SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
POURABLE SEALER S-10 PART A
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Synonyms: none
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance or the preparation:
Construction: Sealing compound
1.3 Company/undertaking identification:
Firestone Building Products
Ikaroslaan 75
B-1930 Zaventem
Tel. : +32 2 711 44 50
Fax : +32 2 721 27 18
Email: info@fbpe.be
1.4 Telephone number for emergency:
+32 70 245 245
Poison Centre
p/a Militair Hospitaal Koningin Astrid, Bruynstraat 1, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
calcium carbonate 471-34-1 30-45 - -
207-439-9
silicon dioxide 7631-86-9 3-12 - -
231-545-4
3. Hazards identification
- No hazard classification in accordance with directives 67/548/EEC and
1999/45/EC
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with water
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Rinse with water
- Soap may be used
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
Printing date : 02-2006 1/1
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
( +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 18-01-2006 Revision date :
Reference number : BIG\43104GB Revision number : 000
Reason for revision :
POURABLE SEALER S-10 PART A
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Water spray
- Polyvalent foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- Combustible
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
carbon monoxide - carbon dioxide)
5.4 Instructions:
- Dilute toxic gases with water spray
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Contain leaking substance
6.3 Methods for cleaning up:
- Take up liquid spill into a non combustible material e.g.: sand
- Scoop absorbed substance into closing containers
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
- Observe normal hygiene standards
7.2 Storage:
- Keep container tightly closed
- Store at room temperature
- Keep out of direct sunlight
- Store in a dry area
- Keep away from: heat sources, oxidizing agents, combustible materials,
acids, bases, water/moisture
Storage temperature : 15/25 掳C
Quantity limits : N.D. kg
Storage life : 365 days
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
Printing date : 02-2006 2/2
POURABLE SEALER S-10 PART A
8. Exposure controls/Personal protection
8.1 Exposure limit values:
calcium carbonate
mg/m3
TLV-TWA : (10) ppm
mg/m3
TLV-STEL :- ppm
mg/m3
OES-LTEL : 4 R/10 I - ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : ppm
3
MAC-TGG 8 h : mg/m
3
MAC-TGG 15 min. : mg/m
mg/m3
VME-8 h : 10 - ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 10 - ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
silicon dioxide
mg/m3
TLV-TWA : (0.1 R/10 I) ppm
mg/m3
TLV-STEL : (-) ppm
mg/m3
OES-LTEL : 2.4 R/6 I - ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : 0.3 A/4 E ppm
mg/m3
MAC-TGG 8 h :
mg/m3
MAC-TGG 15 min. :
mg/m3
VME-8 h : ppm
mg/m3
VLE-15 min. : ppm
mg/m3
GWBB-8 h : 0.1R/2 rook/10 I - ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
Sampling methods:
- Silica, Amorphous (Respirable) NIOSH 7501
- Silica, Amorphous OSHA CSI
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- Respiratory protection not required in normal conditions
8.3.2 hand protection:
- Gloves
Suitable materials: Rubber
- Breakthrough time: N.D.
Printing date : 02-2006 3/3
POURABLE SEALER S-10 PART A
8.3.3 eye protection:
- Safety glasses
8.3.4 skin protection:
- Protective clothing
Suitable materials: Rubber
9. Physical and chemical properties
9.1 General information:
Appearance (at 20掳C) : Liquid
Odour : Mild
Colour : Light grey
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : N.D. 掳C
Flashpoint : 185 掳C
Explosion limits : N.D. vol% ( 掳C)
Vapour pressure (at 20掳C) : < 0.1 hPa
Vapour pressure (at 50掳C) : N.D. hPa
Relative density (at 20掳C) : 1.3
Water solubility : Poorly soluble
Soluble in : N.D.
Relative vapour density : >2
Viscosity : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 掳C
Auto-ignition point : N.D. 掳C
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, oxidizing agents, combustible materials,
acids, bases, water/moisture
10.3 Hazardous decomposition products:
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours,
carbon monoxide - carbon dioxide)
Printing date : 02-2006 4/4
POURABLE SEALER S-10 PART A
11. Toxicological information
11.1 Acute toxicity:
LD50 oral rat : N.D. mg/kg
LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : not listed
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : C (silicon dioxide)
IARC classification : not listed
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms:
- Unlikely to cause harmful effects
11.5 Chronic effects:
- Contains a substance of group C (MAK-Schwangerschaftsgruppe)( silicon
dioxide)
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
Printing date : 02-2006 5/5
POURABLE SEALER S-10 PART A
12. Ecological information
12.1 Ecotoxicity:
- No data available
12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
- Poorly soluble in water
- Substance sinks in water
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : N.D. % ThOD
- water : - No data available
- soil : T 陆: N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK : N.D.
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (75/442/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 08 04 10 (waste adhesives and sealants other than those
mentioned in 08 04 09)
13.2 Disposal methods:
- Recycle/reuse
- Do not discharge into the sewer
- Do not discharge into surface water
13.3 Packaging/Container:
- No available data
Printing date : 02-2006 6/6
POURABLE SEALER S-10 PART A
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
UN number :-
CLASS : NOT SUBJECT
SUB RISKS :
PACKING :
PROPER SHIPPING NAME :
14.2 ADR (transport by road)
CLASS : NOT SUBJECT
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.3 RID (transport by rail)
CLASS :
PACKING : NOT SUBJECT
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.4 ADNR (transport by inland waterways)
CLASS : NOT SUBJECT
PACKING :
CLASSIFICATION CODE :
DANGER LABEL TANKS :
DANGER LABEL PACKAGES :
14.5 IMDG (maritime transport)
CLASS : NOT SUBJECT
SUB RISKS :
PACKING :
MFAG :
EMS :
MARINE POLLUTANT :
14.6 ICAO (air transport)
CLASS : NOT SUBJECT
SUB RISKS :
PACKING :
PACKING INSTRUCTIONS PASSENGER AIRCRAFT :
PACKING INSTRUCTIONS CARGO AIRCRAFT :
14.7 Special precautions in connection with : not restricted for any mode of
transport international transport
15. Regulatory information
Classification according to directives 67/548/EEC and 1999/45/EC
NOT APPLICABLE
Printing date : 02-2006 7/7
POURABLE SEALER S-10 PART A
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered as a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
OES : Occupational Exposure Standards - United Kingdom
MEL : Maximum Exposure Limits - United Kingdom
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
TRK : Technische Richtkonzentrationen - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d鈥橢xposition - France
VLE : Valeurs limites d鈥橢xposition 脿 court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC
I : Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
R : Respirable fraction = A: Alveoleng盲ngiger Aerosolanteil/Alveolar dust
C : Ceiling limit
a: aerosol r: rook/Rauch (fume)
d: damp (vapour) st: stof/Staub (dust)
du: dust ve: vezel (fibre)
fa: Faser (fibre) va: vapour
fi: fibre om: oil mist
fu: fume on: olienevel/脰lnebel (oil mist)
p: poussi猫re (dust) part: particles
Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands
Printing date : 02-2006 8/8
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