Material Safety Data Sheet
MSDS ID NO.: 0241MAR019
Revision date: 07/25/2006
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon No. 5 Fuel Oil
Synonym: No. 5 Fuel Oil
Chemical Family: Petroleum Hydrocarbon
Formula: Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information: 419-421-3070
Emergency telephone number: 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Heavy or residual fuel is a complex mixture of high molecular weight hydrocarbons produced from high temperature
treatment of heavy petroleum fractions.
Product information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon No. 5 Fuel Oil Mixture 100
Component Information:
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Catalytic Cracked Clarified Oil 64741-62-4 0-100
No. 6 Fuel Oil 68553-00-4 0-70
Middle Distillate Fuel 64741-44-2 10-30
Petroleum Residua Mixture 0-28
Sulfur Compounds Mixture 1-3
Naphthalene 91-20-3 0.01-0.15 Skin - potential = 10 ppm TWA
= 50 mg/m3 TWA
significant contribution
to overall exposure by = 15 ppm STEL
= 75 mg/m3 STEL
the cutaneous route
= 10 ppm TWA
= 15 ppm STEL
Hydrogen Sulfide 7783-06-4 0-0.01 = 10 ppm TWA = 10 ppm TWA
= 15 ppm STEL = 14 mg/m鲁 TWA
= 15 ppm STEL
= 21 mg/m鲁 STEL
Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 1 of 11
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
THIS PRODUCT IS A BROWN TO BLACK COLORED LIQUID. THIS PRODUCT IS CONSIDERED TO BE A
COMBUSTIBLE LIQUID PER THE OSHA HAZARD COMMUNICATION STANDARD AND SHOULD BE KEPT AWAY
FROM HEAT, FLAME AND SOURCES OF IGNITION. LONG-TERM SKIN EXPOSURE TO COMPONENTS OF THIS
PRODUCT HAS CAUSED CANCER IN LABORATORY ANIMALS AND HUMANS. REPEATED SKIN CONTACT TO
SOME COMPONENTS OF THIS PRODUCT HAVE PRODUCED SYSTEMIC TOXICITY (INCLUDING LIVER DAMAGE)
IN LABORATORY ANIMALS. WHEN HEATED THIS MATERIAL MAY VENT TOXIC LEVELS OF HYDROGEN SULFIDE
(H2S) VAPORS THAT ACCUMULATE IN THE VAPOR SPACES OF STORAGE AND TRANSPORT COMPARTMENTS.
H2S VAPORS CAN CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION AND ASPHYXIATION.
OSHA WARNING LABEL:
DANGER!
COMBUSTIBLE LIQUID.
LONG-TERM SKIN EXPOSURE TO COMPONENTS OF THIS PRODUCT HAS CAUSED CANCER IN LABORATORY
ANIMALS.
REPEATED SKIN CONTACT TO SOME COMPONENTS IN THIS PRODUCT HAS PRODUCED SYSTEMIC TOXICITY
(INCLUDING LIVER DAMAGE) IN LABORATORY ANIMALS.
MAY VENT HARMFUL CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS WHICH CAN CAUSE
RESPIRATORY IRRITATION AND ASPHYXIATION.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation: Exposure to vapor or mist may cause pulmonary irritation, dizziness, nausea and
loss of consciousness. Significant concentrations of hydrogen sulfide gas can be
present in the vapor space of storage tanks and bulk transport compartments (See
Sections 7, 8 & 11).
Ingestion: Product would be expected to have a low order of acute toxicity. Significant ingestion
of some components of this product may cause liver damage.
Skin contact: Prolonged and repeated liquid contact can cause dermatitis, folliculitis or oil acne.
May cause sensitization by skin contact. Components of this product can cause liver
damage if absorbed through the skin.
Eye contact: Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon No. 5 Fuel Oil NE
Mixture
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of residual (heavy) fuel oil in animals.
Component Information:
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Naphthalene Monograph 82, 2002 Reasonably Anticipated To A4 - Not Classifiable as a Present
91-20-3 Be A Carcinogen Human Carcinogen
Listed
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 2 of 11
Notes: The International Agency for Research on Cancer (IARC) has determined that there
is inadequate evidence for the carcinogenicity of diesel fuel/fuel oil in humans. IARC
determined that there was limited evidence for the carcinogenicity of marine diesel
fuel in animals. Distillate (light) diesel fuels were not classifiable as to their
carcinogeniicty to humans (Group 3A)
The International Agency for Research on Cancer (IARC) has determined that there
is sufficient evidence for the carcinogenicity of catalytically cracked clarified oil
(carbonblack feedstock) in animals.
The International Agency for Research on Cancer (IARC) and the National
Toxicology Program (NTP) have concluded that certain polycyclic aromatic
hydrocarbons, i.e. (benzo(a)pyrene, benz(a)anthracene, benzo(a)phenanthrene,
indeno(1,2,3-cd)pyrene, benzo(j)fluoranthene, benzo(j,k,fluorine,
benzo(g,h,i)perylene, and 5-methylchrysene are probably carcinogenic to humans
(Group 2A and B).
The International Agency for Research on Cancer (IARC) and the Environmental
Protection Agency (EPA) have determined that naphthalene could be a possible
human carcinogen.
4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact: Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
Ingestion: Ingestion not likely. If swallowed, do not induce vomiting and do not give liquids.
Immediately call a physician.
Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
Medical conditions aggravated Preexisting skin conditions, respiratory disorders, and impaired liver function may be
by exposure: aggravated by exposure to components of this product.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product has been determined to be a combustible liquid
per the OSHA Hazard Communication Standard and should
be handled accordingly. For additional fire related
information, see NFPA 30 or the North American Emergency
Response Guide 128.
Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Keep surrounding area cool with water
spray from a distance and prevent further ignition of
combustible material. Keep run-off water out of sewers and
water sources.
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 3 of 11
Flash point: 131(Min) F
Autoignition temperature: 765 F
Flammable limits in air - lower (%): 1.0
Flammable limits in air - upper (%): 6.0
NFPA rating: HMIS classification:
Health: 2 Health: 2
Flammability: 2 Flammability: 2
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Notify local health and pollution control agencies, if
appropriate. Contain liquid with sand or soil. Recover and return product to source.
7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Do not cut, drill, grind or weld on
empty containers since they may contain explosive residues. The fuel oil contained in this product may flash if product
temperature is >131 F.
Harmful concentrations of hydrogen sulfide (H2S) gas can be generated and accumulate in storage tanks and bulk
transport compartments. Stay upwind and vent open hatches before unloading.
Avoid skin contact. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap
and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequate
ventilation.
Respiratory protection: Not required under normal conditions and adequate ventilation. Use atmosphere
supplying respirators in confined spaces or when vapors exceed permissible limits;
otherwise, an organic vapor respirator with pre-filter for fumes can be used. Self-
contained breathing apparatus should be used for fire fighting.
Skin and body protection: Impermeable gloves (e.g., nitrile, viton, tyvek/saranex 23) to prevent skin contact.
Eye protection: Goggles and faceshield when handling hot material.
Hygiene measures: Use mechanical ventilation equipment that is explosion-proof. Chemical resistant
apron or other protective clothing may be needed to avoid skin contact.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Light-dark, Brown Liquid
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 4 of 11
Physical state (Solid/Liquid/Gas): Liquid
Substance type (Pure/Mixture): Mixture
Color: Light to dark brown.
Odor: Hydrocarbon
Molecular weight: Not determined.
pH: Neutral
Boiling point/range (5-95%): 600-1000 F
Melting point/range: Not determined.
Decomposition temperature: Not applicable.
Specific gravity: Not determined
Density: 7.4-7.8 lbs/gal
Bulk density: No data available.
Vapor density: No data available.
Vapor pressure: 1 mm Hg @ 160 F
Evaporation rate: No data available.
Solubility: Negligible
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): No data available.
Viscosity: No data available.
10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.
Polymerization: Will not occur.
Hazardous decomposition products: Combustion produces carbon monoxide, aldehydes,
aromatic and other hydrocarbons.
Materials to avoid: Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid: Sources of heat or ignition.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name CAS Number Inhalation: Dermal: Oral:
Marathon No. 5 Fuel Oil Mixture No data available No data available No data available
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 5 of 11
Summary of health effect data on No. 5 fuel oil components:
Lifetime skin painting studies in animals with products similar to Heavy catalytic cracked distillate, No. 6 fuel oil and/or its
components have produced tumors in animals following prolonged and repeated skin contact. Repeated dermal
application has produced severe irritation and systemic toxicity in subacute toxicity studies.
Lifetime skin painting studies in animals with similar distillate fuels have produced weak to moderate carcinogenic activity
following prolonged and repeated exposure. Similar middle distillates, when tested at nonirritating dose levels, did not
show any significant carcinogenic activity indicating that this tumorigenic response is likely related to chronic irritation and
not to dose. Repeated dermal application has produced severe irritation and systemic toxicity in subacute toxicity studies.
Some components of this product were found to be positive in some mutagenicity tests while negative in others. The
exact relationship between these results and human health is not known.
This product may contain >0.1% naphthalene. Exposure to naphthalene at 30 ppm for two years caused lung tumors in
female mice. Male mice with the same exposure did not develop tumors. Exposure to 10-60 ppm naphthalene for 2 years
caused tumors in the tissue lining of the nose and respiratory tract in male and female rats. Oral administration of 133-
267 mg/kg/day of naphthalene in mice for up to 90 days did not produce mortality, systemic toxicity, adversely affect
organ or body weight or produce changes in blood. Repeated oral administration of naphthalene produced an anemia in
dogs. Repeated intraperitoneal doses of naphthalene produced lung damage in mice. Repeated high doses of
naphthalene has caused the formation of cataracts and retinotoxicity in the eyes of rats and rabbits due to accumulation
of 1,2-naphthoquinone, a toxic metabolite. Effects in human eyes is uncertain and not well documented. Pregnant rats
administered intraperitoneal doses of naphthalene during gestation gave birth to offspring that had delayed heart and
bone development. Pregnant mice given near lethal doses of naphthalene showed no significant maternal toxicity and a
reduction in the number of pups per litter, but no gross abnormalities in offspring. Suppressed spermatogenesis and
progeny development have been reported in mice, rats and guinea pigs after exposure to high concentrations of
naphthalene in their drinking water. Certain groups or individuals, i.e., infants, Semites, Arabs, Asians and Blacks, with a
certain blood enzyme deficiency (glucose-6-phosphate dehydrogenase) are particularly susceptible to hemolytic agents
and can rapidly develop hemolytic anemia and systemic poisoning from ingestion or inhalation of naphthalene.
Catalytic cracked slurry oil (CCSO) may be present in concentrations up to 70% in this product. Lifetime skin painting
studies in animals with CCSO have produced tumors in animals following prolonged and repeated skin contact.
Repeated dermal application of CCSO (30 mg/kg/day for 13 weeks) in rats resulted in anemia, liver degeneration and
injury to bone marrow and lymphoid tissues. 100% mortality was observed at 2,000 mg/kg/day within three weeks.
Repeated dermal application (30 mg/kg/day) of CCSO to pregnant rats during gestation produced maternal and fetal
toxicity. Deaths and systemic toxicity (liver, thymus and blood). The number of viable offspring decreased at doses of 30
mg/kg/day and above. Many of the developmental effects (anomalies, resorptions and growth inhibition) were observed
at doses which produced maternal toxicity. In a separate developmental study CCSO produced decreases in body
weights and food consumption at doses from 10-250 mg/kg/day. Although fertility and reproductive function were not
affected, the no observable adverse effect level for CCSO administered dermally was 1 mg/kg/day.
This product contains polynuclear aromatic hydrocarbons (PAC) at a level of >0.1%. Some PACs that have been
identified in this product such as benzo(a)pyrene, benz(a)anthracene and indeno(1,2,3-cd)pyrene have been shown to be
carcinogenic in experimental animals. An increased risk of cancer has been observed in workers employed in the
aluminum production, coal gasification, coal-tar pitch, coke production and iron and steel industries that had been
occupationally exposed to polynuclear aromatic hydrocarbons. Since these kinds of PACs have been measured at high
levels in air samples taken in these industries, The International Agency for Research on Cancer (IARC) has concluded
that these PACs are probably carcinogenic to humans.
Hydrogen sulfide gas (H2S) is toxic by inhalation. Prolonged breathing of 50-100 ppm H2S vapors can produce eye and
respiratory tract irritation. Higher concentrations (250-600 ppm) for 15-30 minutes can produce headache, dizziness,
nervousness, nausea and pulmonary edema or bronchial pneumonia. Concentrations of >1000 ppm will cause immediate
unconsciousness and death through respiratory paralysis. Rats and mice exposed to 80 ppm H2S, 6 hrs/day, 5
days/week for 10 weeks, did not produce any toxicity except for irritation of nasal passages. H2S did not affect
reproduction and development (birth defects or neurotoxicity) in rats exposed to concentrations of 75-80 ppm or 150 ppm
H2S, respectively. Over the years a number of acute cases of H2S poisonings have been reported. Complete and rapid
recovery is the general rule. However, if the exposure was sufficiently intense and sustained causing cerebral hypoxia
(lack of oxygen to the brain), neurologic effects such as amnesia, intention tremors or brain damage are possible.
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 6 of 11
12. ECOLOGICAL INFORMATION
Ecotoxicity effects: Product can be toxic to fish and aquatic life. The 24 hour TLM of the water soluble
fraction of bunker C fuel oil is 3-6 ppm in marine and estuarine crustaceans and fish.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information: This material when transported via US commerce would be regulated by DOT
Regulations.
Proper shipping name: Fuel Oil, No. 5
UN/Identification No: NA 1993
Hazard Class: 3
Packing group: III
DOT reportable quantity (lbs): Not applicable.
TDG (Canada):
Proper shipping name: Fuel Oil, No. 5
UN/Identification No: NA 1993
Hazard Class: 3
Packing group: III
Regulated substances: Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard: This product has been evaluated and determined to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 7 of 11
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Catalytic Cracked Clarified Oil NA
No. 6 Fuel Oil NA
Middle Distillate Fuel NA
Petroleum Residua NA
Sulfur Compounds NA
Naphthalene NA
Hydrogen Sulfide hydrogen sulfide
SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Catalytic Cracked Clarified Oil NA
No. 6 Fuel Oil NA
Middle Distillate Fuel NA
Petroleum Residua NA
Sulfur Compounds NA
Naphthalene = 0.454 kg final RQ
= 1 lb final RQ
= 100 lb final RQ
= 45.4 kg final RQ
Hydrogen Sulfide = 100 lb final RQ
= 45.4 kg final RQ
SARA Section 311/312: The following EPA hazard categories apply to this product:
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Catalytic Cracked Clarified Oil None
No. 6 Fuel Oil None
Middle Distillate Fuel None
Petroleum Residua None
Sulfur Compounds None
Naphthalene = 0.1 % de minimis concentration
Hydrogen Sulfide None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Catalytic Cracked Clarified Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 8 of 11
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
No. 6 Fuel Oil
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Middle Distillate Fuel
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 2452
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Petroleum Residua
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 9 of 11
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Sulfur Compounds
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:
Naphthalene
Louisiana Right-To-Know: Not Listed
California Proposition 65: Listed
New Jersey Right-To-Know: Listed
Pennsylvania Right-To-Know: Listed
Massachusetts Right-To Know: Listed
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Listed
Substances List:
Illinois - Toxic Air Contaminants Listed
New York - Reporting of Releases Part 597 - Listed
List of Hazardous Substances:
Hydrogen Sulfide
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: sn 1017
Pennsylvania Right-To-Know: environmental hazard
Massachusetts Right-To Know: Extraordinarily hazardous
Florida substance List: Not Listed.
Rhode Island Right-To-Know: Toxic, Flammable
Michigan critical materials register list: Not Listed.
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 10 of 11
Massachusetts Extraordinarily Hazardous extraordinarily hazardous
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: flammable - fourth degree
New Jersey - Environmental Hazardous SN 1017
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - = 100 lbs Air RQ
List of Hazardous Substances: = 100 lbs Land/Water RQ
Canadian Regulatory Information:
Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure:
Naphthalene B4, D2A 1%
Hydrogen Sulfide A; B1; D1A; D2B 1% (English Item 851, French Item 1550)
16. OTHER INFORMATION
Additional Information: The pronounced and easily-recognized rotten egg odor of hydrogen sulfide gas
(H2S) can be detected at concentrations as low as 0.003-0.13 ppm. Since higher
H2S concentrations (100-200 ppm) cause olfactory fatigue and other hydrocarbon
odors can "mask" H2S, the sense of smell cannot be used as a reliable indicator of
H2S exposure.
Prepared by: Craig M. Parker Manager, Toxicology And Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0241MAR019 Product name: Marathon No. 5 Fuel Oil Page 11 of 11
|