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MSDS Material Safety Data Sheet
CAS

2007-11-2
2008-04-0

File Name: selenausa_com---ht3_msds.asp
                                                                      Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:

Material Safety Data Sheet

1. Company and Product Identification

TYTANTM HIGH TEMPERATURE RED SILICONE
Product type:
SEALANT

Silicone Elastomer
Product description:

National Fire Protection Association (NFPA) Profile
Health: 2
Flammability: 1
Instability/Reactivity: 0

SELENA USA, Inc.
Manufacturer:
21715 Beck Drive,
Elkhart, IN 46516
USA
(574)-523-0400; (877)-735-3627(toll free)
Phone number:

CHEMTREC +1 (800) 424-9300
Emergency phone number:

www.SelenaUSA.com
Website:



2. Hazards Identification

Potential health effects

Acute Effects:
Direct contact may cause moderate irritation.
Eye:
May cause moderate irritation.
Skin:
Material is not likely o present an inhalation hazard at ambient conditions.
Inhalation:
However, if material is heated or high vapor/aerosol concentrations are attained,
central nervous system depression may occur, which is characterized by
drowsiness, dizziness, confusion or loss of coordination.
Low ingestion hazard in normal use.
Oral:

Prolonged/Repeated Exposure Effects:
No known applicable information.
Skin:
No known applicable information.
Inhalation:
No known applicable information.
Oral:

Signs and Symptoms of Overexposure: Not known applicable information.

Medical Conditions Aggravated by Exposure: Not known applicable information.



Page 1/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:


3. OSHA Hazard Components

CAS Number Wt [%] Component name

1.0梅5.0 Ethyltriacetoxysilane
17689-77-9

1.0梅5.0 Methyltriacetoxysilane
4253-34-3

The above components are hazardous as defined in 29 CFR 1910.1200


4. First Aid Measures

Immediately flush with water for 15 minutes. Get medical attention.
Eye:
Remove from skin and wash thoroughly with soap and water or waterless cleanser.
Skin:
Get medical attention if irritation or other ill effects develop or persist.
Material is not likely to present an inhalation hazard at ambient conditions. If
Inhalation:
material is heated or vapor/mist/dust/fumes are generated, care should be taken to
prevent inhalation. In case of exposure to vapor/mist/dust/fumes, move to fresh air.
No first should be needed.
Oral:
Treat according to person鈥檚 condition and specifics of exposure.
Comments:



5. Fire-Fighting Measures

>212潞F />100潞C (Closed Cup)
Flash Point:

Autoignition
Not determined.
Temperature:

Flammability Limits in
Not determined.
Air:

On large fires use dry chemical, foam or water spray. On smallfires use
Extinguishing Media:
carbon dioxide (CO2), dry chemical or water spray. Water can be used to
cool fire exposed containers.

Fire Fighting Measure: Self-contained breathing apparatus and protective clothing should be worn
in fighting large fires involving chemicals. Determine the need to evacuate
or isolate the area according to our local emergency pln. Use water spray
to keep fire exposed containers cool.
None
Usual fire hazards:




Page 2/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:


6. Accidental Release Measures
Containment/ Observe all personal protection equipment recommendations described in Sections 5
and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as
Clean up:
appropriate since spilled materials, even in small quantities, may present a slip
hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of
saturated absorbent or cleaning materials appropriately, since spontaneous heating
may occur. Local, state and federal laws and regulations may apply to releases and
disposal of this material, as well as those materials and items employed in the
cleanup of releases. You will need to determine which federal, state and local laws
and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements
See section 8 for Personal Protective Equipment for Spills. For additional
Note:
information call the numbers provided in section 1.




7. Handling and Storage
Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to
Handling:
water or humid air. Provide ventilation during use to control HOAc within exposure
guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Do
not take internally. Avoid breathing vapor. Keep container closed.
Use reasonable care and store away from oxidizing materials. Keep container closed
Storage:
and store away from water or moisture.


8. Exposure Control / Personal Protection

Component exposure limits:


CAS Number Component Name Exposure Limits
17689-77-9 Ethyltriacetoxysilane See acetic acid comments
4253-34-3 Methyltriacetoxysilane See acetic acid comments

Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control
exposure within guidelines of OSHA PEL: TWA: 10ppm; ACGIH TLV: TWA 10ppm; STEL:
15ppm.

Engineering measures:
Local ventilation: recommended.
General ventilation: recommended.

Personal protective equipment for usual handling:
Use proper protection 鈥? safety glasses as a minimum.
Eyes:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be
Skin:
removed as soon as practical and thoroughly cleaned before reuse. Chemical
protective gloves are recommended.

Page 3/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:

Suitable
Butyl Rubber, Nitrile Rubber.
Gloves:
Use respiratory protection unless adequate local exhaust ventilation is provided or
Inhalation:
exposure assessment demonstrates that exposures are within recommended
exposure guidelines. IH personnel can assist in judging the adequacy of existing
engineering controls.
Respiratory protection is not needed under ambient conditions. If
Suitable
vapor/mist/dust/fumes are generated when material is heated or handled, the
respirator:
following is advised. General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where concentrations are
above recommended limits or are unknown, appropriate respiratory protection
should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use
NIOSH/MSHA approved respirators.

Personal protective equipment for spills
Use full face respirator.
Eyes:
Wash at mealtime and end of shift. Contaminated clothing and shoes should
Skin:
be removed as soon as practical and thoroughly cleaned before reuse.
Chemical protective gloves are recommended.
Inhalation/Suitable
Respiratory protection recommended. Follow OSHA Respirator Regulations
Respirator:
(29 CFR 1910.134) and use NIOSH/MHSA approved respirators. Protection
provided by air purifying respirators against exposure to any hazardous
chemical is limited. Use a positive pressure air supplied respirator if there is
any potential for uncontrolled release, exposure levels are unknown, or any
other circumstance where air purifying respirators may not provide adequate
protection.
Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep
Precautionary
container closed. Do not take internally. Use reasonable care.
measures:
Product evolves acetic acid (HOAc) when exposed to water or humid air.
Comments:
Provide ventilation during use to control HOAc within exposure guidelines or
use respiratory protection.
When heated to temperature above 150潞C (300潞F) in the presence of air,
product may form formaldehyde vapor. Physical and health hazard
information is readily available from Selena USA, Inc. and the Material
Safety Data Sheet.

Note: These precautions are for room temperature handling. Use at elevated temperature or
aerosol/spray applications may require added precautions




9. Physical and Chemical Properties

Paste
Physical form:
RED
Color:
Acetic acid odor
Odor:
1.007 g/cm3
Specific gravity@25oC:
Not determined
Viscosity:
Page 4/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:

Not determined
Freezing/Melting Point:
Not determined
Boiling Point:
Not determined
Vapor Pressure@25潞C:
Not determined
Vapor density:
Not determined
Solubility in Water:
Not determined
pH:
Not determined
Volatile Content:
>212掳F/>100掳C (Closed Cup)
Flash Point:

Note: The above information is not intended for use in preparing product specification.




10. Stability and Reactivity

Stable.
Chemical stability:
Hazardous polymerization will not occur.
Hazardous polymerization:
None.
Conditions to avoid:
Oxidizing material can cause a reaction. Water, moisture, or
Materials to avoid:
humid air can cause hazardous vapors to form as described in
Section 8.



11. Toxicological Information

Special hazard information on components:

No known applicable information.




Page 5/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:


12. Ecological Information

Environmental Fate and Distribution
Complete information is not yet available.

Environmental Effects
Complete information is not yet available.

Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.

Ecotoxicity Classification Criteria

Hazard Parameters (LC50 or EC50) High Medium Low
Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100
Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000

This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34,
1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed
above. Please read the other information presented in the section concerning the overall ecological
safety of this material.


13. Disposal Consideration

RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste?
No.
State or local laws may impose additional regulatory requirements regarding disposal.



14. Transport Information

DOT Road Shipment Information (49 CFR 172.101)
not required

Ocean Shipment (IMDG)
not required

Air Shipment (IATA)
not required




Page 6/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:


15. Regulatory Information
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR
1910.1200.
TSCA Status: All chemical substances in this material are included on or exempted from listing on
the TSCA Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings:
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.

Regulatory VOC: 30 g/l

Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the
Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause
cancer, birth defects or other reproductive harm.

None known.

Massachusetts

CAS Number Wt % Component Name

7631-86-9 7.0 梅 13.0 Silica, amorphous
1333-86-4 <= 2.0 Carbon black
13463-67-7 <= 1.8 Titanium dioxide
1309-37-1 <= 1.0 Iron oxide

New Jersey

CAS Number Wt % Component Name
70131-67-8 > 60.0 Dimethyl siloxane, hydroxyl-terminated
7631-86-9 7.0 梅 13.0 Silica, amorphous
64742-46-7 <= 6.9 Hydrotreated middle petroleum distillates
17689-77-9 1.0 梅 5.0 Ethyltriacetoxysilane
63148-2-9 1.0 梅 5.0 Polydimethylsiloxane
1333-86-4 <= 2.0 Carbon black
1309-37-1 <= 1.0 Iron oxide

Page 7/8
Material Safety Data Sheet
Issued: 2007-11-29
Revised: 2008-04-08




TYTAN鈩? HT3
PRODUCT:

147-14-8 <= 2.0 Tetrabenzo-5,10,15,20-diazaporphyrinephtalocyanine
(Pigment blue 15)

4253-34-3 1.0 梅 5.0 Methyltriacetoxysilane
13463-67-7 <= 1.8 Titanium dioxide
1309-37-1 <= 1.0 Iron oxide

Pennsylvania

CAS Number Wt % Component Name
70131-67-8 > 60.0 Dimethyl siloxane, hydroxyl-terminated
7631-86-9 7.0 梅 13.0 Silica, amorphous
64742-46-7 <= 6.9 Hydrotreated middle petroleum distillates
1333-86-4 <= 2.0 Carbon black
13463-67-7 <= 1.8 Titanium dioxide
1309-37-1 <= 1.0 Iron oxide




16. Other information

All information, recommendation or advice contained in this document or given by Selena Co. SA or
any of its subsidiaries, affiliates or authorized representatives, whether written or oral, is given in
good faith, to the best of its knowledge and based on current procedure in effect. Each user of the
product shall convince himself, through all available sources (including finished product testing in its
appropriate environment) of the suitability of the product supplied for its own particular purpose.
Selena Co. SA, its subsidiaries and affiliates cannot be held responsible for any loss incurred through
incorrect or faulty use of the product. The Material Safety Data Sheet related excessively to the
described product. In case of applying it as a component of the other product, the MSDS is no more
valid.




Page 8/8

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