SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
WATER-BLOCK S-20
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Synonyms: none
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance or the preparation:
Construction: sealing compound
1.3 Company/undertaking identification:
Firestone Building Products
Ikaroslaan 75
B-1930 Zaventem
Tel. : +32 2 711 44 50
Fax : +32 2 721 27 18
Email: info@fbpe.be
1.4 Telephone number for emergency:
+32 70 245 245
Poison Centre
p/a Militair Hospitaal Koningin Astrid, Bruynstraat, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
heptane 142-82-5 14 F;Xn;N 11-38-50/53-65-67
(1)
205-563-8
limestone 1317-65-3 >3 - - (1)
215-279-6
kaolin 1332-58-7 >3 - - (1)
310-127-6
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Highly flammable
- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with water
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Clean with alcohol
- Wash with water and soap
Printing date : 02-2006 1/1
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
? +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 12-01-2006 Revision date :
Reference number : BIG\43102GB Revision number : 000
Reason for revision :
WATER-BLOCK S-20
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Immediately give lots of water to drink
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Water spray
- Polyvalent foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- Solid water jet ineffective as extinguishing medium
5.3 Special exposure hazards:
- Gas/vapour spreads at floor level: ignition hazard
- Gas/vapour flammable with air within explosion limits
- Upon combustion CO and CO2 are formed
5.4 Instructions:
- If exposed to fire cool the closed containers by spraying with water
- Take account of environmentally hazardous firefighting water
- Use firefighting water moderately and contain it
5.5 Special protective equipment for firefighters:
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain leaking substance
- Dam up the solid spill
- Try to reduce evaporation
6.3 Methods for cleaning up:
- Scoop solid spill into closing containers
- Carefully collect the spill/leftovers
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
- Insufficient ventilation:
- Avoid prolonged and repeated contact with skin
- Use spark-/explosionproof appliances and lighting system
- Take precautions against electrostatic charges
- Do not discharge the waste into the drain
7.2 Storage:
- Keep container tightly closed
- Store at room temperature
- Keep out of direct sunlight
- Store in a dry area
- Keep away from: heat sources, ignition sources, acids, bases, oxidizing
agents
Printing date : 02-2006 2/2
WATER-BLOCK S-20
Storage temperature : 15/25 掳C
Quantity limits : N.D. kg
Storage life : 365 days
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
heptane
mg/m3
TLV-TWA : 400 ppm
mg/m3
TLV-STEL : 500 ppm
mg/m3
OES-LTEL :- 500 ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : 2100 500 ppm
3
MAC-TGG 8 h : 1200 mg/m
3
MAC-TGG 15 min. : 1600 mg/m
mg/m3
VME-8 h : 2045 500 ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 1664 400 ppm
mg/m3
GWK-15 min. : 2085 500 ppm
mg/m3
Momentary value : ppm
mg/m3
EC : 2085 500 ppm
mg/m3
EC-STEL :- - ppm
limestone
mg/m3
TLV-TWA : (10) ppm
mg/m3
TLV-STEL :- ppm
mg/m3
OES-LTEL : 4 R/10 I - ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : ppm
3
MAC-TGG 8 h : mg/m
3
MAC-TGG 15 min. : mg/m
mg/m3
VME-8 h : 10 - ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 10 - ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
Printing date : 02-2006 3/3
WATER-BLOCK S-20
kaolin
mg/m3
TLV-TWA : 2R ppm
mg/m3
TLV-STEL :- ppm
mg/m3
OES-LTEL : 2R - ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : ppm
mg/m3
MAC-TGG 8 h : 10
mg/m3
MAC-TGG 15 min. :
mg/m3
VME-8 h : 10 - ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 2R - ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
Sampling methods:
- n-Heptane (Hydrocarbons, BP 26 to 126 C) NIOSH 1500
- n-Heptane OSHA 7
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- Gas mask with filter type A
- Insufficient ventilation: wear respiratory protection
8.3.2 hand protection:
- Gloves
Suitable materials: Neoprene
Nitrile rubber
PVA
- Breakthrough time: N.D.
8.3.3 eye protection:
- Protective goggles
8.3.4 skin protection:
- Protective clothing
Suitable materials: Neoprene
Nitrile rubber
PVA
Printing date : 02-2006 4/4
WATER-BLOCK S-20
9. Physical and chemical properties
9.1 General information:
Appearance (at 20掳C) : Paste
Odour : Mild
Colour : Grey
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : 93 掳C
Flashpoint : -10 掳C
Explosion limits : 1.0/7.0 vol% ( 掳C)
Vapour pressure (at 20掳C) : 59 hPa
Vapour pressure (at 50掳C) : N.D. hPa
Relative density (at 20掳C) : 1.3
Water solubility : Insoluble
Soluble in : N.D.
Relative vapour density : 3.4
Viscosity (at 26掳C) : 1600 Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 掳C
Auto-ignition point : N.D. 掳C
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, ignition sources, acids, bases, oxidizing
agents
10.3 Hazardous decomposition products:
- Upon combustion CO and CO2 are formed
11. Toxicological information
11.1 Acute toxicity:
LD50 oral rat : N.D. mg/kg
LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
Printing date : 02-2006 5/5
WATER-BLOCK S-20
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : A4 (kaolin)
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : - (heptane)
IARC classification : not listed
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms:
- AFTER INHALATION
- EXPOSURE TO HIGH CONCENTRATIONS:
- CNS depression
- Dizziness
- Headache
- Nausea
- Narcosis
- Disturbances of consciousness
- AFTER SKIN CONTACT
- Slight irritation
- ON CONTINUOUS EXPOSURE/CONTACT:
- Dry skin
- Cracking of the skin
- AFTER EYE CONTACT
- Slight irritation
11.5 Chronic effects:
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
- Not classified as toxic to reproduction (EC)
- ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
- Enlargement/affection of the liver
- Affection of the renal tissue
- Impairment of the nervous system
Printing date : 02-2006 6/6
WATER-BLOCK S-20
12. Ecological information
12.1 Ecotoxicity:
heptane:
- LC50 (96 h) : 375 mg/l (TILAPIA MOSAMBICA)
- EC50 (48 h) : 0.2 mg/l (CHAETOGAMMARUS MARINUS)
- EC50 (8 h) : 1.5 mg/l (ALGAE)
12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
- Insoluble in water
- Substance sinks in water
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : N.D. % ThOD
- water : - No data available
- soil : T 陆: N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK :2 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergef盲hrdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 08 04 09* (waste adhesives and sealants containing organic
solvents or other dangerous substances)
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Recycle/reuse
- Allow waste to solidify
- Do not discharge into the sewer
- Do not discharge into surface water
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 02-2006 7/7
WATER-BLOCK S-20
14. Transport information
33
1133
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 1133
CLASS :3
SUB RISKS :-
PACKING : III
PROPER SHIPPING NAME :
UN 1133, Adhesives, Special provision 640H
14.2 ADR (transport by road)
CLASS : 3
PACKING : III
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.3 RID (transport by rail)
CLASS : 3
PACKING : III
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.4 ADNR (transport by inland waterways)
CLASS : 3
PACKING : III
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.5 IMDG (maritime transport)
CLASS : 3
SUB RISKS : -
PACKING : III
MFAG : -
EMS : F-E, S-D
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 3
SUB RISKS : -
PACKING : III
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 309/Y309
PACKING INSTRUCTIONS CARGO AIRCRAFT : 310
14.7 Special precautions in connection with : Transport in tanks: not
transport applicable Viscous liquid with
a flash point lower than 23 C,
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- 鈥楿N 1133'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'
Printing date : 02-2006 8/8
WATER-BLOCK S-20
15. Regulatory information
Classification according to directives 67/548/EEC and 1999/45/EC
Highly flammable Dangerous for the
environment
R11 : Highly flammable
R51/53 : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
S(02) : (Keep out of reach of children)
S09 : Keep container in a well-ventilated place
S16 : Keep away from sources of ignition - No smoking
S(46) : (If swallowed, seek medical advice immediately and show
this container or label)
S61 : Avoid release to the environment. Refer to special
instructions/safety data sheets.
Printing date : 02-2006 9/9
WATER-BLOCK S-20
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered as a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
OES : Occupational Exposure Standards - United Kingdom
MEL : Maximum Exposure Limits - United Kingdom
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
TRK : Technische Richtkonzentrationen - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d鈥橢xposition - France
VLE : Valeurs limites d鈥橢xposition 脿 court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC
I : Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
R : Respirable fraction = A: Alveoleng盲ngiger Aerosolanteil/Alveolar dust
C : Ceiling limit
a: aerosol r: rook/Rauch (fume)
d: damp (vapour) st: stof/Staub (dust)
du: dust ve: vezel (fibre)
fa: Faser (fibre) va: vapour
fi: fibre om: oil mist
fu: fume on: olienevel/脰lnebel (oil mist)
p: poussi猫re (dust) part: particles
Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands
Full text of any R-phrases referred to under heading 2:
R11 : Highly flammable
R38 : Irritating to skin
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
R65 : Harmful: may cause lung damage if swallowed
R67 : Vapours may cause drowsiness and dizziness
Printing date : 02-2006 10/10
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