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MSDS Material Safety Data Sheet
CAS

14239-68-0
97-77-8
122-62-3

File Name: rtvanderbilt_com---08039.asp
                             Material Safety Data Sheet                                                                               chemec

Section 1. Chemical Product and Company Identification

Product Name/ ETHYL CADMATE DUSTLESS Code 08039
Trade Name
14239-68-0
CAS#
Supplier R.T. VANDERBILT COMPANY, INC. Call (203)853-1400
In Case of
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Cadmium diethyldithiocarbamate.
Synonym

Cadmium, bis(diethylcarbamodithioato-S,S')-,(T-4)-
Chemical name

Chemical Family Not available.

C10 H20 N2 S4 Cd
Chemical Formula

Industrial applications: Elastomer accelerator
Material Uses




Section 2. Composition, Information on Ingredients
EINECS # /
% by
CAS # Classification
Name
ELINCS #
Weight

tetraethylthiuram disulfide 97-77-8 48.5 202-607-8 Not available.
cadmium (bis)diethyldithiocarbamate 14239-68-0 48.5 238-113-4 Not available.
dioctyl sebacate 122-62-3 3 204-558-8 Not available.
For additional information regarding European classification see sections 15 & 16.



Section 3. Hazards Identification
White to light tan powder. Contains cadmium compound. Cancer hazard. May cause eye and skin irritation.
Emergency Overview
Inhalation and ingestion hazard. Can cause lung and kidney disease. Dust suspended in air in critical
proportions and in the presence of an ignition source may present an explosion hazard.




Section 4. First Aid Measures
Check for and remove any contact lenses. Flush with running water for at least 15 minutes. Do not use an
Eye Contact
eye ointment. Seek medical attention.
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated
Skin Contact
skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and
groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.

Allow the victim to rest in a well ventilated area. Seek immediate medical attention
Inhalation


Do not induce vomiting. Immediately give two glasses of water, a little at a time. Never give anything by
Ingestion
mouth to an unconscious person. Call a physician. If vomiting occurs spontaneously, lower head below waist
to prevent fluid from entering the lungs




Continued on Next Page
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ETHYL CADMATE DUSTLESS

Section 5. Fire and Explosion Data
Not applicable.
Flammability of the Product

Not applicable.
Autoignition Temperature

Not applicable.
Flash point

Not applicable.
Flammable Limits

Carbon disulfide, oxides of sulfur, carbon, cadmium and nitrogen oxides (NO, NO2...)
Products of Combustion


Explosion Hazards in Presence Dust suspended in air in critical proportions and in the presence of an ignition source presents an explosion
hazard.
of Various Substances
Use DRY chemicals, CO2, alcohol foam or water spray.
Fire Fighting Media
and Instructions

Not available.
Special Remarks on Fire
Hazards
Special Remarks on Explosion As with any dry material, pouring or allowing to free-fall or to be conveyed through chutes or pipes can
Hazards accumulate and generate electrostatic sparks, potentially causing ingnition of the material itself, or if any
flammable materials which may come in contact with the material or its container.



Section 6. Accidental Release Measures
Wet down residules with soap and water to avoid creating dust. Place in closed container for disposal.
Small Spill
Prevent entry into sewers and open waters.
Evacuate area of nonessential personnel. Use safety glasses and gloves. Respiratory protection is required
Large Spill
only if a dust is generated. Scoop or shovel spilled solids into containers. Avoid creating a dust. Prevent
spilled product or contaminated wash water from entering drinking water supplies or streams. Use vacuum
with HEPA filter if necessary.



Section 7. Handling and Storage
Carcinogenic, teratogenic or mutagenic materials should be stored in a separate locked safety storage
Storage
cabinet or room.
Avoid contact with skin and eyes. DO NOT breathe dust. DO NOT ingest. Keep away from food, drink and
Handling Procedures and
animal feeding stuffs. When using do not eat, drink or smoke. Do not ingest alcohol while handling this
Equipment
material. Handle with equipment properly grounded to avoid electrostatic discharge.




Section 8. Exposure Controls, Personal Protection
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
Engineering Controls
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Precautions
Gloves.
tetraethylthiuram disulfide)
TLV/PEL
TWA: 2 (mg/m3) from ACGIH (TLV)
TWA: 2 (mg/m3) from ACGIH
TWA: 2 (mg/m3) from RQMT
cadmium (bis)diethyldithiocarbamate
TWA: 0.01 (mg/m3) from ACGIH (TLV) Inhalation Total.
TWA: 0.002 (mg/m3) from ACGIH (TLV) Inhalation Respirable.


Consult local authorities for acceptable exposure limits.




Continued on Next Page
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ETHYL CADMATE DUSTLESS

Section 9. Physical and Chemical Properties
White to light tan. Solid. (Powdered solid.)
Appearance

408.9
Molecular Weight

Not applicable.
pH (1% soln/water)

Not available.
Boiling/Condensation Point

63掳C (145.4掳F)
Melting/Freezing Point

1.48 (Water = 1)
Specific Gravity

Not available.
Density

Not applicable.
Vapor Pressure

Not available.
Vapor Density

Not available.
Volatility

Odorless.
Odor

Not available.
Evaporation Rate

Not available.
Viscosity

Not available.
Water/Oil Dist. Coeff.

Insoluble in cold water. Moderately soluble in toluene.
Solubility

Not applicable.
Flash Point




Section 10. Stability and Reactivity
The product is stable.
Stability

Not available.
Instability Temperature

Not available.
Conditions of Instability

Reactive with oxidizing agents, acids.
Incompatibility with Various
Substances
Not available.
Corrosivity


Special Remarks on Reactivity Not available.




Section 11. Toxicological Information
Absorbed through skin. Eye contact. Inhalation. Ingestion
Routes of Entry

Acute oral toxicity (LD50): >600 mg/kg but <2000 mg/kg [Male Rat
Toxicity to Animals
Acute oral toxicity (LD50): 900 mg/kg [Female Rat]
Acute dermal toxicity (LD50): >2000 mg/kg [Rabbit]. (tetraethylthiuram disulfide

Special Remarks on Toxicity to Not available.
Animals

Acute Effects

May cause eye irritation based on component data.
Eye Contact

May cause slight to mild skin irritation based on component data. Sulfur compound may be absorbed through
Skin Contact
skin but acute toxicity is low. (See remarks below).
Sulfur compound is a potential skin sensitizer.
Sensitization


Continued on Next Page
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ETHYL CADMATE DUSTLESS
Ingestion This product is an ingestion hazard based on animal data.

Inhalation Based on component testing, inhalation of high concentrations may cause respiratory irritation and absorption
into the body. Acute overexposure to cadmium compounds can cause kidney damage. (See remarks below).
Remarks Ingestion/inhalation/skin absorption of this product may cause unpleasant symptoms if alcohol is consumed
whithin hours of exposure (antabuse effect)

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not
Chronic Effects on
classifiable for human.) by IARC [Nitrogen containing organic sulfur compound]. Classified 1 (Proven for
Humans
human.) by IARC [cadmium (bis)diethyldithiocarbamate]. Classified A2 (Suspected for human.) by ACGIH, 2
(Some evidence.) by NTP [cadmium (bis)diethyldithiocarbamate].
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells based on in vitro studies. [Nitrogen
containing organic sulfur compound]. Mutagenic for bacteria and/or yeast. [cadmium
(bis)diethyldithiocarbamate, Nitrogen containing organic sulfur compound].
DEVELOPMENTAL TOXICITY Not available.
:
REPRODUCTIVE TOXICITY: Has been shown to cause reproductive effects in laboratory animals [Nitrogen
containing organic sulfur compound].
Prolonged or repeated exposure to cadmium, even at relatively low concentrations, may result in kidney
Remarks
damage and an increased risk of cancer of the lung and of the prostate.

Prolonged or repeated exposure to sulfur compound includes CNS depression, axonal degeneration and
peripheral neuropathy. It has been found to inhibit tumor induction in animal studies by a variety of
carcinogens. Classified by IARC Group 3 (Animal indefinite.)




Section 12. Ecological Information
Not available.
Ecotoxicity

Not available.
BOD5 and COD

Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Biodegradability


Not available.
Special Remarks




Section 13. Disposal Considerations
RCRA Classification: D006
Waste Information

Not available.
Waste Stream



Section 14. Transport Information
CLASS 6.1: Toxic substance.
ADR Classification


6




PIN Shipping name: Cadmium compounds, 6.1, UN 25 70, PG c

Not available.
Remarks



Not available.
IMDG Classification.

IMDG Class: Marine Pollutant. (Highly
pollutant.)

IATA Classification CLASS 6.1: Toxic substance.


Continued on Next Page
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ETHYL CADMATE DUSTLESS



Section 15. Other Regulatory Information and Pictograms
Regulatory Lists EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Remark

R20/21/22- Harmful by S24- Avoid contact with skin.
EC Classification /
inhalation, in contact with S36/37- Wear suitable protective clothing and gloves.
Labelling
skin and if swallowed. S46- If ingested, seek medical advice immediately and show the
R43- May cause container or the label.
sensitization by skin S56- Dispose of this material and its container at hazardous or special
contact. waste collection point.
R48/22- Harmful: danger of
serious damage to health
by prolonged exposure if
swallowed.
R50/53- Very toxic to
aquatic organisms, may
cause long-term adverse
effects in the aquatic
environment.




Flammability
0
Hazardous Material *2 National Fire Protection
Health Hazard
2 0 Reactivity
Health
Information System Association (U.S.A.)
0
Fire Hazard
(U.S.A.)
0
Physical Hazard Specific hazard

E
Personal Protection




TSCA 8(b) inventory: ETHYL CADMATE庐 DUSTLESS
Other Regulations

CEPA DSL: ETHYL CADMATE庐 DUSTLESS

Australia (NICNAS): ETHYL CADMATE庐 DUSTLESS

China: ETHYL CADMATE庐 DUSTLESS

Japan (MITI): ETHYL CADMATE庐 DUSTLESS



Protective Clothing
(Pictograms)




Continued on Next Page
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ETHYL CADMATE DUSTLESS

Section 16. Other Information
Relevant R phrases:

References Not available.

Other Special Not available.
Considerations

Verified by Alan Lopez.
Validated by Alan Lopez on 7/11/2006.
Printed 10/10/2007.

Information Contact (203) 853-1400
Corporate Risk Management Department

Notice to Reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge
and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or
in violation of any law or regulation. It is the user鈥檚 responsibility to determine for himself the suitability of any material for a specific purpose and to
adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions
of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.

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