Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
EPIKURE鈩? 3300 Curing Agent
Trade name :
Product code : K9110
MSDS Number : 4197
Product Type : Curing agent.
Manufacturer, importer, : Hexion Specialty Chemicals, Inc.
supplier P. O. Box 4500
Houston TX 77210
Contact person : hsebox@hexion.com
Telephone : General Information:
(832) 486-6700
Emergency telephone:
CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Human health hazards : May be corrosive to the eyes. May be corrosive to the skin.
Slightly toxic and may be harmful if absorbed through the skin.
May be harmful if swallowed. Irritating to respiratory system.
May cause skin sensitization.
Safety hazards : Material will not burn unless preheated.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Weight %
Isophoronediamine 2855-13-2 100 %
SECTION 4. FIRST AID MEASURES
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
Inhalation : Remove victim to fresh air and provide oxygen if breathing is
difficult. Give artificial respiration if not breathing. Get medical
attention.
Skin contact : Immediately remove contaminated clothing or shoes, wipe
excess from skin and flush with plenty of water for at least 15
minutes. Use soap if available or follow by washing with soap
and water. Do not reuse clothing until thoroughly cleaned. Get
medical attention.
Eye contact : Immediately flush eyes with plenty of water for 15 minutes while
holding eyelids open. Rinse continuously with water while on
way to get medical attention
Ingestion : Do not induce vomiting. Have victim rinse out mouth with water,
then drink sips of water to remove taste from mouth. Do not give
liquids to a drowsy, convulsing or unconscious person. If
vomiting occurs spontaneously, keep head below hips to
prevent aspiration. Get medical attention.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Use water fog, "alcohol foam", dry chemical or carbon dioxide.
media
Specific hazards during fire : DANGER. Corrosive. Material will not burn unless preheated.
fighting
Evacuate the area of all non-essential personnel. Cool fire
exposed containers with water. Containers exposed to intense
heat from fires should be cooled with water to prevent vapor
pressure buildup which could result in container rupture.
Container areas exposed to direct flame contact should be
cooled with large quantities of water as needed to prevent
weakening of container structure.
Special protective : Do not enter confined fire space without full bunker gear (helmet
equipment for fire-fighters with face shield, bunker coats, gloves and rubber boots).
including a positive pressure NIOSH approved self-contained
breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Corrosive.
May burn although not readily ignitable.
Prevent all bodily contact with spilled material.
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
Use cautious judgement when cleaning up large spills.
Shut off leaks, if possible without personal risk.
Remove ignition sources.
Environmental precautions : Dike and contain.
Contain run-off and dispose of properly.
Prevent from entering into drains, ditches or rivers.
Clean-up methods - small : Take up with an absorbent material and place in non-leaking
spillage containers.
Seal tightly for proper disposal.
Clean-up methods - large : Remove with vacuum trucks or pump to storage/salvage
spillage vessels.
Soak up residue with an absorbent such as clay, sand or other
suitable material; place in non-leaking containers for proper
disposal.
Flush area with water to remove trace residue.
Additional advice : Notify authorities if any exposures to the general public or
environment occurs or is likely to occur.
See Section 13 for information on disposal.
SECTION 7. HANDLING AND STORAGE
Handling
Advice on safe handling : Do not get in eyes, on skin or on clothing. Do not taste or
swallow. Do not breathe material. Use only with adequate
ventilation. Avoid contact with skin, eyes and clothing Avoid
prolonged or repeated contact with skin, eyes and clothing
Wash thoroughly after handling. DANGER. May be corrosive to
the eyes. May be corrosive to the skin. Slightly toxic and may
be harmful if absorbed through the skin. May be harmful if
swallowed. Causes respiratory tract irritation. May cause skin
sensitization. Containers, even those that have been emptied,
can contain hazardous product residues. Wash with soap and
water before eating, drinking, smoking, applying cosmetics, or
using toilet facilities. Launder contaminated clothing before
reuse. Contaminated leather articles, including shoes, cannot
be decontaminated and should be destroyed to prevent reuse.
Storage
Requirements for storage : Keep containers closed when not in use.
areas and containers
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective measures : Wear appropriate respirator and full-body protective clothing.
Engineering measures : Use ventilation as required to control vapor concentrations.
Eye wash fountains and safety showers should be available for
emergency use.
Eye protection : Do not get in eyes.
Wear chemical goggles and face shield.
Skin and body protection : Do not get on skin, on clothing.
Wear chemical-resistant protective clothing such as gloves,
outer clothing or apron, overshoes and a face-shield suitable to
potential exposure.
Respiratory protection : Do not breathe vapors or mists.
Use a NIOSH-approved respirator as required to prevent
overexposure.
In accord with 29 CFR 1910.134, the types of respirator(s) to be
considered include:
Full-Face Air-Purifying Respirator for Organic Vapors.
Full-Face Supplied-Air Respirator.
Exposure Guidelines
Components with Regulation Exposure time Value Remarks
workplace control
parameters
Isophoronediamine ACGIH None established.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Colour : Colourless
Odour : Amine
pH : 14
Melting / freezing point : 10 掳C (50 掳F)
Boiling point : 247 掳C (477 掳F)
Flash point : 112 掳C (234 掳F) (Closed cup)
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
Vapour pressure : 0.01 mbar at 25 掳C (77 掳F)
Relative density : 0.924
Solubility in water : Completely miscible.
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Avoid high temperatures.
Hazardous reactions : Stable under normal use conditions.
Hazardous polymerization will not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : Moderately toxic, 400 < LD50 <= 2000 mg/kg.
Acute dermal toxicity : Moderately toxic, 1 < LC50 <= 5 mg/l.
Chronic Health Hazard
Components Concentration Regulation Value Remarks
Isophoronediamin 100 % US. IARC Monographs on This
e Occupational Exposures to component
Chemical Agents has not been
classified by
the
International
Agency for
Research on
Cancer
(IARC).
Potential Health Effects
Inhalation : Irritating to respiratory system.
Not expected to be a relevant route of exposure, however,
under conditions where exposure to vapors or mists is possible,
could cause respiratory tract irritation.
Skin : May be corrosive to the skin.
Slightly toxic and may be harmful if absorbed through the skin.
May cause skin sensitization.
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
Eyes : May be corrosive to the eyes and may cause severe damage,
including blindness.
Ingestion : May be harmful if swallowed.
SECTION 12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Biodegradability : This section will be updated as ecological reviews are
completed.
Ecotoxicity effects
Toxicity to fish : This section will be updated as ecological reviews are
completed.
SECTION 13. DISPOSAL CONSIDERATIONS
Product disposal : If this material becomes a waste material, it would be a corrosive
hazardous waste, hazardous waste number D002 (40 CFR
262). Refer to the latest EPA or state regulations regarding
proper disposal.
SECTION 14. TRANSPORT INFORMATION
: UN/NA-No 2289
DOT
Class 8
Packing group III
ERG No. 153
Proper shipping name ISOPHORONEDIAMINE
: UN-Number 2289
IMDG
Class 8
Packaging group III
EmS F-A S-B
Description of the goods ISOPHORONEDIAMINE
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
: UN-Number 2289
IATA
Cargo
Class 8
Packaging group III
ERG No. 153
Description of the goods ISOPHORONEDIAMINE
SECTION 15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.
Notification status
AICS : Listed.
DSL : Listed.
INV (CN) : Listed.
ENCS (JP) : Listed.
TSCA : Listed.
EINECS : Listed.
KECI (KR) : Listed.
PICCS (PH) : Listed.
y = Yes (Listed); AICS = Australian Inventory of Chemical
Notification status
Substances; DSL = Canadian Domestic Substances List;
Legend
INV(CN) = Inventory of Existing Chemicals Substances in
China; ENCS(JP) = Japanese Existing and New Chemical
Substances; TSCA = Toxic Substance Control Act; EINECS =
European Inventory of New and Existing Chemicals; KECI(KR)
= Korean Existing Chemicals Inventory; PICCS(PH) = Philippine
Inventory of Chemicals and Chemical Substances
US. EPA CERCLA Hazardous Substances (40 CFR 302)
Isophoronediamine No RQ
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
SARA 311/312 Hazards
Acute Health Hazard
Chronic Health Hazard
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 313 Toxic Chemicals(40 CFR 372. 65) - Supplier Notification Required
Isophoronediamine No De minimis Concentration
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
Isophoronediamine Threshold Planning Quantity: No TPQ
Isophoronediamine Reportable quantity: No RQ
New Jersey Right-To-Know Chemical List
Isophoronediamine Not Listed
Pennsylvania Right-To-Know Chemical List
Isophoronediamine Not Listed
Massachusetts Right-To-Know Chemical List
Isophoronediamine Not Listed
HMIS Rating : Health: 3
Fire: 1
Reactivity: 0
SECTION 16. OTHER INFORMATION
Reference : Prepared in accordance with 29 CFR 1910.1200.
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Material Safety Data Sheet
EPIKURE鈩? 3300 Curing Agent
Version 3.1 Print Date 07/06/2007
Revision Date 06/02/2007
The information provided herein was believed by Hexion Specialty Chemicals ("Hexion") to be accurate at the
time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to
investigate and understand other pertinent sources of information, to comply with all laws and procedures
applicable to the safe handling and use of the product and to determine the suitability of the product for its
intended use. All products supplied by Hexion are subject to Hexion's terms and conditions of sale. HEXION
MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF
ANY INFORMATION PROVIDED BY HEXION, except that the product shall conform to Hexion's specifications.
Nothing contained herein constitutes an offer for the sale of any product.
庐 鈩?
and Licensed trademarks of Hexion Specialty Chemicals, Inc.
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