SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
SPLICE WASH SW-100
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Synonyms: none
CAS No. : 64742-89-8
EC index No. : 649-267-00-0 NFPA code : N.D.
EINECS No. : 265-192-2 Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance or the preparation:
Solvent
Cleansing agent
1.3 Company/undertaking identification:
Firestone Building Products
Ikaroslaan 75
B-1930 Zaventem
Tel. : +32 2 711 44 50
Fax : +32 2 721 27 18
Email: info@fbpe.be
1.4 Telephone number for emergency:
+32 70 245 245
Poison Centre
p/a Militair Hospitaal Koningin Astrid, Bruynstraat 1, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
low boiling point naphtha 64742-89-8 100 F;Xn;N 12-38-51/53-65-67
(conc benzene < 0.1%) (Labelling in compliance
265-192-2 with CONCAWE )( (1)
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Highly flammable
- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
- Harmful: may cause lung damage if swallowed
- Repeated exposure may cause skin dryness or cracking
- Vapours may cause drowsiness and dizziness
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with water
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Wash immediately with lots of water
Printing date : 10-2006 1/1
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
( +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 18-01-2006 Revision date :
Reference number : BIG\43021GB Revision number : 000
Reason for revision :
SPLICE WASH SW-100
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Water spray
- Alcohol-resistant foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- Solid water jet ineffective as extinguishing medium
5.3 Special exposure hazards:
- Gas/vapour spreads at floor level: ignition hazard
- May build up electrostatic charges: risk of ignition
- Upon combustion CO and CO2 are formed
5.4 Instructions:
- Cool tanks/drums with water spray/remove them into safety
- Take account of environmentally hazardous firefighting water
- Use firefighting water moderately and contain it
- Do not move the load if exposed to heat
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Large spills/in enclosed spaces: compressed air apparatus
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain released substance, pump over in suitable containers
- Plug the leak, cut off the supply
- Dam up the liquid spill
- Try to reduce evaporation
6.3 Methods for cleaning up:
- Take up liquid spill into inert absorbent material
- Scoop absorbed substance into closing containers
- Carefully collect the spill/leftovers
- Damaged/cooled tanks must be emptied
- Do not use compressed air for pumping over spills
- Clean contaminated surfaces with a soap solution
- Take collected spill to manufacturer/competent authority
7. Handling and storage
7.1 Handling:
- Observe strict hygiene
- Use spark-/explosionproof appliances and lighting system
- Handle uncleaned empty containers as full ones
- Do not discharge the waste into the drain
- Clean contaminated clothing
Printing date : 10-2006 2/2
SPLICE WASH SW-100
7.2 Storage:
- Keep container tightly closed
- Limited time of storage
- Store at room temperature
- Keep out of direct sunlight
- Keep away from: heat sources, ignition sources, oxidizing agents, acids,
bases
Storage temperature : 15/25 掳C
Quantity limits : N.D. kg
Storage life : 365 days
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
TLV-TWA : not listed
TLV-STEL : not listed
TLV-Ceiling : not listed
WEL-LTEL : not listed
WEL-STEL : not listed
MAK : not listed
TRK : not listed
MAC-TGG 8 h : not listed
MAC-TGG 15 min. : not listed
MAC-Ceiling : not listed
VME-8 h : not listed
VLE-15 min. : not listed
GWBB-8 h : not listed
GWK-15 min. : not listed
Momentary value : not listed
EC : not listed
EC-STEL : not listed
Sampling methods:
- Petroleum Distillate (Naphthas) NIOSH 1550
- Petroleum Distillates (Naphtha) OSHA 48
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- High vapour concentration: gas mask with filter A
Printing date : 10-2006 3/3
SPLICE WASH SW-100
8.3.2 hand protection:
- Gloves
Suitable materials: PVA
Rubber
- Breakthrough time: N.D.
8.3.3 eye protection:
- Protective goggles
8.3.4 skin protection:
- Protective clothing
Suitable materials: PVA
Rubber
9. Physical and chemical properties
9.1 General information:
Appearance (at 20掳C) : Liquid
Odour : Petroleum-like
Colour : Pale coloured
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : 120/139 掳C
Flashpoint : 13 掳C
Explosion limits : 1/7 vol% ( 掳C)
Vapour pressure (at 20掳C) : 34 hPa
Vapour pressure (at 50掳C) : N.D. hPa
Relative density (at 20掳C) : 0.72/0.79
Water solubility : Insoluble
Soluble in : N.D.
Relative vapour density : 3.8
Viscosity : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : 1.2
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 掳C
Auto-ignition point : N.D. 掳C
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, ignition sources, oxidizing agents, acids,
bases
10.3 Hazardous decomposition products:
- Upon combustion CO and CO2 are formed
Printing date : 10-2006 4/4
SPLICE WASH SW-100
11. Toxicological information
11.1 Acute toxicity:
LD50 oral rat : 8000 mg/kg
LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : 3400 ppm/4 h
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : not listed
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : not listed
IARC classification :3
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms:
- AFTER INHALATION
- CNS depression
- Nausea
- Headache
- Dizziness
- Feeling of weakness
- Disturbances of consciousness
- AFTER INGESTION
- Risk of aspiration pneumonia
- AFTER SKIN CONTACT
- ON CONTINUOUS EXPOSURE/CONTACT:
- Dry skin
- Cracking of the skin
- AFTER EYE CONTACT
- Irritation of the eye tissue
- Redness of the eye tissue
- Lacrimation
11.5 Chronic effects:
- Not classifiable as a human carcinogen
- Not listed in mutagenicity class (EC,MAK)
- Not classified as toxic to reproduction (EC)
Printing date : 10-2006 5/5
SPLICE WASH SW-100
12. Ecological information
12.1 Ecotoxicity:
- No data available
12.2 Mobility:
- Volatile organic compounds (VOC): 100%
- Insoluble in water
- Substance floats in water
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : N.D. % ThOD
- water : - No data available
- soil : T 陆: N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK :2 (Classification in compliance with Verwaltungsvorschrift
wassergef盲hrdender Stoffe (VwVwS) of 27 July 2005)
- Effect on the ozone layer : Not dangerous for the ozone layer
(Council Regulation (EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 14 06 03* (other solvents and solvent mixtures)
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Recycle by distillation
- Remove to an authorized waste incinerator for solvents
- Do not discharge into drains or the environment
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 10-2006 6/6
SPLICE WASH SW-100
14. Transport information
33
1268
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 1268
CLASS :3
SUB RISKS :-
PACKING : II
PROPER SHIPPING NAME :
UN 1268, Petroleum distillates, n.o.s. or Petroleum products, n.o.s. (low
boiling point naphtha), Special provision 640D
14.2 ADR (transport by road)
CLASS : 3
PACKING : II
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.3 RID (transport by rail)
CLASS : 3
PACKING : II
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.4 ADNR (transport by inland waterways)
CLASS : 3
PACKING : II
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.5 IMDG (maritime transport)
CLASS : 3
SUB RISKS : -
PACKING : II
MFAG : -
EMS : F-E, S-E
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 3
SUB RISKS : -
PACKING : II
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 305/Y305
PACKING INSTRUCTIONS CARGO AIRCRAFT : 307
14.7 Special precautions in connection with : none
transport
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- 鈥楿N 1268'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'
Printing date : 10-2006 7/7
SPLICE WASH SW-100
15. Regulatory information
Classification and labelling based on the properties and in compliance with
CONCAWE recommendations
Highly flammable Harmful Dangerous for the
environment
contains: low boiling point naphtha
R11 : Highly flammable
R51/53 : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
R65 : Harmful: may cause lung damage if swallowed
R66 : Repeated exposure may cause skin dryness or cracking
R67 : Vapours may cause drowsiness and dizziness
S(02) : (Keep out of reach of children)
S23 : Do not breathe vapour
S24 : Avoid contact with skin
S61 : Avoid release to the environment. Refer to special
instructions/safety data sheets.
S(62) : (If swallowed, do not induce vomiting: seek medical
advice immediately and show this container or label)
Printing date : 10-2006 8/8
SPLICE WASH SW-100
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered as a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
WEL : Workplace Exposure Limits - United Kingdom
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
TRK : Technische Richtkonzentrationen - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d鈥橢xposition - France
VLE : Valeurs limites d鈥橢xposition 脿 court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC
I : Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
R : Respirable fraction = A: Alveoleng盲ngiger Aerosolanteil/Alveolar dust
C : Ceiling limit
a: aerosol r: rook/Rauch (fume)
d: damp (vapour) st: stof/Staub (dust)
du: dust ve: vezel (fibre)
fa: Faser (fibre) va: vapour
fi: fibre om: oil mist
fu: fume on: olienevel/脰lnebel (oil mist)
p: poussi猫re (dust) part: particles
Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands
Full text of any R-phrases referred to under heading 2:
R12 : Extremely flammable
R38 : Irritating to skin
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
R65 : Harmful: may cause lung damage if swallowed
R66 : Repeated exposure may cause skin dryness or cracking
R67 : Vapours may cause drowsiness and dizziness
Printing date : 10-2006 9/9
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