MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION Page: 1
24-Hour Emergency Phone Number: 989-636-4400
Product:AFFINITY* PF 1140G Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101
The Dow Chemical Company, Midland, MI 48674
Customer Information Center: 800-258-2436
2. COMPOSITION/INFORMATION ON INGREDIENTS
Copolymer of ethylene and octene-1 CAS# 026221-73-8 >99%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
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鈭? Translucent or white pellets or granules. Odorless. Slipping *
鈭? hazard. *
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POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.)
EYE: Solid or dust may cause irritation or corneal injury
due to mechanical action. Vapor may cause eye irritation
experienced as mild discomfort and redness.
SKIN: Brief contact is essentially non-irritating to skin.
Mechanical injury only. Under normal processing conditions,
material is heated to elevated temperatures; contact with the
material may cause thermal burns. No adverse effects
anticipated by skin absorption.
INGESTION: Very low toxicity if swallowed. Harmful effects
not anticipated from swallowing small amounts. May cause
choking if swallowed.
INHALATION: No adverse effects are anticipated from single
exposure to dust. Vapors/fumes released during thermal
processing may cause respiratory irritation.
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Additives are encapsulated
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MATERIALSAFETYDATASHEET PAGE: 2
Product:AFFINITY* PF 1140G Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101 -
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in the product and are not expected to be released under normal
processing conditions or foreseeable emergency.
CANCER INFORMATION: No relevant information found.
TERATOLOGY (BIRTH DEFECTS): No relevant information found.
REPRODUCTIVE EFFECTS: No relevant information found.
4. FIRST AID
EYE: Flush eyes thoroughly with water for several minutes.
Remove contact lenses after initial 1-2 minutes and continue
flushing for several additional minutes. If effects occur,
consult a physician, preferably an ophthalmologist.
SKIN: If molten material comes in contact with the skin, do not
apply ice but cool under ice water or running stream of water.
DO NOT attempt to remove the material from skin. Removal could
result in severe tissue damage. Seek medical attention
immediately.
INGESTION: If swallowed, seek medical attention. May cause
gastrointestinal blockage. Do not give laxatives. Do not induce
vomiting unless directed to do so by medical personnel.
INHALATION: Move person to fresh air; if effects occur, consult a
physician.
NOTE TO PHYSICIAN: If burn is present, treat as any thermal burn,
after decontamination. No specific antidote. Treatment of
exposure should be directed at the control of symptoms and the
clinical condition of the patient.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: Not applicable
METHOD USED: Not applicable
AUTOIGNITION TEMPERATURE: Not applicable
FLAMMABILITY LIMITS
LFL: Not applicable
UFL: Not applicable
HAZARDOUS COMBUSTION PRODUCTS: During a fire, smoke may contain
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* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
MATERIALSAFETYDATASHEET PAGE: 3
Product:AFFINITY* PF 1140G Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101
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the original material in addition to combustion products of
varying composition which may be toxic and/or irritating.
Combustion products may include and are not limited to: carbon
monoxide, carbon dioxide.
OTHER FLAMMABILITY INFORMATION: Pneumatic conveying and other
mechanical handling operations can generate combustible dust.
To reduce the potential for dust explosions, do not permit
dust to accumulate. Dense smoke is emitted when burned without
sufficient oxygen.
EXTINGUISHING MEDIA: Water fog or fine spray, dry chemical fire
extinguishers, carbon dioxide fire extinguishers and foam. General
purpose synthetic foams (including AFFF type) or protein foams are
preferred if available. Alcohol resistant foams (ATC type) may
function.
FIRE FIGHTING INSTRUCTIONS: Keep people away. Isolate fire area
and deny unnecessary entry. Soak thoroughly with water to cool
and prevent re-ignition. If material is molten, do not apply
direct water stream. Use fine water spray or foam. Cool
surroundings with water to localize fire zone. Hand held dry
chemical or carbon dioxide extinguishers may be used for small
fires.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive-pressure,
self-contained breathing apparatus (SCBA) and protective fire
fighting clothing (includes fire fighting helmet, coat, pants,
boots, and gloves). If protective equipment is not available or
not used, fight fire from a protected location or safe
distance.
6. ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory
Information)
PROTECT PEOPLE: Spilled material may cause a slipping hazard. Use
appropriate safety equipment. For additional information, refer
to Section 8, Exposure Controls and Personal Protection.
PROTECT THE ENVIRONMENT: Prevent from entering into soil, ditches,
sewers, waterways and/or groundwater. See Section 12, Ecological
Information.
CLEANUP: Sweep up. Contain spilled material if possible. Collect
in suitable and properly labeled containers. See Section 13,
Disposal Considerations for additional information.
7. HANDLING AND STORAGE
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MATERIALSAFETYDATASHEET PAGE: 4
Product:AFFINITY* PF 1140G Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101 -
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HANDLING: Avoid breathing process fumes. Electrically ground all
equipment. When appropriate, unique handling information for
containers can be found on the product label.
STORAGE: Store in accordance with good manufacturing practices.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Good general ventilation should be
sufficient for most conditions. Local exhaust ventilation
may be necessary for some operations.
PERSONAL PROTECTIVE EQUIPMENT
EYE/FACE PROTECTION: Use safety glasses. If there is a
potential for exposure to particles which could cause eye
discomfort, wear chemical goggles. If exposure causes eye
discomfort, use a full-face respirator.
SKIN PROTECTION: No precautions other than clean body-covering
clothing should be needed. Use gloves with insulation for
thermal protection, when needed.
RESPIRATORY PROTECTION: Use an approved air-purifying respirator
when vapors are generated at increased temperatures or when dust
or mist is present.
EXPOSURE GUIDELINE(S): None established.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE: Translucent white, pellets or granules
ODOR: Odorless
VAPOR PRESSURE: Not applicable VAPOR
DENSITY: Not applicable BOILING POINT: Not
applicable SOLUBILITY IN
WATER/MISCIBILITY: Nil SPECIFIC GRAVITY OR
DENSITY: 0.84 - 0.97
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable.
CONDITIONS TO AVOID: Exposure to elevated temperatures can cause
product to decompose.
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* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
MATERIALSAFETYDATASHEET PAGE: 5
Product:AFFINITY* PF 114OG Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101
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INCOMPATIBILITY WITH OTHER MATERIALS: None known.
HAZARDOUS DECOMPOSITION PRODUCTS: Decomposition products depend
upon temperature, air supply and the presence of other
materials. Processing may release fumes and other
decomposition products. At temperatures exceeding melt
temperatures, polymer fragments can be released. Fumes can
be irritating. Decomposition products can include and are not
limited to: carbon monoxide, carbon dioxide, aldehydes,
alcohols, organic acids. Decomposition products can include
trace amounts of hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health
Effects. For detailed toxicological data, write or call the
address or non-emergency number shown in Section 1)
SKIN: The dermal LD50 has not been determined.
INGESTION: Single dose oral LD50 has not been determined.
MUTAGENICITY: No relevant information found.
12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call
the address or non-emergency number shown in Section 1)
ENVIRONMENTAL FATE
MOVEMENT & PARTITIONING: No bioconcentration is expected
because of the relatively high molecular weight (MW >1000).
In the terrestrial environment, material is expected to remain
in the soil. In the aquatic environment, material is expected
to float.
DEGRADATION & PERSISTENCE: This water insoluble polymeric
solid is expected to be inert in the environment. Surface
photodegradation is expected with exposure to sunlight. No
appreciable biodegradation is expected.
ECOTOXICITY: Not expected to be acutely toxic, but pellets may
mechanically cause adverse effects if ingested by waterfowl or
aquatic life.
13. DISPOSAL CONSIDERATIONS (See Section 15 for Regulatory Information)
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MATERIALSAFETYDATASHEET PAGE: 6
Product:AFFINITY* PF 1140G Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101
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DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY
BODY OF WATER. All disposal methods must be in compliance with
all Federal, State/Provincial and local laws and regulations.
Regulations may vary in different locations. Waste character-
izations and compliance with applicable laws are the responsi-
bility solely of the waste generator. THE DOW CHEMICAL COMPANY
HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS
SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2
(Composition/Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options in-
clude sending to a licensed, permitted: recycler, reclaimer,
incinerator or other thermal destruction device, and landfill.
For additional information, refer to Stability & Reactivity
Information, MSDS Section 10.
As a service to its customers, Dow can provide names of
information resources to help identify waste management
companies and other facilities which recycle, reprocess or
manage chemicals or plastics, and that manage used drums.
Telephone Dow's Customer Information Center at 800-258-2436
or 989-832-1556 for further details.
14. TRANSPORT INFORMATION
DEPARTMENT OF TRANSPORTATION (D.O.T.): This product is not regulated by
D.O.T. when shipped domestically by land.
CANADIAN TDG INFORMATION: This product is not regulated by TDG
when shipped domestically by land.
15. REGULATORY INFORMATION (Not meant to be all-inclusive--selected
regulations represented)
NOTICE: The information herein is presented in good faith and believed
to be accurate as of the effective date shown above. However, no
warranty, express or implied is given. Regulatory requirements are
subject to change and may differ from one location to another; it is
the buyer's responsibility to ensure that its activities comply with
federal, state or provincial, and local laws. The following specific
information is made for the purpose of complying with numerous federal,
state or provincial, and local laws and regulations.
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* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
MATERIALSAFETYDATASHEET PAGE: 7
Product:AFFINITY* PF 1140G Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101
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other sections for health and safety information.
U.S. REGULATIONS
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SARA 313 INFORMATION: To the best of our knowledge, this product
contains no chemical subject to SARA Title III Section 313 supplier
notification requirements.
鈭?- - - - - - - - - - - - - - - - - - - -
SARA HAZARD CATEGORY: This product has been reviewed according to the EPA
"Hazard Categories" promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following
categories:
Not to have met any hazard category
鈭? --------------------
TOXIC SUBSTANCES CONTROL ACT (TSCA):
All ingredients are on the TSCA inventory or are not required to be
listed on the TSCA inventory.
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STATE RIGHT-TO-KNOW: This product is not known to contain any
substances subject to the disclosure requirements of
New Jersey
Pennsylvania
鈭? --------------------
OSHA HAZARD COMMUNICATION STANDARD:
This product is not a "Hazardous Chemical" as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.
CANADIAN REGULATIONS -
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MATERIALSAFETYDATASHEET PAGE: 8
Product:AFFINITY* PF 114OG Polyolefin Plastomer
Product Code: 95835
Effective Date: 08/28/02 Date Printed: 06/16/04 MSD: 002101 -
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REGULATORY INFORMATION (CONTINUED)
WHMIS INFORMATION: The Canadian Workplace Hazardous Materials
Information System (WHMIS) Classification for this product is:
This product is not a "Controlled Product" under WHMIS. -
-------------------CANADIAN ENVIRONMENTAL
PROTECTION ACT (CEPA):
All substances in this product are listed on the Canadian Domestic
Substances List (DSL) or are not required to be listed.
16. OTHER INFORMATION
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS:
Health 0
Flammability 1
Reactivity 0
MSDS STATUS: Revised Section 6.
* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
The Information Herein Is Given In Good Faith, But No Warranty,
Express Or Implied, Is Made. Consult The Dow Chemical Company
For Further Information.
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