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MSDS Material Safety Data Sheet
CAS

8003-34-7
51-03-6
112926-00-8
67-64-1
64741-66-8
75-37-6
811-97-2

File Name: fluorideaction_org---1112-tetrafl.tri-die.asp
                                         MATERIAL SAFETY DATA SHEET
WHITMIRE MICRO-GEN (800) 777-8570 (8:00 A.M. to 4:30 P.M. CST)
Prescription Treatment庐 brand
RESEARCH LABORATORIES, INC. EMERGENCY PHONE NUMBERS:
TRI-DIE庐
3568 TREE COURT IND. BLVD. MEDICAL: (800) 225-3320 PROSAR
ST. LOUIS, MO 63122 TRANSPORTATION: (800) 424-9300 CHEMTREC
Pressurized Silica + Pyrethrin Dust
EFFECTIVE DATE: OCTOBER 12, 1998 EPA REG. NO.: 499-385
Formula 1

SECTION 1: HAZARDOUS INGREDIENTS SECTION 6: SPILL OR LEAK PROCEDURES
ACGIH ACGIH OSHA Steps to be taken in case material is released or spilled: If container begins to leak
Active Ingredients: TLV/TWA STEL PEL (through puncture, etc.), allow it to discharge completely in well ventilated area, then dispose
Pyrethrins: 0.6% (CAS #8003-34-7) 5mg/m3 of in safe place. In case of spillage on skin, wash thoroughly with plenty of soap and water.
10mg/m3 NE
Piperonyl Butoxide, Technical: 4.8% Emergency Telephone Number of Chemtrec: (800) 424-9300
NE NE NE
(CAS #51-03-6) (for transportation spills)
Amorphous Silica Dioxide: 8.0% Waste Disposal Method: Do not contaminate water, food or feed by disposal. Pesticide
10mg/m3 NE 6mg/m3
(CAS #112926-00-8) Disposal: Wastes resulting from the use of this product may be disposed of on site or at an
Solvents & Propellants: 86.6% approved waste disposal facility. Container Disposal: This container may be recycled in the few
Acetone: (CAS #67-64-1) but growing number of communities where steel aerosol can recycling is available. Before
750ppm 1,000ppm 750ppm
Isoparaffinic Hydrocarbon: offering for recycling, empty the can by using the product according to the label. (DO NOT
NE NE 400ppm
(CAS #64741-66-8) PUNCTURE!). If recycling is not available, wrap the container and discard in the trash.
(Exxon)
Difluoroethane: (CAS #75-37-6) In case of spillage, this product is subject to reporting requirements of the Comprehensive
1,000ppm NE NE
1,1,1,2-Tetrafluoroethane: (CAS #811-97-2) Environmental Response, Compensation, and Liability Act (CERCLA).
NE NE NE
All components of this product are listed or excluded from listing on the US Toxic Substances
Control Act (TSCA) Chemical Substance Inventory.
SECTION 7: SPECIAL PROTECTION INFORMATION
SECTION 2: PHYSICAL DATA Respiratory Protection: None required if applied according to label directions. When used in
confined areas or when prolonged exposure to spray mist occurs, wear a pesticide dust
Boiling Point: NA Evaporation Rate: NA
respirator approved by the Mining Enforcement and Safety Administration (formerly the U.S.
Specific Gravity (H20 = 1): 7.2 lbs./gal. @ 20oC Solubility in Water: Slight.
Bureau of Mines) and by the National Institute of Occupational Safety and Health under the
Vapor Pressure in Aerosol Container: Appearance and Odor: Sprays as tan
provisions of 30 CFR Part II.
70 psig @ 70oF powder with characteristic pyrethrin odor.
Ventilation:
Percent Volatile: ~84.2
Local Exhaust: None required. Mechanical: None required.
Vapor Density: NA
Special: None required. Other: Provide adequate ventilation of treatment area.
Protective Gloves: None required.
SECTION 3: FIRE AND EXPLOSION HAZARD DATA Eye Protection: Goggles, face shield or glasses.
Other Protective Equipment: None required.
Flashpoint: >18聰 (CSMA Flame Projection Test)
Flammable Limits: NA
SECTION 8: SPECIAL PRECAUTIONS
NFPA 30B Flammability: Level 2 Aerosol
Extinguishing Media: CO2; Dry Chemical; Foam
Precautions to be taken in handling and storage: Hazards to Humans and Domestic Animals:
Special Firefighting Procedures: None required.
WARNING - Causes skin irritation. Do not get on skin or on clothing. Wear protective eyewear
Unusual Fire and Explosion Hazards: Contents under pressure. Exposure to temperatures
(goggles, face shield or glasses). Causes substantial but temporary eye injury. Do not get in
above 130oF may cause bursting.
eyes, on skin or on clothing. Harmful if absorbed through skin. Harmful if inhaled. Avoid breath-
ing spray dust. Wash thoroughly with soap and water after handling. Remove contaminated
SECTION 4: HEALTH HAZARD DATA clothing and wash before reuse. Prolonged or frequently repeated skin contact may cause aller-
gic reactions in some individuals. In hospitals, remove patients prior to treatment. Ventilate area
Threshold Limit Value: NE
for two hours prior to returning patients. Environmental Hazards: This product is toxic to fish,
Routes of Entry:
birds and other wildlife. Do not apply directly to water. Apply this product only as specified on its
Inhalation? Skin? Ingestion?
label. Do not contaminate water by cleaning of equipment or disposal of wastes. Physical or
Secondary Primary Tertiary
Chemical Hazards: Flammable. Contents under pressure. Keep away from heat, sparks and open
Health Hazard (Acute and Chronic) - Signs and Symptoms of Exposure:
flame. Do not puncture or incinerate container. Exposure to temperatures above 130 oF may
Eye: Product is an eye irritant.
cause bursting. Storage: Do not contaminate water, food or feed by storage. Store in a cool dry
Skin: Prolonged exposure may cause skin irritation. Acute dermal LD50 > 2,000mg/kg
place away from heat or open flame.
(rabbits).
Ingestion & Inhalation: Unlikely due to the product being pressurized and producing particles
SECTION 9: HEALTH RATING INFORMATION (NFPA)
large enough not to be respirable. A few cases of extrinsic asthma from pyrethrin mixtures
have been reported. Prolonged exposure may cause drying of nose and throat. Acute oral LD50
Health - 1 Flammability - 1 Reactivity - 1
> 5,000 mg/kg (rats). Acute inhalation LC50 > 4.78mg/l (rats).
Carcinogenicity:
SECTION 10: SARA TITLE III/SEC. 313 SUPPLIER NOTIFICATION
NTP? IARC Monograph? OSHA Regulated?
No No No This product contains the following toxic chemicals subject to the reporting requirements of
Emergency and First Aid Procedures: Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40
If in Eyes: Flush eyes with plenty of water. Get medical attention. CFR 372:
If Swallowed: Call a physician or poison control center immediately. Gastric lavage may be CAS# Chemical Name % by weight
indicated if material was taken internally. DO NOT INDUCE VOMITING. Vomiting may cause 51-03-6 Piperonyl Butoxide 4.8
aspiration pneumonia.
If Inhaled: Remove victim to fresh air. Apply artificial respiration if indicated. Get medical
SECTION 11: DOT SHIPPING INFORMATION
attention.
If on Skin: Remove contaminated clothing and wash affected areas with plenty of soap and Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D
water. Get medical attention.
Medical Conditions Generally Aggravated by Exposure: None known.



SECTION 5: REACTIVITY DATA Product Code: 02-0239
NA - Not Applicable
Prepared by: Dana M. Thomas
NE - Not Established
Stability: Indefinite when used according to label directions.
PEL - Permissible Exposure Limit
Conditions to Avoid: Do not spray into open flame or onto very hot surfaces.
ACL - Acceptable Ceiling Level
Hazardous Decomposition Products: Thermal decomposition in open flame may result in
MPC - Maximum Peak Concentration
halogen acids.
Hazardous Polymerization: Will not occur.



P/N 19-0720
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