The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont Page 1
Material Safety Data Sheet
----------------------------------------------------------------------
USED REFRIGERANTS AND REFRIGERANT BLENDS
6116FR Revised 7-MAY-2004
----------------------------------------------------------------------
----------------------------------------------------------------------
CHEMICAL PRODUCT/COMPANY IDENTIFICATION
----------------------------------------------------------------------
Tradenames and Synonyms
USED REFRIGERANT 11
USED REFRIGERANT 12
USED REFRIGERANT 13
USED REFRIGERANT 13B1
USED REFRIGERANT 14
USED REFRIGERANT 22
USED REFRIGERANT 23
USED REFRIGERANT 113
USED REFRIGERANT 114
USED REFRIGERANT 116
USED REFRIGERANT 123
USED REFRIGERANT 124
USED REFRIGERANT 125
USED REFRIGERANT 134a
USED REFRIGERANT 407C
USED REFRIGERANT 410A
USED REFRIGERANT 500
USED REFRIGERANT 502
USED REFRIGERANT 503
USED REFRIGERANT 508B
USED REFRIGERANT HP62
USED REFRIGERANT HP80
USED REFRIGERANT HP81
USED REFRIGERANT MP39
USED REFRIGERANT MP52
USED REFRIGERANT MP66
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont
1007 Market Street
Wilmington, DE 19898
PHONE NUMBERS
Product Information : 1-800-441-7515 (outside the U.S.
302-774-1000)
Transport Emergency : CHEMTREC 1-800-424-9300(outside U.S.
703-527-3887)
Medical Emergency : 1-800-441-3637 (outside the U.S.
302-774-1000)
6116FR DuPont Page 2
Material Safety Data Sheet
----------------------------------------------------------------------
COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------
Components
Material CAS Number %
REFRIGERANT COMPONENTS
*METHANE, TRICHLOROFLUORO- 75-69-4 <100
(Refrigerant 11)
*METHANE, DICHLORODIFLUORO- 75-71-8 <100
(Refrigerant 12)
*METHANE, CHLOROTRIFLUORO- 75-72-9 <100
(Refrigerant 13)
*METHANE, CHLORODIFLUORO- 75-45-6 <100
(Refrigerant 22)
METHANE, TRIFLUORO- 75-46-7 <100
(HFC-23)
DIFLUOROMETHANE 75-10-5 <30
(HFC-32)
*1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE 76-13-1 <100
(Refrigerant 113)
*ETHANE, 1,2-DICHLOROTETRAFLUORO- 76-14-2 <100
(Refrigerant 114)
*ETHANE, CHLOROPENTAFLUORO- 76-15-3 <60
(Refrigerant 115)
*ETHANE, 2,2-DICHLORO-1,1,1-TRIFLUORO- 306-83-2 <100
(Refrigerant 123)
*ETHANE, 2-DICHLORO-1,1,1,2- 2837-89-0 <100
TETRAFLUORO- (Refrigerant 124)
PENTAFLUOROETHANE 354-33-6 <70
(HFC-125)
ETHANE, 1,1-DIFLUORO- 75-37-6 <30
(Refrigerant 152a)
*METHANE, BROMOTRIFLUORO- 75-63-8 <100
(Refrigerant 13B1)
ETHANE, 1,1,1,2-TETRAFLUORO- 811-97-2 <100
(HFC-134a)
ETHANE, 1,1,1-TRIFLUORO- 420-46-2 <55
(HFC-143a)
PROPANE 74-98-6 <6
CONTAMINANTS
REFINED MINERAL OILS 64742-52-5 <30
REFINED MINERAL OILS 64742-44-5 <30
REFINED MINERAL OILS 64741-88-4 <30
ALKYL BENZENE 68648-86-2 <30
OIL MIST IF GENERATED
POLYALKYLENE GLYCOL OIL 9038-95-3 <30
POLYOL ESTER PLUS PHOSPHATE ESTER OIL <30
POLYALKYLENE GLYCOL OIL 9003-13-8 <30
6116FR DuPont Page 3
Material Safety Data Sheet
(COMPOSITION/INFORMATION ON INGREDIENTS - Continued)
* Disclosure as a toxic chemical is required under Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR part 372.
Components (Remarks)
The above components represent DuPont Refrigerant and
Refrigerant Blends that are returned for reclamation. Any
(and/or all) components may be contained in the material
returned. The information is representative for any and all
components.
The specification for used refrigerant returned for
reclamation is a maximum of 30% TOTAL lubricating oil
content. Most used refrigerant contains significantly less.
----------------------------------------------------------------------
HAZARDS IDENTIFICATION
----------------------------------------------------------------------
Potential Health Effects
Potential Health Effects
Inhalation of high concentrations of vapor is harmful and
may cause heart irregularities, unconsciousness, or death.
Intentional misuse or deliberate inhalation may cause death
without warning. Vapor reduces oxygen available for
breathing and is heavier than air. Causes skin and eye
irritation.
HUMAN HEALTH EFFECTS:
Human health effects of overexposure by skin contact may
include skin irritation with discomfort or rash. Prolonged
skin contact may cause temporary tingling, numbness,
coldness or drying of skin. Skin contact with some
components may cause frostbite. Eye contact may cause eye
irritation with discomfort, tearing, or blurring of vision.
Eye contact with some components may cause "frostbite like"
effects.
Inhalation may cause temporary lung irritation effects with
cough, discomfort, difficulty breathing, or shortness of
breath. Inhalation or ingestion may cause temporary nervous
system depression with anesthetic effects such as dizziness,
headache, confusion, incoordination, and loss of
consciousness. Higher exposures may cause irregular heart
beat with a strange sensation in the chest, "heart thumping"
apprehension, lightheadedness, feeling of fainting,
dizziness, weakness, sometimes progressing to loss of
consciousness and death. Suffocation, if air is displaced by
vapors, can occur. Ingestion may cause nonspecific
discomfort, such as nausea, headache, or weakness.
6116FR DuPont Page 4
Material Safety Data Sheet
(HAZARDS IDENTIFICATION - Continued)
The major ingestion hazard is aspiration of the liquid into
the lung which may result in "chemical pneumonia". Symptoms
include coughing, gasping, choking, shortness of breath,
bluish discoloration of the skin, rapid breathing and heart
rate and fever. Pulmonary edema or bleeding, drowsiness,
confusion, coma, and seizures may occur in more serious
cases. Symptoms may develop immediately or as late as 24
hours after the exposure, depending on how much chemical
entered the lungs.
REFRIGERANT 12:
Refrigerant 12 has been infrequently associated with skin
sensitization in humans.
REFRIGERANT 152a:
Higher exposures (>20%) to Refrigerant 152a may lead to
abnormal kidney function as detected by laboratory tests.
REFINED MINERAL OILS AND ALKYL BENZENE
Prolonged skin exposure to Refined Mineral Oils and Alkyl
Benzene may defat skin and cause dermatitis. Ingestion may
cause cramps and diarrhea.
Individuals with preexisting diseases of the central nervous
system, cardiovascular system, lungs or kidneys may have
increased susceptibility to the toxicity of excessive
exposures.
Carcinogenicity Information
The following components are listed by IARC, NTP, OSHA or ACGIH as
carcinogens.
Material IARC NTP OSHA ACGIH
REFINED MINERAL OILS 1 X
----------------------------------------------------------------------
FIRST AID MEASURES
----------------------------------------------------------------------
First Aid
INHALATION
If high concentrations are inhaled, immediately remove to fresh
air. Keep person calm. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Call a
physician.
SKIN CONTACT
6116FR DuPont Page 5
Material Safety Data Sheet
(FIRST AID MEASURES - Continued)
Flush area with lukewarm water. Do not use hot water. If
frostbite has occurred, call a physician.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
If swallowed, do not induce vomiting. Immediately give 2 glasses
of water. Never give anything by mouth to an unconscious person.
Call a physician.
Notes to Physicians
THIS MATERIAL MAY MAKE THE HEART MORE SUSCEPTIBLE TO
ARRHYTHMIAS. Catecholamines such as adrenaline, and other
compounds having similar effects, should be reserved for
emergencies and then used only with special caution.
----------------------------------------------------------------------
FIRE FIGHTING MEASURES
----------------------------------------------------------------------
Flammable Properties
Flash Point : >150 C (>302 F)
Pure Refrigerants will not burn. However, the lubricating
oil contaminants will burn and they may be at a high enough
concentration that the mixture will burn.
Fire and Explosion Hazards:
Drums may rupture under fire conditions. Decomposition may
occur.
Extinguishing Media
As appropriate for combustibles in area.
Fire Fighting Instructions
Use water spray or fog to cool container. Self-contained
breathing apparatus (SCBA) is required if drums rupture and
contents are spilled under fire conditions.
6116FR DuPont Page 6
Material Safety Data Sheet
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ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------
Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Accidental Release Measures
Ventilate area. Do not flush into sewers. Dike spill.
Collect on absorbent material and transfer to steel drums
for recovery or disposal. Use self-contained breathing
apparatus (SCBA) for large spills. Comply with Federal,
State, and local regulations on reporting releases.
----------------------------------------------------------------------
HANDLING AND STORAGE
----------------------------------------------------------------------
Handling (Personnel)
Avoid breathing vapors or mist. Avoid contact with eyes,
skin or clothing. Wash thoroughly after handling. Use with
sufficient ventilation to keep employee exposure below
recommended limits.
Storage
Clean, dry area. Do not heat above 125 deg F (52 deg C).
----------------------------------------------------------------------
EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------
Engineering Controls
Normal ventilation for standard manufacturing procedures is
generally adequate. Local exhaust should be used when large
amounts are released. Mechanical ventilation should be used
in low or enclosed places.
Personal Protective Equipment
Impervious gloves and chemical splash goggles should be used
if contact is possible.
RESPIRATOR
Where there is potential for airborne exposures in excess of
applicable limits, wear NIOSH/MSHA approved respiratory
protection.
# Exposure Guidelines
6116FR DuPont Page 7
Material Safety Data Sheet
Applicable Exposure Limits
METHANE, TRICHLOROFLUORO-
PEL (OSHA) : 1,000 ppm, 5,600 mg/m3, 8 Hr. TWA
TLV (ACGIH) : Ceiling 1,000 ppm, 5,620 mg/m3, A4
AEL * (DuPont) : None Established
METHANE, DICHLORODIFLUORO-
PEL (OSHA) : 1,000 ppm, 4,950 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 1,000 ppm, 4,950 mg/m3, 8 Hr. TWA, A4
AEL * (DuPont) : None Established
METHANE, CHLORODIFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : 1,000 ppm, 3,540 mg/m3, 8 Hr. TWA, A4
AEL * (DuPont) : None Established
METHANE, TRIFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA
DIFLUOROMETHANE
AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA
WEEL (AIHA) : 1000 ppm, 8 Hr. TWA
1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
PEL (OSHA) : 1,000 ppm, 7,600 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 1,000 ppm, 7,670 mg/m3, 8 Hr. TWA, A4
STEL 1,250 ppm, 9,590 mg/m3, A4
AEL * (DuPont) : None Established
ETHANE, 1,2-DICHLOROTETRAFLUORO-
PEL (OSHA) : 1,000 ppm, 7,000 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 1,000 ppm, 6,990 mg/m3, 8 Hr. TWA, A4
AEL * (DuPont) : None Established
ETHANE, CHLOROPENTAFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : 1,000 ppm, 6,320 mg/m3, 8 Hr. TWA
AEL * (DuPont) : None Established
ETHANE, 2,2-DICHLORO-1,1,1-TRIFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 50 ppm, 8 & 12 Hr. TWA
WEEL (AIHA) : 50 ppm, 8 Hr. TWA
ETHANE, 2-DICHLORO-1,1,1,2-
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA
WEEL (AIHA) : 1000 ppm, 8 Hr. TWA
PENTAFLUOROETHANE
6116FR DuPont Page 8
Material Safety Data Sheet
(Applicable Exposure Limits - Continued)
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA
WEEL (AIHA) : 1000 ppm, 4900 mg/m3, 8 Hr. TWA
ETHANE, 1,1-DIFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 1000 ppm, 8 Hr. TWA
WEEL (AIHA) : 1000 ppm, 8 Hr. TWA
METHANE, BROMOTRIFLUORO-
PEL (OSHA) : 1,000 ppm, 6,100 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 1,000 ppm, 6,090 mg/m3, 8 Hr. TWA
AEL * (DuPont) : None Established
ETHANE, 1,1,1,2-TETRAFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA
WEEL (AIHA) : 1000 ppm, 8 Hr. TWA
ETHANE, 1,1,1-TRIFLUORO-
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 1000 ppm, 8 & 12 Hr. TWA
WEEL (AIHA) : 1000 ppm, 8 Hr. TWA
PROPANE
PEL (OSHA) : 1,000 ppm, 1,800 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 1000 ppm, 8 Hr. TWA
AEL * (DuPont) : None Established
OIL MIST IF GENERATED
PEL (OSHA) : 5 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 5 mg/m3, 8 Hr. TWA, STEL 10 mg/m3
Notice of Intended Changes (2004)
5 mg/m3, 8 Hr. TWA, (As sampled by
method that does not collect vapors)
AEL * (DuPont) : 5 mg/m3, 8 Hr. TWA
* AEL is DuPont鈥檚 Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
6116FR DuPont Page 9
Material Safety Data Sheet
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PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------
Physical Data
Odor : Slight ethereal
Form : Liquid, compressed gas, liquefied gas
Color : Clear, colorless, slightly yellow
----------------------------------------------------------------------
STABILITY AND REACTIVITY
----------------------------------------------------------------------
Chemical Stability
Material is stable. However, avoid open flames and high
temperatures.
Incompatibility with Other Materials
Refrigerants are incompatible with alkali or alkaline earth
metals - powdered Al, Zn, Be, etc. The Refined Mineral Oils
are incompatible with strong oxidizers.
Decomposition
Decomposition products are hazardous. This compound can be
decomposed by high temperatures (open flames, glowing metal
surfaces, etc.) forming hydrochloric and hydrofluoric acids,
and possibly carbonyl halides. Refined Mineral Oils, if
present, can produce carbon monoxide and carbon dioxide upon
combustion.
Polymerization
Polymerization will not occur.
----------------------------------------------------------------------
TOXICOLOGICAL INFORMATION
----------------------------------------------------------------------
Animal Data
Animal Data
As a class of compounds, inhalation exposure to the
individual refrigerants has caused the following toxic
effects in animal testing:
Nervous system effects; anesthetic effects such as tremors,
dizziness, incoordination, and loss of consciousness;
irregular heartbeat; and cardiac sensitization (a
potentially fatal disturbance of heart rhythm associated
with a heightened sensitivity to the action of epinephrine).
In animal testing, some refrigerants caused altered blood
pressure; decreased body weight; altered clinical chemistry;
altered respiratory function; respiratory irritation;
6116FR DuPont Page 10
Material Safety Data Sheet
(TOXICOLOGICAL INFORMATION - Continued)
increased liver weight; alterations in blood chemistry.
REFRIGERANT 11:
Inhalation 4-hour LC50: 26,200 ppm in rats
Oral ALD : 3,725 mg/kg in rats
In animals exposed to Refrigerant 11, various cardiovascular
and circulatory abnormalities have been reported. Changes in
the lungs, liver, brain and spleen were observed in a study
of rats exposed by inhalation to 12 times the TLV.
REFRIGERANT 12:
Inhalation 30-minute LC50: 800,000 ppm in rats
Oral ALD : >1000 mg/kg in rats
ETHANE, 2-CHLORO-1,1,1,2-TETRAFLUORO- (HCFC-124):
4 hour Inhalation, ALC, rat: 230,000 - 300,000 ppm
REFRIGERANT 13:
Inhalation 2-hour LC50: >600,000 ppm in rats
REFRIGERANT 113:
Inhalation 4-hour LC50: 52,500 ppm in rats
Skin Absorption ALD : >11,000 mg/kg in rabbits
Oral LD50 : 43,000 mg/kg in rats
Refrigerant 113 produced weak allergic skin sensitization in
a laboratory animal. High, single oral administration of the
liquid, at or near lethal doses, produced lethargy within
several minutes. In a reproductive toxicity study in rats
with Refrigerant 113, no adverse effects on reproductive
performance were seen at concentrations of 500 ppm, and only
minimal effects (slight decrease in corpora lutea) were
observed at 12,500 ppm.
CFC-114:
Inhalation 30-minute LC50: 720,000 ppm in rats
Oral ALD : >2250 mg/kg in rats
Repeated inhalation exposures to rats and mice at 200,000
ppm of Refrigerant 114 caused slight hematological effects
and respiratory irritation.
REFRIGERANT 123:
Inhalation 4-hour LC50: 32,000 ppm in rats
Oral ALD : 9,000 mg/kg in rats
Skin Absorption LD50 : >2,000 mg/kg in rabbits
6116FR DuPont Page 11
Material Safety Data Sheet
(TOXICOLOGICAL INFORMATION - Continued)
Repeated inhalation exposures to 300 ppm of HCFC-123
resulted in alterations in blood chemistry; Inhalation
exposures above 300 ppm caused reduced lymphocyte counts,
enzyme alterations, increased urinary fluoride concentration
in rats; dogs demonstrated slight liver damage. HCFC-123
was not neurotoxic in animals repeatedly exposed by
inhalation at concentrations up to 5,000 ppm, but did cause
a slight decrease in arousal at this concentration.
Inhalation of 300, 1000 or 5000 ppm HCFC-123 for two years
caused an increase in benign testicular and benign
pancreatic tumors in male rats; an increase in benign
pancreatic tumors was observed in female rats exposed to
5000 ppm. In the same study, male and female rats exposed
to 5000 ppm showed an increased incidence in benign liver
tumors. Smaller increases in the incidence of these benign
liver tumors were observed in females at 300 and 1000 ppm,
while none were observed in female controls. The tumors
were late-occurring and none were judged to be
life-threatening. The biological significance of these
tumors to man is considered to be limited. Additionally,
evidence of retinal atrophy was observed in this two-year
study in both treated and control animals, although the
toxicological significance is undetermined. HCFC 123 does
not produce genetic damage in bacterial cell cultures or in
animals; however, in one study genetic damage was produced
in mammalian cell cultures.
REFRIGERANT 22:
Inhalation 4-hour LC50: 220,000 ppm in rats
In chronic inhalation studies, HCFC-22, at a concentration
of 50,000 ppm (v/v), produced a small, but statistically
significant increase of late-occurring tumors involving
salivary glands in male rats, but not female rats or male or
female mice. In the same studies, no increased incidence of
tumors was seen in either species at concentrations of
10,000 ppm or 1000 ppm (v/v). HCFC-22 was mutagenic in some
strains of bacteria in bacterial cell cultures, but not
mammalian cell cultures or animals. It did not cause
heritable genetic damage in mammals. A slight, but
significant increase in developmental toxicity was observed
at high concentrations (50,000 ppm) of HCFC-22, a
concentration which also produced toxic effects in the adult
animal. Based on these findings, and other negative
developmental studies, HCFC-22 is not considered a unique
hazard to the conceptus.
HFC-152a:
Inhalation 4-hour ALC: 383,000 ppm in rats
Oral ALD : >1,500 mg/kg in rats
6116FR DuPont Page 12
Material Safety Data Sheet
(TOXICOLOGICAL INFORMATION - Continued)
Effects of repeated inhalation exposure to HFC-152a include
increased urinary fluoride, reduced kidney weight, and
reversible kidney changes.
REFRIGERANT 115:
Inhalation 4-hour LC50: >800,000 ppm in rats
Oral ALD : >1,200 mg/kg in rats
The effects of repeated ingestion of Refrigerant 115 include
mild diarrhea, salivation and increased activity.
HFC-23:
Inhalation 1-hour LC50: >900,000 ppm (species unknown)
ETHANE, 1,1,1,2-TETRAFLUORO- (HFC-134a):
4 hour, ALC, rat: 567,000 ppm
Single inhalation exposure to near lethal doses caused
pulmonary edema. Repeated exposure caused increased
adrenals, liver, spleen weight; decreased uterine, prostate
weight. Repeated dosing of higher concentrations caused
tremors. In a two-year inhalation study, HFC-134a, at a
concentration of 50,000 ppm, produced an increase in
late-occurring benign testicular tumors, testicular
hyperplasia and testicular weight. The no-effect-level for
this study was 10,000 ppm. Animal data show slight
fetotoxicity but only at exposure levels producing other
toxic effects in the adult animal. Reproductive data on
male mice show: No change in reproductive performance.
Tests have shown that this material does not cause genetic
damage in bacterial or mammalian cell cultures, or in
animals. In animal testing, this material has not caused
permanent genetic damage in reproductive cells of mammals
(has not produced heritable genetic damage).
REFRIGERANT 13B1:
Inhalation 1-hour LC50: >770,000 ppm in rats
Lung irritation and degeneration of the liver and kidneys
were seen in animals exposed repeatedly by inhalation to
lethal or near lethal concentrations of Refrigerant 13B1.
The acute Oral LD50 in rats for Refined Oil (CAS 64742-52-5)
is >15 g/kg.
FC-143a:
Inhalation 4 hour LC50: > 540,000 ppm in rats
Two, 4-week inhalation studies of FC-143a have been
6116FR DuPont Page 13
Material Safety Data Sheet
(TOXICOLOGICAL INFORMATION - Continued)
conducted. In the first study, pathological changes in the
testes were observed at all exposure concentrations; no
effects were observed in females. The testicular effect was
considered related to the method used to expose the rats to
HFC-143A. In the second study using the same exposure
concentrations, no effects were noted in males at any
concentration. Tests of FC-143a in bacterial cell cultures
demonstrate mutagenic activity, but the compound did not
induce oncogenic transformation of mammalian cells in
culture. HFC-143A was not mutagenic in animals.
HFC-125:
INHALATION:
4 hour, ALC, rat: > 709,000 ppm
HFC-32:
4 hour inhalation, ALC, rat: > 520,000 ppm
Animal data on HFC-32 show slight fetotoxicity but only at
exposure levels producing other toxic effects in the adult
animal.
----------------------------------------------------------------------
DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------
Waste Disposal
Comply with Federal, State, and local regulations. Remove
to a permitted waste disposal facility.
----------------------------------------------------------------------
TRANSPORTATION INFORMATION
----------------------------------------------------------------------
Shipping Information
DOT/IMO/IATA
Proper Shipping Name: REFRIGERANT GASES, N.O.S.
(FLUORINATED HYDROCARBONS)
Hazard Class : 2.2
UN No. : 1078
DOT/IMO/IATA Label : NONFLAMMABLE GAS
Shipping Containers : Cylinders
Tank Cars
Tank Trucks
THE FOLLOWING SHIPPING DESCRIPTION IS FOR USED R-11, USED
R-113, AND USED R-123 ONLY:
NOT REGULATED AS A HAZARDOUS MATERIAL BY DOT, IMO, OR IATA.
6116FR DuPont Page 14
Material Safety Data Sheet
(TRANSPORTATION INFORMATION - Continued)
Shipping Containers: Drums
Cylinders
----------------------------------------------------------------------
REGULATORY INFORMATION
----------------------------------------------------------------------
U.S. Federal Regulations
TSCA Inventory Status : Reported/Included.
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute : Yes
Chronic : Yes
Fire : No
Reactivity : No
Pressure : Yes
LISTS:
SARA Extremely Hazardous Substance -No
CERCLA Hazardous Substance -Yes*
Toxic Chemicals -(Yes)**
*For Freon 11,12
**See component section
----------------------------------------------------------------------
OTHER INFORMATION
----------------------------------------------------------------------
NFPA, NPCA-HMIS
NPCA-HMIS Rating
Health :1
Flammability :1
Reactivity :1
Personal Protection rating to be supplied by user depending on use
conditions.
----------------------------------------------------------------------
The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsibility for MSDS : MSDS Coordinator
> : DuPont Fluoroproducts
Address : Wilmington, DE 19898
Telephone : (800) 441-7515
# Indicates updated section.
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
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