THE DOW CHEMICAL COMPANY
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 1 of 13
Dow (hereinafter, and for purposes of this MSDS only, refers to The Dow Chemical Company and to Dow
Chemical Canada Inc.) encourages and expects you to read and understand the entire MSDS, as there is
important information throughout the document. Dow expects you to follow the precautions identified in
this document unless your use conditions would necessitate other appropriate methods or actions.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1.1 IDENTIFICATION
Product Name AMPLIFY* GR 209 Functional Polymer
1.2 COMPANY IDENTIFICATION
The Dow Chemical Company
Midland, MI 48674
1.3 EMERGENCY TELEPHONE NUMBER
24-HOUR EMERGENCY TELEPHONE NUMBER: (989)636-4400.
Customer Information Number: 1-800-258-2436.
* or 庐 Indicates a Trademark of The Dow Chemical Company.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 2 of 13
2. COMPOSITION INFORMATION
Component CAS # Amount (%W/W )
2,5-Furandione Modified Ethylene/Butene- Not available >= 99 %
1 Polymer
2,5-Furandione 108-31-6 < 0.1%
3. HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
White to off-white
Appearance
Pellets
Physical
State
Acidic
Odor
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
Hazards of
SLIPPING HAZARD.
product
3.2 POTENTIAL HEALTH EFFECTS
Effects of Single Acute Overexposure
Inhalation No adverse effects are anticipated from single exposure to dust. Vapors/fumes
released during thermal processing may cause respiratory irritation. For the minor component(s):
Maleic anhydride. May cause allergic respiratory response.
Eye Contact Solid or dust may cause irritation or corneal injury due to mechanical action.
Vapor may cause eye irritation experienced as mild discomfort and redness.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 3 of 13
Skin Contact Brief contact is essentially nonirritating to skin. Mechanical injury only. Under
normal processing conditions, material is heated to elevated temperatures; contact with the
material may cause thermal burns.
Skin Absorption No adverse effects anticipated by skin absorption.
Swallowing Very low toxicity if swallowed. Harmful effects not anticipated from swallowing
small amounts. May cause choking if swallowed.
Chronic, Prolonged or Repeated Overexposure
Other Effects of Overexposure No information available.
See Section 11 for toxicological information and additional information about potential health
effects.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
See Section 12 for Ecological Information.
4. FIRST AID PROCEDURES
4.1 INHALATION
Move person to fresh air; if effects occur, consult a physician.
4.2 EYE CONTACT
Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2
minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
4.3 SKIN CONTACT
If molten material comes in contact with the skin, do not apply ice but cool under ice water or
running stream of water. DO NOT attempt to remove the material from skin. Removal could
result in severe tissue damage. Seek medical attention immediately.
4.4 SWALLOWING
If swallowed, seek medical attention. May cause gastrointestinal blockage. Do not give
laxatives. Do not induce vomiting unless directed to do so by medical personnel.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 4 of 13
4.5 NOTES TO PHYSICIAN
May cause respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants
and antitussives may be of help.
If burn is present, treat as any thermal burn, after decontamination.
No specific antidote.
Treatment of exposure should be directed at the control of symptoms and the clinical condition of
the patient.
5. FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES - REFER TO SECTION 9, PHYSICAL AND
CHEMICAL PROPERTIES
5.2 EXTINGUISHING MEDIA
Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers.
Foam. General purpose synthetic foams (including AFFF type) or protein foams are preferred if
available. Alcohol resistant foams (ATC type) may function.
5.3 FIRE FIGHTING PROCEDURES
Keep people away. Isolate fire and deny unnecessary entry. Soak thoroughly with water to cool
and prevent re-ignition. If material is molten, do not apply direct water stream. Use fine water
spray or foam. Cool surroundings with water to localize fire zone. Hand held dry chemical or
carbon dioxide extinguishers may be used for small fires.
5.4 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting
clothing (includes fire fighting helmet, coat, pants, boots, and gloves). If protective equipment is
not available or not used, fight fire from a protected location or safe distance.
5.5 UNUSUAL FIRE AND EXPLOSION HAZARDS
Pneumatic conveying and other mechanical handling operations can generate combustible dust.
To reduce the potential for dust explosions, do not permit dust to accumulate.
Dense smoke is emitted when burned without sufficient oxygen.
5.6 HAZARDOUS COMBUSTION PRODUCTS
During a fire, smoke may contain the original material in addition to combustion products of
varying composition which may be toxic and/or irritating. Combustion products may include and
are not limited to: Carbon monoxide. Carbon dioxide.
6. ACCIDENTAL RELEASE MEASURES
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 5 of 13
Steps to be Taken if Material is Released or Spilled:
Sweep up. Contain spilled material if possible. Collect in suitable and properly labeled
containers. See Section 13, Disposal Considerations for additional information.
Personal Precautions: Spilled material may cause a slipping hazard. Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal
Protection.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/
or groundwater. See Section 12, Ecological Information.
7. HANDLING AND STORAGE
7.1 HANDLING
General Handling
Avoid breathing process fumes.
Electrically ground all equipment.
When appropriate, unique handling information for containers can be found on the product label.
Ventilation
Provide general and/or local exhaust ventilation to control airborne levels below the exposure
guidelines.
7.2 STORAGE
Store in accordance with good manufacturing practices.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 EXPOSURE LIMITS
Component Exposure Limits Skin Form
2,5-Furandione 0.1 ppm TLV; SEN; A4 ACGIH
0.25 ppm PEL OSHA
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 6 of 13
In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the
Form Column for a particular limit, the listed limit includes all airborne forms of the substance
that can be inhaled.
A "Yes" in the Skin Column indicates a potential significant contribution to overall exposure by
the cutaneous (skin) route, including mucous membranes and the eyes, either by contact with
vapors or by direct skin contact with the substance. A "Blank" in the Skin Column indicates that
exposure by the cutaneous (skin) route is not a potential significant contributor to overall
exposure.
8.2 PERSONAL PROTECTION
Atmospheric levels should be maintained below the exposure
Respiratory
guideline. When respiratory protection is required, use an approved
Protection:
air-purifying or positive-pressure supplied-air respirator depending on
the potential airborne concentration.
Provide general and/or local exhaust ventilation to control airborne
Ventilation:
levels below the exposure guidelines.
Use safety glasses.
Eye Protection:
If there is a potential for exposure to particles which could cause eye
discomfort, wear chemical goggles.
If exposure causes eye discomfort, use a full-face respirator.
Use gloves chemically resistant to this material when prolonged or
Other Protective
frequently repeated contact could occur.
Equipment:
Use gloves with insulation for thermal protection, when needed.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Pellets
Appearance: White to off-white
Odor: Acidic
Flash Point - Closed Cup: No test data available.
Flammable Limits In Air:
Lower No test data available.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 7 of 13
Upper No test data available.
Autoignition Temperature: ~ 350 掳C ~ > 662 掳F
Vapor Pressure: Not applicable.
Boiling Point (760 mmHg): Not applicable.
Vapor Density (air = 1): Not applicable.
Specific Gravity (H2O = 1): 0.84 - 0.97
Freezing Point: Not applicable.
Melting Point: No test data available.
Solubility in Water (by weight): No test data available.
pH: No test data available.
10. STABILITY AND REACTIVITY
10.1 STABILITY/INSTABILITY Stable
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.
Incompatible Materials: None known.
Thermal Decomposition: Decomposition products depend upon temperature, air supply and
the presence of other materials. Processing may release fumes and other decomposition
products. At temperatures exceeding melt temperatures, polymer fragments can be released.
Fumes can be irritating. Decomposition products can include and are not limited to: Carbon
dioxide. Carbon monoxide. Alcohols. Aldehydes. Organic acids. Decomposition products can
include trace amounts of: Hydrocarbons.
10.2 HAZARDOUS POLYMERIZATION Will not occur.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 8 of 13
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Peroral
Single dose oral LD50 has not been determined.
Percutaneous
The dermal LD50 has not been determined.
12. ECOLOGICAL INFORMATION
12.1 ENVIRONMENTAL FATE
This water-insoluble polymeric solid is expected to be inert in the environment. Surface
photodegradation is expected with exposure to sunlight. No appreciable biodegradation is
expected.
12.2 ECOTOXICITY
Not expected to be acutely toxic, but pellets may mechanically cause adverse effects if ingested
by waterfowl or aquatic life.
12.3 FURTHER INFORMATION
No bioconcentration is expected because of the relatively high molecular weight (MW > 1000).
In the terrestrial environment, material is expected to remain in the soil. In the aquatic
environment, material is expected to float.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 9 of 13
13. DISPOSAL CONSIDERATIONS
13.1 DISPOSAL
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION
PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED
CONDITION AS DESCRIBED IN MSDS SECTION 2 (Composition/ Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a
licensed, permitted: recycler. reclaimer. incinerator or other thermal destruction device. landfill.
As a service to its customers, Dow can provide names of information resources to help identify
waste management companies and other facilities which recycle, reprocess or manage
chemicals or plastics, and that manage used drums. Telephone Dow's Customer Information
Group at 1-800-258-2436 or 1-989-832-1556 (U.S.), or 1-800-331-6451 (Canada) for further
details .
14. TRANSPORT INFORMATION
14.1 U.S. D.O.T.
NON-BULK
Proper Shipping Name : NOT REGULATED
BULK
Proper Shipping Name : NOT REGULATED
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information
can be obtained through an authorized sales or customer service representative. It is the
responsibility of the transporting organization to follow all applicable laws, regulations and rules
relating to the transportation of the material.
15. REGULATORY INFORMATION
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 10 of 13
15.1 FEDERAL/NATIONAL
OSHA HAZARD COMMUNICATION STANDARD
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT) SECTION 313
To the best of our knowledge this product does not contain chemicals at levels which
require reporting under this statute.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT)SECTIONS 311 AND 312
Delayed (Chronic) Health Hazard : No
Fire Hazard : No
Immediate (Acute) Health Hazard : Yes
Reactive Hazard : No
Sudden Release of Pressure Hazard : No
CEPA - DOMESTIC SUBSTANCES LIST (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances
List (DSL) or are not required to be listed.
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS)
The components of this product are on the EINECS inventory or are exempt from EINECS
inventory requirements.
TOXIC SUBSTANCES CONTROL ACT (TSCA)
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 11 of 13
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements.
15.2 STATE/LOCAL
PENNSYLVANIA (WORKER AND COMMUNITY RIGHT TO KNOW ACT): PENNSYLVANIA HAZARDOUS SUBSTANCES
LIST AND/OR PENNSYLVANIA ENVIRONMENTAL HAZARDOUS SUBSTANCE LIST:
To the best of our knowledge this product does not contain chemicals at levels which require
reporting under this statute.
PENNSYLVANIA (WORKER AND COMMUNITY RIGHT TO KNOW ACT): PENNSYLVANIA SPECIAL HAZARDOUS
SUBSTANCES LIST:
To the best of our knowledge this product does not contain chemicals at levels which require
reporting under this statute.
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986)
This product contains no listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
This section provides selected regulatory information on this product including its components.
This is not intended to include all regulations. It is the responsibility of the user to know and
comply with all applicable rules, regulations and laws relating to the product being used.
16. OTHER INFORMATION
16.1 ADDITIONAL INFORMATION
No additional information available.
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 12 of 13
16.2 HAZARD RATING SYSTEM
NFPA ratings for this product are: H - 0 F- 1 R-0
These ratings are part of a specific hazard communication program and should be disregarded
where individuals are not trained in the use of this hazard rating system. You should be familiar
with the hazard communication programs applicable to your workplace.
16.3 RECOMMENDED USES AND RESTRICTIONS
A polyethylene plastic.
For industrial conversion as a raw material for manufacture of articles or goods.
Dow recommends that you use this product in a manner consistent with the listed use. If your
intended use is not consistent with Dow's stated use, please contact Dow's Customer
Information Group at 1-800-258-2436 (U.S.) or 1-800-331-6451 (Canada) for more information.
FOR INDUSTRY USE ONLY.
16.4 REVISION
Version: 3.0
Revision: 09/27/2002
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
16.5 LEGEND
Bacterial/NA Non Acclimated Bacteria
F Fire
H Health
IHG Industrial Hygiene Guideline
N/A Not available
NFPA National Fire Protection Association
O Oxidizer
R Reactivity
TS Trade secret
VOL/VOL Volume/Volume
W Water Reactive
W/W Weight/Weight
MATERIAL SAFETY DATA SHEET
Product Name: AMPLIFY* GR 209 Functional Polymer Effective Date: 09/27/2002
MSDS#: 22418 Page 13 of 13
NOTICE: Dow urges each customer or recipient of this MSDS to study it carefully and consult
appropriate expertise, as necessary or appropriate, to become aware of and understand the data
contained in this MSDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above.
However, no warranty, express or implied, is given., Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure
that its activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of Dow, it is the buyer's/user's duty to determine the conditions
necessary for the safe use of this product., Due to the proliferation of sources for information
such as manufacturer-specific MSDSs, Dow is not and cannot be responsible for MSDSs
obtained from any source other than Dow. If you have obtained a Dow MSDS from a non-Dow
source or if you are not sure that a Dow MSDS is current, please contact Dow for the most
current version.
|