|
Page 1
MATERIAL SAFETY DATA SHEET
Printed: 4/12/06
LUPEROX DDM-9 RED
PRODUCT IDENTIFICATION AND USE
MANUFACTURER: ARKEMA CANADA INC.
700 THIRD LINE
OAKVILLE, ONTARIO
L6J 5A3
EMERGENCY PHONE NUMBER: (905) 827-9841 (ARKEMA)
(613) 996-6666 (CANUTEC)
PRODUCT IDENTIFIER: LUPEROX DDM-9 RED
PRODUCT CODE: LU120
PRODUCT USE: POLYMERIZATION INITIATOR
WHMIS CLASSIFICATION: B3 鈥? COMBUSTIBLE LIQUID .
C 鈥? OXIDIZING MATERIAL.
D1B 鈥? TOXIC MATERIAL CAUSING IMMEDIATE AND SERIOUS
TOXIC EFFECTS.
D2B 鈥? TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS.
HAZARDOUS INGREDIENTS
% W/W CAS # TLV
METHYL ETHYL KETONE PEROXIDE(S) 15-40 1338-23-4 ACGIH CEILING = 0.2
LD50: 484 MG/KG (ORAL-RAT)* PPM
LD50: 4,000 MG/KG (DERMAL-RABBIT)*
LC50: 17-50 MG/ML (4-HR 鈥? INHALATION-RAT)*
HEXYLENE GLYCOL 5-10 107-41-5 ACGIH CEILING = 25
LD50: 2,800-4,700 MG/KG (ORAL-RAT) PPM
LD50: 12,300-13,200 MG/KG (DERMAL-RABBIT)
METHYL ETHYL KETONE 1-5 78-93-3 ACGIH TWA = 200
LD50: 2,700-5,600 MG/KG (ORAL-RAT) PPM
LD50: 5,000-13,000 MG/KG (DERMAL-RABBIT) ACGIH STEL = 300
LC50: 11,700 PPM (4-HR 鈥? INHALATION-RAT) PPM
HYDROGEN PEROXIDE 0.1-1 7722-84-1 ACGIH TWA = 1 PPM
LD50: 805 MG/KG (ORAL-RAT)**
LD50: >6500 MG/KG (DERMAL-RABBIT)**
LC50: 170 MG/M3 (4HR 鈥揑NHALATION RAT)**
*ACUTE TOXICITY TEST RUN ON 40-60% MEKP IN DIMETHYL PHTHALATE. PRODUCT NO LONGER
CONTAINS DIMETHYL PHTHALATE.
** 70% SOLUTION
ADDITIONAL INGREDIENT INFORMATION (WHMIS NOT CONTROLLED):
2,2,4-TIMETHYL-1,3-PENTANEDIOL DIISOBUTYRATE
PHYSICAL DATA
PHYSICAL STATE: LIQUID
ODOUR AND APPEARANCE: RED OILY LIQUID, KETONE ODOUR.
ODOUR THRESHOLD: NE
SPECIFIC GRAVITY/DENSITY (G/ML): 1.0088 @ 20掳C
VAPOUR PRESSURE: 5.2 TORR @ 19掳C
VAPOUR DENSITY (AIR=1): NE
NA - NOT APPLICABLE NE - NOT ESTABLISHED
Page 2
MATERIAL SAFETY DATA SHEET
Printed: 4/12/06
LUPEROX DDM-9 RED
VOLATILITY/VOL(%): NE
SOLUBILITY IN H20: SLIGHT
EVAPORATION RATE: NE
BOILING POINT: NE
FREEZING POINT: NE
PH: NA
LOG KOW: NE
SHIPPING INFORMATION
UN 3105, 5.2, II, ORGANIC PEROXIDE TYPE D, LIQUID. [METHYL ETHYL KETONE PEROXIDE(S), <=45%]
FIRE AND EXPLOSION HAZARD
FLAMMABILITY: COMBUSTIBLE
CONDITIONS: WILL BURN ABOVE FLASH POINT.
MEANS OF EXTINCTION: WATER SPRAY, FOAM OR DRY CHEMICAL
FLASHPOINT: 82掳C (SETA CC)
UPPER EXPLOSION LIMIT (% V): NE
LOWER EXPLOSION LIMIT (%V): NE
AUTO-IGNITION TEMPERATURE: 75掳C / 169掳F (45 LB CTN)
(SELF ACCELERATING DECOMPOSITION TEMPERATURE).
HAZARDOUS COMBUSTION PRODUCTS: NE
EXPLOSION DATA: CONTAMINATION, TEMPERATURE 鈥? CAN DECOMPOSE WITH
FORCE IF CONFINED DURING EXPOSURE TO FIRE.
SENSITIVITY TO IMPACT: NO
SENSITIVITY TO STATIC DISCHARGE: NO
REACTIVITY
CHEMICAL STABILITY: UNSTABLE
INCOMPATIBLE MATERIALS: STRONG ACIDS, ALKALIS, OXIDIZERS, TRANSITION METAL SALTS,
PROMOTERS / ACCELERATORS, & REDUCING AGENTS.
CONDITIONS OF REACTIVITY: NE
HAZARDOUS DECOMPOSITION DECOMPOSITION PRODUCTS ARE FLAMMABLE.
PRODUCTS:
HEALTH HAZARD INFORMATION
ROUTE OF ENTRY
SKIN CONTACT: MAY CAUSE SKIN IRRITATION.
SKIN ABSORPTION: MAY BE ABSORBED.
EYE: MAY CAUSE SEVERE IRRITATION OR BLINDNESS.
INGESTION: MAY BE HARMFUL
INHALATION: VAPOURS MAY CAUSE SEVERE IRRITATION
ACUTE OVER EXPOSURE EFFECTS: NE
CHRONIC OVER EXPOSURE EFFECTS: NE
SENSITIZATION: MAY CAUSE ALLERGIC SKIN REACTION.
CARCINOGENICITY: HYDROGEN PEROXIDE IS CLASSIFIED BY ACGIH AS A3 鈥?
ANIMAL CARCINOGEN. CAUSES CANCER IN ANIMALS UNDER
UNCOMMON CONDITIONS THAT MAY NOT BE RELEVANT TO
WORKER EXPOSURE.
TERATOGENICITY: METHYL ETHYL KETONE IS A POSSIBLE TERATOGEN.
MUTAGENICITY: DOES NOT MEET WHMIS CRITERIA.
REPRODUCTIVE TOXICITY: DOES NOT MEET WHMIS CRITERIA.
NA - NOT APPLICABLE NE - NOT ESTABLISHED
Page 3
MATERIAL SAFETY DATA SHEET
Printed: 4/12/06
LUPEROX DDM-9 RED
PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT: WEAR GOGGLES, FACE SHIELD, PROTECTIVE CLOTHING
AND USE IMPERVIOUS GLOVES. WEAR A NIOSH
APPROVED RESPIRATOR EQUIPPED WITH AN ORGANIC
VAPOUR CARTRIDGE.
SPECIFIC ENGINEERING CONTROLS: LOCAL EXHAUST IS RECOMMENDED.
LEAK AND SPILL PROCEDURES: USE ABSORBENT MATERIAL. SWEEP OR SCOOP AND
PLACE IN A CLOSED CONTAINER. WET DOWN WITH
WATER AND DISPOSE OF IMMEDIATELY.
WASTE DISPOSAL: HAZARDOUS WASTE. DO NOT ALLOW PRODUCT TO
ENTER THE ENVIRONMENT. CONSULT FEDERAL OR
LOCAL AUTHORITIES FOR APPROVED DISPOSAL
METHODS.
HANDLING PROCEDURES AND EQUIPMENT: WASH BEFORE EATING, DRINKING, USING TOBACCO
PRODUCTS OR REST ROOMS.
STORAGE REQUIREMENTS: KEEP IN A CLOSED, LABELED CONTAINER IN A
VENTILATED AREA. STORE BELOW 38掳C/100掳F.
FIRST AID MEASURES
EYE FLUSH EYES WITH LARGE AMOUNT OF WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. SEEK MEDICAL ATTENTION.
SKIN WASH SKIN WITH WATER AND SOAP. SEEK MEDICAL ATTENTION IF IRRITATION
OCCURS OR PERSISTS.
INGESTION DO NOT GIVE LIQUIDS IF PERSON IS UNCONSCIOUS OR VERY DROWSY. DO NOT
INDUCE VOMITING. SEEK IMMEDIATE MEDICAL ATTENTION.
INHALATION REMOVE PERSON TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED, APPLY
ARTIFICIAL RESPIRATION AND ADMINISTER OXYGEN IF NECESSARY. SEEK MEDICAL
ATTENTION.
PREPARATION DATE
PREPARED BY: TECHNICAL DEPARTMENT.
PHONE NUMBER OF PREPARER: 905-827-9841
DATE PREPARED (MM/DD/YY): 10/06/97
DATE REVISED (MM/DD/YY): 04/12/06
MINIMUM CONTACT WITH THIS AND ALL CHEMICALS IS RECOMMENDED AS A GOOD GENERAL POLICY TO
FOLLOW.
THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED TO BE
DEPENDABLE AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE. HOWEVER, SINCE DATA, SAFETY
STANDARDS, AND GOVERNMENT REGULATIONS ARE SUBJECT TO CHANGE AND THE CONDITIONS OF
HANDLING AND USE, OR MISUSE ARE BEYOND OUR CONTROL, ARKEMA CANADA MAKES NO WARRANTY
EXPRESSED OR IMPLIED, WITH RESPECT TO COMPLETENESS OR CONTINUING ACCURACY OF THE
INFORMATION CONTAINED HEREIN AND DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. USER
SHOULD SATISFY HIMSELF THAT HE HAS ALL CURRENT DATA RELEVANT TO HIS PARTICULAR USE.
NA - NOT APPLICABLE NE - NOT ESTABLISHED
