Material Safety Data Sheet chemec
Section 1. Chemical Product and Company Identification
VANCIDE庐 TH
Product Name/ Code 47005
Trade Name
7779-27-3
CAS#
Supplier R.T. VANDERBILT COMPANY, INC. Call (203)853-1400
In Case of
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Hexahydro-1,3,5-triethyl-s-triazine
Synonym
1,3,5-Triazine, 1,3,5-triethylhexahydro-
Chemical name
Chemical Family Not available.
C9H21N3
Chemical Formula
Applications: Industrial Preservative
Material Uses
Section 2. Composition, Information on Ingredients
EINECS # /
% by
CAS # Classification
Name
ELINCS #
Weight
hexahydro-1,3,5-triethyl-s-triazine 7779-27-3 96.3 Not available.
Inert ingredients 3.7 Not available.
For additional information regarding European classification see sections 15 & 16.
Section 3. Hazards Identification
Colorless to light yellow liquid. Corrosive to the skin. Severely irritating to the eyes. Harmful if inhaled.
Emergency Overview
Possible release of formaldehyde as an off-gas.
Section 4. First Aid Measures
IF IN EYES: Hold eye open and rinse slowly and gently with water or 15-20 minutes. Remove contact
Eye Contact
lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for
treatment advices.
For skin contact, flush affected areas with plenty of water for several minutes. Remove and clean
Skin Contact
contaminated clothing and shoes. Seek medical attention if irritation occurs.
If inhaled, remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth.
Inhalation
Get medical attention.
If swallowed, drink promptly a large quantity of water. Avoid alcohol. Get medical attention.
Ingestion
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VANCIDE庐 TH Page Number: 2
Section 5. Fire and Explosion Data
COMBUSTIBLE.
Flammability of the Product
Not available.
Autoignition Temperature
CLOSED CUP: 66掳C (150.8掳F).
Flash point
Not available.
Flammable Limits
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Products of Combustion
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Not available.
Special Remarks on Fire
Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
Small Spill
container.
Combustible material. Keep away from heat and sources of ignition. Wear proper protective equipment.
Large Spill
Absorb on a porous, inert material and transfer to a closed container. Prevent entry into sewers, basements
or confined areas; dike if needed.
Section 7. Handling and Storage
Do not contaminate water, food or feed in storage or disposal. Open dumping is prohibited. Store in a cool,
Storage
dry place.
Avoid contact with skin and eyes. Avoid breathing vapors or spray mists. Avoid creation of sprays or spray
Handling Procedures and
mists. Keep away from food, drink and animal feeding stuffs. Keep container tightly closed and in a
Equipment
well-ventilated place. Wear suitable protective clothing.
Section 8. Exposure Controls, Personal Protection
Effective exhaust to draw fumes and vapors away from workers to prevent routine inhalation. If local exhaust
Engineering Controls
ventilation is applied, a capture velocity of 100 to 150 fpm should be maintained. Local exhaust is
recommended during product mixing. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Splash goggles. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Full
Personal Precautions
suit.
For possible off-gas: Formaldehyde
TLV/PEL
OSHA PEL: 0.75 ppm (8 hr. TWA)
2 ppm OSHA STEL ( 15 minute period)
OSHA action level at 0.5 ppm (8 hr. TWA)
Note: Simulated routine customer handling suggests that formaldehyde off-gas is unlikely to exceed any of
the above standards. Typical handling of VANCIDE TH yielded formaldehyde off-gas levels of <0.005 to 0.01
ppm for an 8 hour exposure (extrapolated). Because off-gas is affected by temperature, pH and plant-specific
controls, plant specific monitoring is recommended to establish compliance with the standard.
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VANCIDE庐 TH Page Number: 3
Section 9. Physical and Chemical Properties
Colorless to light Liquid.
Appearance
yellow.
171.29
Molecular Weight
11 [Basic.]
pH (1% soln/water)
Not available.
Boiling/Condensation Point
Not available.
Melting/Freezing Point
0.89 (Water = 1)
Specific Gravity
Not available.
Density
15.7 mmHg @ 25掳C
Vapor Pressure
Not available.
Vapor Density
100% (w/w).
Volatility
Not available.
Odor
Not available.
Evaporation Rate
2.8 cSt
Viscosity
Not available.
Water/Oil Dist. Coeff.
Soluble in cold water, acetone and ethyl alcohol.
Solubility
CLOSED CUP: 66掳C (150.8掳F).
Flash Point
Section 10. Stability and Reactivity
The product is stable.
Stability
Not available.
Instability Temperature
Avoid pH <6.3 and high temperatures
Conditions of Instability
Reactive with acids.
Incompatibility with Various
Substances
Not available.
Corrosivity
Special Remarks on Reactivity Forms ethylamine and formaldehyde at pH <6.3
Section 11. Toxicological Information
Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion
Routes of Entry
Acute oral toxicity (LD50): 280 mg/kg [Rat].
Toxicity to Animals
Acute dermal toxicity (LD50): 499 mg/kg [Rabbit]
Acute inhalation toxicity (LC50) 4-hour : 251 mg/cu m [Rats]
Special Remarks on Toxicity to Inhalation of 2660 mg/cu m/1 hr. (rat) caused transient effects.
Animals
Acute Effects
Severe eye irritant. Eye irritation showed corneal damage to the eyes of rabbits. If not immediately rinsed
Eye Contact
out, the effect may be irreversible.
Skin irritation studies showed that the substance is corrosive to rabbit skin. Dermal studies showed that the
Skin Contact
substance was absorbed through the skin. Hemolysis and passive congestion of the liver was noted.
No data available.
Sensitization
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VANCIDE庐 TH Page Number: 4
Ingestion This product is considered a moderate ingestion hazard based on animal data.
Inhalation This product is an inhalation hazard based on animal data.
Remarks Not available.
CARCINOGENIC EFFECTS: Possible release of formaldehyde as an off-gas. OSHA has designated
Chronic Effects on
formaldehyde as a potential human carcinogen.
Humans
MUTAGENIC EFFECTS Not available.
:
DEVELOPMENTAL TOXICITY: In a developmental toxicity study with rats, VANCIDE TH庐 was administered
by oral gavage at 10, 75, and 150 mg/kg. Under the conditions of the study, the product was not teratogenic.
The developmental No Observed Effect Level (NOEL) was 75 mg/kg and the Lowest Observed Effect Level
(LOEL) was 150 mg/kg.
REPRODUCTIVE TOXICITY Not available.
:
In unscheduled DNA synthesis in rat primary hepatocytes the material was tested at nine different dose levels
Remarks
ranging from 0.00003-0.1 ul/ml. It was found that the test material induced a dose-related increase in
unscheduled DNA synthesis. The material caused a significant increase in the mean number of net nuclear
grains, an increase of at least 5 counts over the solvent control, at 0.06 ul/ml. A reduction in cytoplasmic and
nuclear grain counts was also noted at 0.06 ul/ml.
Micronucleus Cytogenic Assay in Mice - Male and female IRC mice were given
hexahydro-1,3,5-triethyl-s-triazine using a single dose oral gavage administration. The dosages given were
25, 125, and 225 mg/kg. It was found that there was no significant increase in the number of micronucleated
polychromatic erythrocytes observed at 24, 48, and 72 hours after dose administration in male and female
mice. It was concluded that the material was negative under the conditions of the assay.
Section 12. Ecological Information
Ecotoxicity in water (LC50): 35 mg/l 96 hours [Rainbow trout].
Ecotoxicity
Ecotoxicity in water (EC50): 26 mg/l [Daphnia magna]
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Biodegradability
Not available.
Special Remarks
Section 13. Disposal Considerations
Dispose of in accordance with state and local regulations.
Waste Information
Not available.
Waste Stream
Section 14. Transport Information
CLASS 6.1: Toxic substance.
ADR Classification
CLASS 8: Corrosive liquid.
6 8
PIN Shipping name: Toxic liquids, corrosive, organic, n.o.s. (Hexahydro-1,3,5-triethyl-s-triazine), 6.1, 8, UN: 2927
PG: II
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VANCIDE庐 TH Page Number: 5
IMDG Classification.
Not available.
IATA Classification Class 6.1: Toxic material.
Section 15. Other Regulatory Information and Pictograms
Regulatory Lists EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Not available.
Remark
R26- Very toxic by S26- In case of contact with eyes, rinse immediately with plenty of water
EC Classification /
inhalation. and seek medical advice.
Labelling
R21/22- Harmful in contact S28- After contact with skin, wash immediately with plenty of water
with skin and if swallowed. S29- Do not empty into drains.
R34- Causes burns. S36/37/39- Wear suitable protective clothing, gloves and eye/face
R52/53- Harmful to aquatic protection.
organisms, may cause S45- In case of accident or if you feel unwell, seek medical advice
long-term adverse effects immediately (show the label where possible).
in the aquatic environment. S63- In case of accident by inhalation: remove casualty to fresh air and
keep at rest.
Flammability
2
Hazardous Material 4 National Fire Protection
Health Hazard
4 1 Reactivity
Health
Information System Association (U.S.A.)
2
Fire Hazard
(U.S.A.)
1
Physical Hazard Specific hazard
H
Personal Protection
TSCA 8(b) inventory: VANCIDE庐 TH
Other Regulations
CEPA DSL: VANCIDE庐 TH
Australia (NICNAS): VANCIDE庐 TH
Korea (TCCL): VANCIDE庐 TH
Philippines (RA6969): VANCIDE庐 TH
Protective Clothing
(Pictograms)
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VANCIDE庐 TH Page Number: 6
Section 16. Other Information
Relevant R phrases:
References Not available.
Other Special Not available.
Considerations
Verified by Romana Uzar.
Validated by Romana Uzar on 4/12/2007.
Printed 4/12/2007.
Information Contact (203) 853-1400
Corporate Risk Management Department
Notice to Reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge
and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or
in violation of any law or regulation. It is the user鈥檚 responsibility to determine for himself the suitability of any material for a specific purpose and to
adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions
of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.
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