Material Name: LAWX 307 Adhesives Safety Data Sheet
ID: 2055
Section 1 - Product and Company Identification
Product Name LAWX 307 Adhesive
Generic Name Adhesive (Latex)
Formula Mixture
Chemical Name: Mixture
Hazard Label None necessary.
Company Information
Johns Manville Insulation Group Telephone: 303-978-2000 8:00AM-5:00PM M-F
Insulation Systems Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: 307C Adhesive; 307X Adhesive; 307X-NFR Adhesive
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
Not Available Latex emulsion 70-80
7732-18-5 Water 5-10
1317-65-3 Calcium carbonate 0-30
21645-51-2 Aluminum (hydrated) 0-10
1309-42-8 Magnesium hydroxide 1-10
1309-64-4 Antimony trioxide (fire retardant) 0-10*
68610-51-5 Antioxidant 1-5
148-79-8 Thiabendazole [fungicide) <1
14808-60-7 Crystalline silica 0-0.2*
* Note: Due to the product form, exposures to hazardous dusts will not occur. Exposure limits are given for reference only.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Off-white liquid of medium viscosity.
Inhalation of excessive amounts of dust from the product may cause temporary upper respiratory irritation and/or congestion--
remove individual to fresh air.
Potential Health Effects
Summary
Due to the form of the product hazardous exposures are unlikely to occur. Exposure may cause slight temporary irritation to
skin, eyes, nose, or throat.
Inhalation
Temporary irritation of nose and throat may occur.
Skin
Temporary irritation (itching) or redness may occur.
Absorption
Not applicable
Ingestion
This product is not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause nausea and
systemic poisoning.
Eyes
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Skin contact, eye contact, inhalation, ingestion.
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Material Name: LAWX 307 Adhesives Safety Data Sheet
ID: 2055
Target Organs
Skin, eyes, nose, throat, gastrointestinal system.
Medical Conditions Aggravated by Exposure
None identified.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
For skin contact flush with large amounts of water while removing contaminated clothing. Wash contaminated clothing before
reuse.
First Aid: Ingestion
This product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting. Drink plenty of water.
Contact a physician immediately.
First Aid: Eyes
Flush eyes with large amounts of water until irritation subsides. If symptoms persist, contact a medical professional.
First Aid: Notes to Physician
Treat symptomatically. Emesis may be indicated in recent (within 30 minutes) ingestion of large quantities.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: None known Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
Combustibility depends on the product form. As latex, the material is not combustible. The dried resin, however, is
combustible, similar to wood. Burning resin emits dense, black smoke.
Extinguishing Media
Water fog
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Containment Procedures
Dam, mop, absorb onto sawdust or other absorbent, and place in suitable container. Do not allow liquid to contaminate
sewers, or other water sources.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Store at temperatures between 4掳-43掳C/40掳-110掳F.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and protected
from moisture. Do not freeze. Avoid direct exposure to very high heat or flame.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
No information available for the product.
B: Component Exposure Limits
Calcium carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Crystalline silica (14808-60-7)
ACGIH: 0.025 mg/m3 TWA (respirable fraction)
OSHA: 0.1 mg/m3 TWA (respirable dust)
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Material Name: LAWX 307 Adhesives Safety Data Sheet
ID: 2055
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields, chemical goggles, or face mask recommended.
Personal Protective Equipment: Skin
Any chemical impervious glove may be used to protect skin.
Personal Protective Equipment: Respiratory
Respiratory protection is not required if mechanical or dilution ventilation is sufficient to keep the exposure levels below the
applicable exposure limits.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Personal Protective Equipment: General
An apron or coveralls impervious to chemicals can be used to protect clothing. Wash exposed skin after contact, before breaks
and meals, and at end of work period.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Off-white No significant odor
Physical State: pH:
Thick liquid 9.0
Vapor Pressure: Vapor Density:
Not determined Not determined
Boiling Point: Melting Point:
100潞C/212潞F Not applicable
Solubility (H2O): Specific Gravity:
<45% 1.2
Freezing Point: Solids Content
Not determined 56%
Evaporation Rate: Viscosity:
Same as water 3700 cps
Percent Volatile: VOC:
44% Not applicable
Section 10 - Stability & Reactivity Information
Stability
This is a stable material. This product is not reactive.
Stability: Conditions to Avoid
Do not freeze.
Incompatibility
This product may react with oxidizing agents.
Hazardous Decomposition
Carbon monoxide, carbon dioxide, and traces of acetic acid.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Skin, eye, and upper respiratory irritation may occur after contact with product.
B: Component Analysis - LD50/LC50
Water (7732-18-5)
Oral LD50 Rat: >90 mL/kg
Aluminum (hydrated) (21645-51-2)
Oral LD50 Rat: >5000 mg/kg
Magnesium hydroxide (1309-42-8)
Oral LD50 Rat: 8500 mg/kg
Antimony trioxide (fire retardant) (1309-64-4)
Oral LD50 Rat: >34600 mg/kg
Antioxidant (68610-51-5)
Inhalation LC50 Rat: >165 mg/L/1H; Oral LD50 Rat: >200 mg/kg; Dermal LD50 Rabbit: >5010 mg/kg
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Material Name: LAWX 307 Adhesives Safety Data Sheet
ID: 2055
Thiabendazole [fungicide) (148-79-8)
Oral LD50 Rat: 2080 mg/kg
Crystalline silica (14808-60-7)
Oral LD50 Rat: 500 mg/kg
Carcinogenicity
A: General Product Information
No additional information available.
B: Component Carcinogenicity
Antimony trioxide (fire retardant) (1309-64-4)
ACGIH: A2 - Suspected Human Carcinogen (production)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 47 [1989])
Crystalline silica (14808-60-7)
ACGIH: A2 - Suspected Human Carcinogen
NTP: Known Carcinogen (Select Carcinogen)
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 68 [1997] (listed under Crystalline silica
inhaled in the form of quartz or cristobalite from occupational sources))
Chronic Toxicity
Inhalation of antimony trioxide dust has been shown to cause lung and liver cancer in animals, but carcinogenicity in humans
has not been established. Due to product form, exposures to hazardous dusts are not expected to occur.
Crystalline silica is considered a hazard by inhalation. The International Agency for Research on Cancer (IARC) has classified
crystalline silica as a Group 1 substance, carcinogenic to humans. This classification is based on the findings of laboratory
animal studies (inhalation and implantation) and epidemiology studies that were considered sufficient for carcinogenicity.
Several studies have been conducted to determine the risk of cancer to workers exposed to dusts which contain crystalline
silica. However, these studies did not consider other factors or elements that workers may be exposed to. Therefore, the
causes of the excess deaths due to cancer could not be precisely determined. Further studies are being conducted to
determine the risk of cancer when working with crystalline silica products. Excessive exposure to crystalline silica can cause
silicosis, a non-cancerous lung disease. Due to the product form, exposures to hazardous dusts are not expected to occur.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Antimony trioxide (fire retardant) (1309-64-4)
96 Hr LC50 Pimephales promelas: 833.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 530 mg/L; 96 Hr LC50 Brachydanio rerio:
>1000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 67 mg/L
7 Hr EC50 Pseudomonas putida: >3.5 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Antioxidant (68610-51-5)
96 Hr LC50 Oncorhynchus mykiss: >0.2 mg/L [semi-static]
72 Hr EC50 Selenastrum capricornutum: >0.2 mg/L
48 Hr EC50 Daphnia magna: >0.2 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product, as supplied, is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under
Resource Conservation and Recovery Act (RCRA) regulations. Comply with state and local regulations for disposal. If you are
unsure of the regulations, contact your local Public Health Department, or the local office of the EPA.
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Material Name: LAWX 307 Adhesives Safety Data Sheet
ID: 2055
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
Shipping Name: This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard. Delayed
(chronic) health hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Antimony trioxide (fire retardant) (1309-64-4)
CERCLA: 1000 lb final RQ; 454 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Calcium carbonate 1317-65-3 No No Yes Yes No Yes
Antimony trioxide (fire retardant) 1309-64-4 Yes No Yes Yes Yes Yes
Crystalline silica 14808-60-7 No No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Antimony trioxide (fire retardant) 1309-64-4
Crystalline silica 14808-60-7
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
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Material Name: LAWX 307 Adhesives Safety Data Sheet
ID: 2055
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Water 7732-18-5 Yes Yes Yes
Calcium carbonate 1317-65-3 Yes No Yes
Aluminum (hydrated) 21645-51-2 Yes Yes Yes
Magnesium hydroxide 1309-42-8 Yes Yes Yes
Antimony trioxide (fire retardant) 1309-64-4 Yes Yes Yes
Antioxidant 68610-51-5 Yes Yes Yes
Thiabendazole [fungicide) 148-79-8 Yes No Yes
Crystalline silica 14808-60-7 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Antimony trioxide (fire retardant) 1309-64-4 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Insulation Systems
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 2054-1.0000 New MSDS authoring system.
01/10/01 2054-1.0100 Update crystalline silica Sect. 8 (ACGIH exposure guideline) and
Sect. 11 (ACGIH suspected carcinogen).
11/06/03 2054-1.0101 Regulatory review. Minor edits.
11/26/03 2054-1.0102 Section 16 division change from RID to BID
07/15/05 2054-1.0103 Regulatory updates: Sections 11 & 15
05/17/07 2054-1.0203 Addition of LAWX to Material Name in Section 1. Minor edits
throughout.
This is the end of MSDS # 2055
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