Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
Material Safety Data Sheet
1. Company and Product Identification
TYTANTM GUTTER & SEAM SEAL
Product type:
Silicone Sealant
Product description:
National Fire Protection Association (NFPA) Profile
Health: 2
Flammability: 1
Instability/Reactivity: 0
SELENA USA, Inc.
Manufacturer:
21715 Beck Drive,
Elkhart, IN 46516
USA
(574) -523-0400; (877)-735-3627(toll free)
Phone number:
CHEMTREC 1-(800) 424-9300
Emergency phone number:
www.SelenaUSA.com
Website:
2. Hazards Identification
The potential effects of overexposure listed below are based on actual data, results of studies
performed upon similar compositions, component data and/or expert review of the product. For
toxicology information, refer to section 11.
Potential health effects
Acute Effects:
Direct contact may cause moderate irritation.
Eye:
May cause moderate irritation.
Skin:
Irritates respiratory passages very slightly. Vapor overexposure may cause
Inhalation:
drowsiness.
Low ingestion hazard in normal use.
Oral:
Prolonged/Repeated Exposure Effects:
Overexposure may injure internally if absorbed.
Skin:
Overexposure by inhalation may injure the following organ(s): blood, liver.
Inhalation:
Repeated ingestion or swallowing large amounts may injure internally.
Oral:
Signs and Symptoms of Overexposure: Not known applicable information.
Medical Conditions Aggravated by Exposure: Not known applicable information.
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
3. Composition/ Information on Ingredients
CAS Number Wt [%] Component name
96-29-7 < 0.5 Methyl ethyl ketoxime
22984-54-9 < 3.0 Methyl tri(ethylmethylketoxime)silane
1760-24-3 < 2.0 Aminoethylaminopropyltrimethoxysilane
4. First Aid Measures
Action
Immediately flush with water for 15 minutes. Get medical attention.
Eye:
Remove from skin immediately with paper towel and flush with water or water and
Skin:
soap for 15 minutes. Get medical attention if irritation or other ill effects develop or
persist.
Remove to fresh air. Get medical attention if ill effects persist.
Inhalation:
Get medical attention.
Oral:
Treat according to person鈥檚 condition and specifics of exposure.
Caution:
5. Fire-Fighting Measures
Fire fighting measures: Self-contained breathing apparatus and protective clothing should be worn
in fighting large fires involving chemicals. Determine the need to evacuate
or isolate the area according to your local emergency plan. Use water
spray to keep fire exposed containers cool.
Respective
On large fires use dry chemical, foam or water spray. On small fires use
extinguishing media:
carbon dioxide (CO2), dry chemical or water spray. Water can be used to
cool fire exposed containers.
Not applicable.
Flash point:
Autoignition
Not applicable.
temperature:
Flammability limits in
Not applicable.
air:
None
Usual fire hazards:
Hazardous decomposition products:
Thermal breakdown of this product during fire or very high heat conditions may evolve the following
hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon
compounds. Nitrogen oxides.
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
6. Accidental Release Measures
Containment/ Observe all personal protection equipment recommendations described in Sections 5
and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as
Clean up:
appropriate since spilled materials, even in small quantities, may present a slip
hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of
saturated absorbent or cleaning materials appropriately, since spontaneous heating
may occur. Local, state and federal laws and regulations may apply to releases and
disposal of this material, as well as those materials and items employed in the
cleanup of releases. You will need to determine which federal, state and local laws
and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements
See section 8 for Personal Protective Equipment for Spills. For additional
Caution:
information call the numbers provided in section 1.
7. Handling and Storage
Use with adequate ventilation. Product evolves methyl ethyl ketoxime (MEKO) when
Handling:
exposed to water or humid air. Provide ventilation during use to control methyl ethyl
ketoxime (MEKO) within exposure guidelines or use respiratory protection. Traces of
benzene (carcinogen) may form if heated in air above 300oF. Provide ventilation to
control vapor exposure within inhalation guidelines when handling at elevated
temperatures. Review the OSHA benzene regulation for detailed information on safe
handling requirements. Avoid eye contact. Avoid skin contact. Do not take internally.
Avoid breathing vapor, mist, dust or fumes. Keep container closed. Keep away from
children.
Use reasonable care and store away from oxidizing materials. Keep container closed
Storage:
and store away from water or moisture protecting from freezing in the temperature
not higher than 86oF
8. Exposure Control / Personal Protection
Ingredients name CAS Number Exposure limits
Methyl tri(ethylmethylketoximo)silane 22984-54-9 See MEKO comments
Aminoethylaminopropyltrimethoxysilane 1760-24-3 See methyl alcohol comments
Methyl ethyl ketoxime is formed upon contact with water or humid air. Provide adequate ventilation
to control exposures within the following exposure guidelines:
Vendor guide TWA: 3ppm; STEL: 10ppm; AIHA WEEL TWA: 10ppm.
Methyl alcohol forms on contact with water and humid air. Provide adequate ventilation to control
exposures: OSHA PEL: TWA: 200ppm; ACGIH TLV-skin: TWA 200ppm; STEL 250ppm.
Engineering measures:
Local ventilation: recommended.
General ventilation: recommended.
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
Personal protective equipment for usual handling:
Use proper protection 鈥? at least safety glasses.
Eyes:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be
Skin:
removed as soon as practical and thoroughly cleaned before reuse. Chemical
protective gloves are recommended.
Use protective gloves made from: Butyl Rubber, Neoprene Rubber, Nitrile
Hands:
Rubber.
Use respiratory protection unless adequate local exhaust ventilation is provided or
Inhalation:
exposure assessment demonstrates that exposures are within recommended
exposure guidelines.
Respiratory protection is not needed under ambient conditions. If
Suitable
vapor/mist/dust/fumes are generated when material is heated or handled, the
respirator:
following is advised. General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Respiratory protection
should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use
NIOSH/MSHA approved respirators.
Personal protective equipment for spills
Use full face respirator.
Eyes:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be
Skin:
removed as soon as practical and thoroughly cleaned before reuse.
Chemical protective gloves are recommended.
Hands:
Respiratory protection recommended. Follow OSHA Respirator Regulations (29
Inhalation:
CFR 1910.134) and use NIOSH/MHSA approved respirators. Protection provided
by air purifying respirators against exposure to any hazardous chemical is limited.
Use a positive pressure air supplied respirator if there is any potential for
uncontrolled release, exposure levels are unknown, or any other circumstance
where air purifying respirators may not provide adequate protection.
Precautionary Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust or
fumes. Keep container closed. Do not take internally. Use reasonable care.
measures:
Product evolves methyl ethyl ketoxime (MEKO) when exposed to water or humid
Comments:
air. Provide ventilation during use to control methyl ethyl ketoxime (MEKO)
within exposure guidelines or use respiratory protection. Traces of benzene
(carcinogen) may form if heated in air above 300oF. Provide ventilation to control
vapor exposure within inhalation guidelines when handling at elevated
temperatures. Review the OSHA benzene regulation for detailed information on
safe handling requirements.
Note: These precautions are for room temperature handling. Use at elevated temperature or
aerosol/spray applications may require added precautions
9. Physical and Chemical Properties
Paste
Physical state:
WHITE
Color:
Some odor
Odor:
Not determined.
Freezing/melting point:
Not determined.
Boiling point temperature:
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
Vapor Pressure @ 25oC 0,1 kPa
Methyl ethyl ketoxime
(MEKO) vapor density against
3
the air:
Not soluble.
Solubility in water:
Not determined.
PH:
Not determined.
Volatile content:
1.00 g/cm3 at 25oC
Specific gravity:
>392oF
Decomposition temperature:
None
Other information:
The above information is not intended for use in preparing
Note:
products specifications.
10. Stability and Reactivity
Stable, if applied according to guidelines.
Chemical stability:
Upon contact with humidity, polymerization occurs. During
Hazardous polymerization:
polymerization, methyl ethyl ketoxime (MEKO) occurs.
None.
Conditions to avoid:
Oxidizing material can cause a reaction. Water, moisture, or
Materials to avoid:
humid air can cause hazardous vapors to form as described in
Section 8
11. Toxicological Information
Component toxicology information:
Contains methyl ethyl ketoxime (MEKO). Male rodents exposed to MEKO vapor throughout their
lifetime developed liver cancer. Additional testing is planned by the MEKO supplier to determine
any relevance to humans. Until more data is known, exposure levels should be maintained as low as
achievable.
Methyl Ethyl Ketoxime (MEKO) is formed upon contact with water or humid air. Male rodents
exposed to MEKO vapor throughout their lifetime developed liver cancer. Additional testing is
planned by the MEKO supplier to determine any relevance to humans. Until more data is known,
exposure levels should be maintained as low as achievable.
Special hazard information on components:
Component name CAS no. Wt %
Methyl ethyl ketoxime 96-29-7 < 0.5 Possible skin sensitizer
Methyl tri(methylethylketoximo) silane 22984-54-9 < 3.0 Possible skin sensitizer
Aminoethylaminopropyltrimethoxysilane 1760-24-3 < 2.0 Possible skin sensitizer
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
12. Ecological Information
Environmental Fate and Distribution
Complete information is not yet available. Does not biodegrade. Do not dispose to sewage system,
surface and ground waters. Product can be easily separated from water through filtration.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50) High Medium Low
Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100
Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34,
1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed
above. Please read the other information presented in the section concerning the overall ecological
safety of this material.
13. Disposal Consideration
RCRA Hazard Class (40 CFR 261)
When discarding this material, as received, is it not classified as a hazardous waste. State or local
laws may impose additional regulatory requirements regarding disposal.
Call the number provided in section 1, if additional information is required.
14. Transport Information
DOT Road Shipment Information (49 CFR 172.101)
not required
Ocean Shipment (IMDG)
not required
Air Shipment (IATA)
not required
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
15. Regulatory Information
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR
1910.1200.
TSCA Status: All chemical substances in this material are included on or exempted from listing on
the TSCA Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings:
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: Yes
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Regulatory VOC: 1.8 g/l
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the
Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause
cancer, birth defects or other reproductive harm.
None known.
Massachusetts
CAS Number Wt % Component Name
7631-86-9 3.0 梅 9.0 Silica, amorphous
13463-67-7 <= 2.0 Titanium Dioxide
New Jersey
CAS Number Wt % Component Name
70131-67-8 < 60.0 Polydimethylsiloxane, hydroxyl-terminated
7631-86-9 3.0 梅 9.0 Silica, amorphous
22984-54-9 < 3.0 Methyl tri(methylethylketoximo)silane
13463-67-7 <= 2.0 Titanium Dioxide
Pennsylvania
CAS Number Wt % Component Name
70131-67-8 < 60.0 Polydimethylsiloxane, hydroxyl-terminated
7631-86-9 3.0 梅 9.0 Silica, amorphous
22984-54-9 < 3.0 Methyl tri(methylethylketoximo)silane
13463-67-7 <= 2.0 Titanium Dioxide
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Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08
TYTAN鈩? GUTTER & SEAM SEAL
PRODUCT:
16. Other Information
All information, recommendation or advice contained in this document or given by Selena Co. SA or
any of its subsidiaries, affiliates or authorized representatives, whether written or oral, is given in
good faith, to the best of its knowledge and based on current procedure in effect. Each user of the
product shall convince himself, through all available sources (including finished product testing in its
appropriate environment) of the suitability of the product supplied for its own particular purpose.
Selena Co. SA, its subsidiaries and affiliates cannot be held responsible for any loss incurred through
incorrect or faulty use of the product. The Material Safety Data Sheet related excessively to the
described product. In case of applying it as a component of the other product, the MSDS is no more
valid.
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