get medical aid at once. Give oxygen if respiration is depressed.
Inhalation:
Give artificial respiration if necessary. Get medical aid. Keep victim warm, at rest. Move victim to fresh air.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information:
Negligible fire and explosion hazard when exposed to heat or flame. Move container if possible, avoid breathing
vapors or dust.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
Autoignition Temperature:
No information found.
Flash Point:
No information found.
NFPA Rating:
CAS# 7732-18-5: Not published.
CAS# 10034-96-5: Not published.
Explosion Limits:
Lower: Upper:
Section 6 - Accidental Release Measures
General Information:
Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal.
Material Safety Data Sheet
Manganous sulfate solutions
Section 7 - Handling and Storage
Handling:
Wash thoroughly after handling. Avoid breathing dust, vapor, mist, or gas.
Storage:
Store capped at room temperature. Protect from heat and incompatibles.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:
Provide local exhaust or general dilution ventilation.
Exposure Limits
Chemical Name: ACGIH NIOSH OSHA
None of the components None of the components
None of the components
Water
are on this list. are on this list.
are on this list.
None of the components None of the components
None of the components
Manganese sulfate monohydrate
are on this list. are on this list.
are on this list.
OSHA Vacated PELs
Personal Protective Equipment
Eyes:
Do not wear contact lenses when working with chemicals. An eye wash fountain should be available in the immediate
work area. Wear splash-proof safety goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Not required for normal use. Firefighting-- any self-contained breathing apparatus with full facepiece operated in
pressure-demand mode.
Section 9 - Physical and Chemical Properties
Physical State: Clear liquid
Color: Pink
Odor: Odorless
pH: 4-7
Vapor Pressure: 14mm Hg @20掳C
Vapor Density: 0.7 (H2O)
Evaporation Rate: < ether
Viscosity: No information found.
Boiling Point: > 212掳F (> 100.00掳C)
Freezing/Melting Point: < 32掳F (< 0.00掳C)
Material Safety Data Sheet
Manganous sulfate solutions
Decomposition Temperature: No information found.
Solubility in water: Soluble.
Specific Gravity/Density: 1.0
Molecular Formula: No information found.
Molecular Weight No information found.
Section 10 - Stability and Reactivity
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials
None reported.
Hazardous Decomposition Products
Oxides of sulfur.
Hazardous Polymerization
Has not been reported
Section 11 - Toxicological Information
RTECS:
CAS# 7732-18-5: ZC0110000.
CAS# 10034-96-5: OP0893500.
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg.
CAS# 10034-96-5:
No information found.
Carcinogenicity:
CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65.
CAS# 10034-96-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65.
Epidemiology:
Manganous sulfate solution is highly toxic by intraperitoneal routes, but is poorly absorbed through inhalation or
ingestion. Causes irritation to eyes and mucous membranes.
Teratogenicity:
Reproductive:
Mutagenicity:
Neurotoxicity:
Section 12 - Ecological Information
No information found.
Material Safety Data Sheet
Manganous sulfate solutions
Section 13 - Disposal Considerations
Dispose of in accordance with Federal, State, and local regulations.
Section 14 - Transport Information
US DOT
Shipping Name: Not regulated
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US Federal
TSCA
CAS# 7732-18-5 is listed on the TSCA Inventory.
CAS# 10034-96-5 is not on the TSCA Inventory, however, its anhydrous form is on the inventory and so this hydrate
is exempt from TSCA Inventory requirements (40CFR270.3(u)(2)).
SARA Reportable Quantities (RQ)
None of the components are on this list.
CERCLA/SARA Section 313
None of the components are on this list.
OSHA - Highly Hazardous
None of the components are on this list.
US State
State Right to Know
California Regulations
European/International Regulations
Canadian DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada Ingredient Disclosure List
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10034-96-5 is not listed on Canada's Ingredient Disclosure List.
Section 16 - Other Information
MSDS Creation Date: February 19, 1998
Revision Date: February 27, 2007
Material Safety Data Sheet
Manganous sulfate solutions
Information in this MSDS is from available published sources and is believed to be accurate. No warranty,
express or implied, is made and Qorpak assumes no liability resulting from the use of this MSDS. The user
must determine suitability of this information for his application.
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