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MSDS Material Safety Data Sheet
CAS

163440-98-0
14228-73-0

File Name: resins_com---K8134.asp
Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information

EPON鈩? Resin 58042
Trade name :

Product code : K8134

MSDS Number : 1638

Product Type : Epoxy resin.

Manufacturer, importer, : Hexion Specialty Chemicals, Inc.
supplier P. O. Box 4500
Houston TX 77210

Contact person : hsebox@hexion.com

Telephone : General Information:
(832) 486-6700

Emergency telephone:
CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887


SECTION 2. HAZARDS IDENTIFICATION


Emergency Overview

Human health hazards : May be irritating to the eyes and skin. May be moderately toxic
if swallowed. May cause skin sensitization.

Safety hazards : Material will not burn unless preheated.



SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS


Chemical Name CAS-No. Weight %

2-Propenenitrile, polymer with 1,3-butadiene, 163440-98-0 60 % - 70 %
3-carboxy-1-cyano-1-methylpropyl-terminated,
polymers with 2,2'-[1,4-cyclohexanediylbi
Oxirane, 14228-73-0 30 % - 40 %
2,2'-[1,4-cyclohexanediylbis(methyleneoxymethylene)]
bis-

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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007



SECTION 4. FIRST AID MEASURES

Inhalation : Remove victim to fresh air and provide oxygen if breathing is
difficult. Give artificial respiration if not breathing. Get medical
attention.

Skin contact : Remove contaminated clothing/shoes and wipe excess from
skin. Flush skin with water. Follow by washing with soap and
water. In case of inflammation (redness, irritation, ...) obtain
medical attention. Show this sheet to the doctor. Do not reuse
clothing until cleaned. Contaminated leather articles, including
shoes, cannot be decontaminated and should be destroyed to
prevent reuse.

Eye contact : Flush eyes with plenty of water for 15 minutes while holding
eyelids open. Get medical attention.

Ingestion : Do not induce vomiting. In general, no treatment is necessary
unless large quantites of product are ingested. However, get
medical advice.

Notes to physician

Symptoms : Irritation as noted above. Skin sensitization (allergy) may be
evidenced by rashes, especially hives.

Treatment : In general, emesis induction is unnecessary in high viscosity,
low volatility products.



SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing : Use water fog, foam, dry chemical or carbon dioxide.
media

Specific hazards during fire : Material will not burn unless preheated.
fighting

Cool fire exposed containers with water.

Special protective : Do not enter confined fire space without full bunker gear (helmet
equipment for fire-fighters with face shield, bunker coats, gloves and rubber boots).
including a positive pressure NIOSH approved self-contained
breathing apparatus.




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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007



SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : May burn although not readily ignitable.
Use cautious judgement when cleaning up large spills.
Shut off leaks, if possible without personal risk.

Environmental precautions : Dike and contain.
Contain run-off and dispose of properly.
Prevent from entering into drains, ditches or rivers.

Clean-up methods - small : Take up with an absorbent material and dispose of properly.
spillage

Clean-up methods - large : Remove with vacuum trucks or pump to storage/salvage
spillage vessels.
Soak up residue with an absorbent such as clay, sand or other
suitable material; place in non-leaking containers for proper
disposal.
Flush area with water to remove trace residue.


Additional advice : Notify authorities if any exposures to the general public or
environment occurs or is likely to occur.
See Section 13 for information on disposal.



SECTION 7. HANDLING AND STORAGE

Handling
Advice on safe handling : WARNING. May be moderately toxic if swallowed. May cause
skin, eye, and respiratory tract irritation. May cause skin
sensitization. Minimize all contact with material. Wash with
soap and water before eating, drinking, smoking, applying
cosmetics, or using toilet facilities. Launder contaminated
clothing before reuse. Contaminated leather articles, including
shoes, cannot be decontaminated and should be destroyed to
prevent reuse. To prevent thermal burns avoid contact with hot
product.

Storage
Requirements for storage : Store in a cool, dry place with adequate ventilation. Keep away
areas and containers from open flames and high temperatures.




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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007



SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Protective measures : Wear appropriate respirator and protective clothing.

Engineering measures : Use ventilation as required to control vapor concentrations.
Eye wash fountains and safety showers should be available for
emergency use.

Eye protection : Avoid contact with eyes.
Wear chemical goggles if there is potential contact with eyes.

Skin and body protection : Avoid prolonged or repeated contact with skin.
Wear chemical-resistant gloves and other clothing as required to
minimize contact.

Respiratory protection : Avoid prolonged or repeated breathing of vapors or mists.
Use a NIOSH-approved respirator as required to prevent
overexposure.
In accord with 29 CFR 1910.134,
Use either a full-face, atmosphere-supplying respirator or
air-purifying respirator for organic vapors.
Avoid breathing vapors which may be produced under some
conditions such as heating or applications of uncured material in
large surface areas (e.g., flooring and painting).
Avoid breathing aerosols and mists which may be formed by
various methods of application.


Exposure Guidelines


Components with Regulation Exposure time Value Remarks
workplace control
parameters
2-Propenenitrile, polymer ACGIH None established.
with 1,3-butadiene,
3-carboxy-1-cyano-1-meth
ylpropyl-terminated,
polymers with
2,2'-[1,4-cyclohexanediylbi
Oxirane, ACGIH None established.
2,2'-[1,4-cyclohexanediylbi
s(methyleneoxymethylene
)]bis-


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Mobile liquid
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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007



Colour : Colourless

Odour : Mild

Boiling point : > 149 掳C (> 300 掳F)

Flash point : > 93.33 掳C (> 199.99 掳F) (Setaflash)

Vapour pressure : < 1.33 mbar at 20 掳C (68 掳F)

Relative density : 1.02

Solubility in water : Negligible.



SECTION 10. STABILITY AND REACTIVITY

Materials to avoid : Can react vigorously with strong oxidizing agents, strong lewis
or mineral acid, and strong mineral and organic bases,
especially primary and secondary aliphatic amines.
Reacts with considerable heat release with some curing
agents.

Hazardous decomposition : Carbon monoxide, aldehydes, and acids may be formed during
products combustion.


Hazardous reactions : Stable.

Hazardous polymerization will not occur.



SECTION 11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : Expected to be of low toxicity, LD50 > 2000 mg/kg.

Chronic Health Hazard

Components Concentration Regulation Value Remarks




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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007


2-Propenenitrile, 60 % - 70 % US. IARC Monographs on This
polymer with Occupational Exposures to component
1,3-butadiene, Chemical Agents has not been
3-carboxy-1-cyan classified by
o-1-methylpropyl-t the
erminated, International
polymers with Agency for
2,2'-[1,4-cyclohex Research on
anediylbi Cancer
(IARC).
Oxirane, 30 % - 40 % US. IARC Monographs on This
2,2'-[1,4-cyclohex Occupational Exposures to component
anediylbis(methyl Chemical Agents has not been
eneoxymethylene) classified by
]bis- the
International
Agency for
Research on
Cancer
(IARC).


Potential Health Effects

Inhalation : Not expected to be a relevant route of exposure, however,
under conditions where exposure to vapors or mists is possible,
could cause respiratory tract irritation.

Skin : May be moderately irritating to the skin.
May cause skin sensitization.

Eyes : May be irritating to the eyes.

Ingestion : Not likely to be a relevant route of exposure.
May be moderately toxic and may be harmful if swallowed.

Aggravated Medical : Preexisting eye,skin and respiratory disorders may be
Condition aggravated by exposure to this product.



SECTION 12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability)
Biodegradability : This section will be updated as ecological reviews are
completed.

Ecotoxicity effects

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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007

Toxicity to fish : This section will be updated as ecological reviews are
completed.




SECTION 13. DISPOSAL CONSIDERATIONS

Product disposal : If this material becomes a waste, it would not be a hazardous
waste by RCRA criteria (40 CFR 261). Place in an appropriate
disposal facility in compliance with local and federal regulations.



SECTION 14. TRANSPORT INFORMATION


NOT REGULATED FOR TRANSPORT
CFR_ROAD

NOT REGULATED FOR TRANSPORT
IMDG

NOT REGULATED FOR TRANSPORT
IATA_C




SECTION 15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.
Notification status
TSCA : All components listed.

EINECS : Not all components listed.

DSL : All components listed.

AICS : Not all components listed.

INV (CN) : All components listed.

KECI (KR) : Not all components listed.

PICCS (PH) : Not all components listed.

ENCS (JP) : Not all components listed.



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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007

US. EPA CERCLA Hazardous Substances (40 CFR 302)

2-Propenenitrile, polymer with No RQ
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-te
rminated, polymers with
2,2'-[1,4-cyclohexanediylbi

Oxirane, No RQ
2,2'-[1,4-cyclohexanediylbis(methyle
neoxymethylene)]bis-

SARA 311/312 Hazards

Acute Health Hazard
Chronic Health Hazard

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 313 Toxic Chemicals(40 CFR 372. 65) - Supplier Notification Required

2-Propenenitrile, polymer with No De minimis Concentration
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-te
rminated, polymers with
2,2'-[1,4-cyclohexanediylbi

Oxirane, No De minimis Concentration
2,2'-[1,4-cyclohexanediylbis(methyle
neoxymethylene)]bis-

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)

2-Propenenitrile, polymer with Threshold Planning Quantity: No TPQ
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-te
rminated, polymers with
2,2'-[1,4-cyclohexanediylbi

Oxirane, Threshold Planning Quantity: No TPQ
2,2'-[1,4-cyclohexanediylbis(methyle
neoxymethylene)]bis-

2-Propenenitrile, polymer with Reportable quantity: No RQ
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-te
rminated, polymers with
2,2'-[1,4-cyclohexanediylbi



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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007

Oxirane, Reportable quantity: No RQ
2,2'-[1,4-cyclohexanediylbis(methyle
neoxymethylene)]bis-

New Jersey Right-To-Know Chemical List

2-Propenenitrile, polymer with Not Listed
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-ter
minated, polymers with
2,2'-[1,4-cyclohexanediylbi

Oxirane, Not Listed
2,2'-[1,4-cyclohexanediylbis(methylen
eoxymethylene)]bis-

Additional Components Not Found In Section 2:

Components CAS-No. Concentration Remarks
1,3-Butadiene 106-99-0 < 5 PPM Listed.
1-chloro-2,3-epoxy propane 106-89-8 < 5 PPM Listed.
2-Propenenitrile 107-13-1 < 40 PPM Listed.

Pennsylvania Right-To-Know Chemical List

2-Propenenitrile, polymer with Not Listed
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-ter
minated, polymers with
2,2'-[1,4-cyclohexanediylbi

Oxirane, Not Listed
2,2'-[1,4-cyclohexanediylbis(methylen
eoxymethylene)]bis-

Additional Components Not Found In Section 2:

Components CAS-No. Concentration Remarks
1,3-Butadiene 106-99-0 < 5 PPM Special hazard.
1-chloro-2,3-epoxy propane 106-89-8 < 5 PPM Special hazard.
2-Propenenitrile 107-13-1 < 40 PPM Special hazard.

Massachusetts Right-To-Know Chemical List




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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007

2-Propenenitrile, polymer with Not Listed
1,3-butadiene,
3-carboxy-1-cyano-1-methylpropyl-ter
minated, polymers with
2,2'-[1,4-cyclohexanediylbi

Oxirane, Not Listed
2,2'-[1,4-cyclohexanediylbis(methylen
eoxymethylene)]bis-

Additional Components Not Found In Section 2:

Components CAS-No. Concentration Remarks
1,3-Butadiene 106-99-0 < 5 PPM Carcinogenic.
1-chloro-2,3-epoxy propane 106-89-8 < 5 PPM Carcinogenic.
2-Propenenitrile 107-13-1 < 40 PPM Carcinogenic.

US. California Safe Drinking Water & Toxic Enfor cement Act (Proposition 65)
Additional Components Not Found In Section 2:

Components Concentration Regulation Value Remarks
1,3-Butadiene < 5 PPM US. California Safe Drinking Listed: April Carcinogenic.
Water & Toxic Enfor cement 1, 1988
Act (Proposition 65)

Components Concentration Regulation Value Remarks
1-chloro-2,3-epox < 5 PPM US. California Safe Drinking Listed: Carcinogenic.
y propane Water & Toxic Enfor cement October 1,
Act (Proposition 65) 1987


Components Concentration Regulation Value Remarks
2-Propenenitrile < 40 PPM US. California Safe Drinking Listed: July Carcinogenic.
Water & Toxic Enfor cement 1, 1987
Act (Proposition 65)

HMIS Rating : Health: 2
Fire: 1
Reactivity: 0



SECTION 16. OTHER INFORMATION


Reference : Prepared in accordance with 29 CFR 1910.1200.



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Material Safety Data Sheet


EPON鈩? Resin 58042
Version 7.1 Print Date 07/06/2007
Revision Date 06/02/2007

The information provided herein was believed by Hexion Specialty Chemicals ("Hexion") to be accurate at the
time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to
investigate and understand other pertinent sources of information, to comply with all laws and procedures
applicable to the safe handling and use of the product and to determine the suitability of the product for its
intended use. All products supplied by Hexion are subject to Hexion's terms and conditions of sale. HEXION
MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF
ANY INFORMATION PROVIDED BY HEXION, except that the product shall conform to Hexion's specifications.
Nothing contained herein constitutes an offer for the sale of any product.
庐 鈩?
and Licensed trademarks of Hexion Specialty Chemicals, Inc.

A vertical bar ( | ) in the left margin indicates an amendment from the previous version.




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