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MSDS Material Safety Data Sheet
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File Name: 1448-92_busan_1024_6_2_2006_2_50_04_pm.asp
BUCKMAN LABORATORIES, INC.
MATERIAL SAFETY DATA SHEET

BUSAN 1024
Revision date: 3/2/2005
Phone 1-800-BUCKMAN
Buckman Laboratories, Inc.
1256 North McLean Boulevard 24 Hour Emergency Phone: (901) 767-2722
Memphis, TN 38108

SECTION 1 OSHA HAZARD CLASSIFICATIONS

Irritating to eyes.

SECTION 2 HAZARDOUS COMPONENTS

Chemical Name CAS Number % by Weight TLV
Formaldehyde 50-00-0 0.2 ACGIH (United States).
CEIL: 0.37 mg/m3
CEIL: 0.3 ppm
OSHA (United States).
TWA: 0.75 ppm
STEL: 2 ppm
Buckman Laboratories reports the component(s) listed above as known OSHA hazardous material(s) contained in this
product.

SECTION 3 FIRST AID INFORMATION

Eye Flush immediately with copious amounts of tap water or normal saline (minimum of 15
Exposure: minutes). Take exposed individual to a health care professional, preferably an ophthalmologist,
for further evaluation.
Skin Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and
Exposure: wash thoroughly before reuse. If irritation persists consult a health care professional.
Inhalation: If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If
individual experiences nausea, headache, dizziness, has difficulty in breathing or is cyanotic,
seek a health care professional immediately.
Ingestion: DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk, first. Irrigate
the esophagus and dilute stomach contents by slowly giving one (1) to two (2) glasses of water or
milk. Avoid giving alcohol or alcohol related products. In cases where the individual is semi-
comatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case of intentional
ingestion of the product seek medical assistance immediately; take individual to nearest medical
facility.




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SECTION 4 PRIMARY ROUTES OF EXPOSURE
1. Effects from Acute Exposure:
Eye Slightly hazardous in case of eye contact (irritant).
Exposure:

Skin Non-irritant for skin. Non-sensitizer for skin.
Exposure:

Inhalation: Slightly hazardous in case of inhalation. Effects will depend on concentration and length of
time of exposure.
Ingestion: Ingestion is not expected to be a primary route of exposure.

2. Effects from Chronic Exposure:
This product has tested negative in both animal and human sensitization tests. Birth defects are unlikely,
as animal tests on the active ingredient were negative.
SECTION 5 Toxicological Information
Acute Effects:
Acute Oral (LD50) = >5000 mg/kg Rat
Acute Dermal (LD50) = >2000 mg/kg Rabbit
Acute Inhalation (LC50) = >3.2 mg/l ( 4 hours) Rat
Irritant / Sensitization Effects:
Slightly hazardous in case of eye contact (irritant).
Non-irritant for skin. Non-sensitizer for skin.
Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time
of exposure.

Carcinogenic Potential:
Not tested by Buckman Laboratories. Contains a small amount of formaldehyde, which has been
proven to be a carcinogen.
Target Organs Effects:
May cause damage to the following organs: upper respiratory tract, skin, eyes.

Other Health Effects:
Inhalation toxicity was conducted under misting conditions. Normal use of this product under
non-misting conditions should not present an occupational hazard.
This product has tested negative in both animal and human sensitization tests.
Birth defects are unlikely, as animal tests on the active ingredient were negative.
SECTION 6 Environmental Toxicological Information

LC50 = 136 mg/l 48 hours Daphnia magna
LC50 = 337 mg/l 96 hours Bluegill sunfish.
LC50 = 624 mg/l 96 hours Rainbow trout.




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USA
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SECTION 7 Physical and Chemical Properties
Appearance .............................. Clear, colorless. liquid
Odor ........................................... Alcohol. (Slight.)
Density ...................................... 1.06 g/cm3 at 25掳C (77掳F)
Flash Point ............................... Closed cup: >100掳C (212掳F). (Pensky-Martens.)
Melting/Freezing Point .... Not available.
Boiling Point ............................ >100掳C (212掳F)
Solubility ................................... Soluble in cold water. Soluble in hot water. Insoluble in methanol. Insoluble in
diethyl ether. Insoluble in N-Octanol. Insoluble in acetone.
pH (Neat) .................................. 8.5 [Basic.]
pH (100 ppm in water) ........... 7.5
Vapor Pressure........................ Not available.
The product is much more soluble in water.
o/w Partition Coefficient .........
Not Tested.
Oxidizing/Reducing Properties .
Not available.
Viscosity ...................................
Not available.
Additional pH Information ......
NOTE: The physical data presented above are typical values and should not be construed as specifications.
SECTION 8 Fire and Explosion Information
Flammable Limits .................. Not available.
Extinguishing Media ............... Water fog, carbon dioxide, foam, dry chemical.
Special Firefighting Fire-fighters should wear positive pressure self-contained breathing apparatus
Procedures ...............................
(SCBA) and full turnout gear.
SECTION 9 Reactivity Information
Stability ...................................... Stable under normal conditions of use and storage.

Incompatibility .......................... Incompatible with primary amines.

Hazardous Decomposition
Products ....................................Exposure to strong oxidants or flame may generate oxides of carbon and nitrogen,
and/or hydrogen chloride. Contact with primary amines may generate ammonia,
methylamine, diemethylamine, and/or trimethylamine.
SECTION 10 Handling Precautions
Rubber gloves, protective eyewear, body protective clothing and shoes are recommended. Eye-wash fountains
in the work place are recommended. The handling precautions for this product are based on the
characteristics of the neat product unless otherwise specified.
SECTION 11 Satisfactory Materials of Construction

Polypropylene
Teflon.
PVC - rigid
Buna-N rubber
Viton
EPDM rubber

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PVC - flexible
Neoprene
Polyethylene - low density
Tygon
Silicone rubber
Stainless steels 304 and 316
Polyethylene - high density
Lexan
Butyl rubber
Polyethylene - crosslink
ABS (Plastic)
Morton test liner (108 T 44LV)
6/6 Nylon


SECTION 12 Spill, Leak, and Disposal Procedures

SPILL AND LEAK RESPONSE GUIDELINES:
Important: Before responding to a spill or leak of this product, review each section of this MSDS. Follow the recommendations
given in the Handling Precautions sections. Check the Fire and Explosion Data section to determine if the use of non-sparking tools
is merited. Insure that spilled or leaked product does not come into contact with materials listed as incompatible. If irritating
fumes are present, consider evacuation of affected areas.

Emergency Response Assistance: Emergency technical assistance is available at any time from Buckman Laboratories, Inc., by
calling (901) 767-2722. Collect calls are accepted.

Initially minimize area affected by the spill or leak. Block any potential routes to water systems (e.g., sewers, streams, lakes, etc.).
Based on the product's toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact on
contaminated environments (e.g. water systems, ground, air equipment, etc.). There are no methods available to completely
eliminate any toxicity this product may have on aquatic environments. Minimize adverse effects on these environments. Buckman
Laboratories, Inc. can be contacted for technical assistance. Determine if federal, state, and/or local release notification is
required (see Regulatory Information section of this MSDS). Recover as much of the pure product as possible into appropriate
containers. Later, determine if this recovered product can be used for its intended purpose. Address clean-up of contaminated
environments. Spill or leak residuals may have to be collected and disposed of. Clay, soil, or commercially available absorbents
may be used to recover any material that can not readily be recovered as pure product. Flushing residual material to an industrial
sewer, if present at the site of a spill or leak incident, may be acceptable if authorized approval is obtained. If product and/or
spill/leak residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible materials.

DISPOSAL GUIDELINES

Note: Follow federal, state, and local regulations governing the disposal of waste materials.

Neat Product: Contact your Buckman representative.

Contaminated Materials: Determine if waste containing this product can be handled by available industrial effluent system or
other on-site waste management unit. If off-site management is required, contact a company experienced in industrial waste
management.

Container Disposal: If assistance is needed, contact your Buckman sales representative.




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USA
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SECTION 13 Transportation and Shipping Information

DOT Shipping Information:
Not Regulated.
IMO/IMDG Shipping Information:
Not Regulated.
IATA Shipping Information:
Not Regulated.

Unless otherwise stated, the shipping information provided above applies only to non-bulk containers of this product. Proper shipping
name and general shipping information may vary depending on packaging and mode of shipment. All products shipped from Buckman
locations have been properly packaged and labeled according to appropriate hazardous materials shipping regulations. If any
alteration of packaging, product, or mode of transportation is further intended, different shipping information, including but not limited
to proper shipping name, RQ designation, and labeling may apply. For further information pertaining to the shipping requirements for
this product, contact Buckman's Transportation Department or DOT Coordinator.

SECTION 14 Regulatory Information

The following Regulations are known to apply to the use and disposal of this product. Additional Federal,
State and Local regulations may also be applicable.
SARA (Superfund Amendments and Reauthorization Act)
SARA 302 Extremely Hazardous Substances List ...
Formaldehyde
SARA 312 Hazard Category ...
Immediate (Acute) Health Hazard
SARA 313 Toxic Chemicals List ...
This product contains the following toxic chemical(s) subject to the reporting requirements of section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part
372 :
Formaldehyde
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act)
Formaldehyde ..... RQ = 100 lbs.
RCRA (Resource Conversation and Recovery Act) Listed Hazardous Waste
This product contains a small amount of formaldehyde, which is a listed RCRA Hazardous Waste.
CWA (Clean Water Act) Listed Substances
No components of this product are listed.
FDA ( Food and Drug Administration)
This product is not approved for food contact uses.
TSCA (Toxic Substances Control Act) Applicability
All components may not be listed on the TSCA Inventory. Registered pesticides are exempt from the
requirements of TSCA.
FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act)
This product is a registered pesticide. EPA Reg. No. 1448-92
HMIS/NPCA Rating ... Health Flammability Reactivity
1 1 1
NFPA Ratings ............. Health Flammability Reactivity
1 1 1
State Regulations

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Various State Right To Know Acts ...
Non-proprietary hazardous chemicals are listed in Section 2 of this MSDS. Should you require
further information on specific proprietary or inert ingredients please contact Buckman
Laboratories' Regulatory Affairs Department.

The information on this Material Safety Data Sheet reflects the latest information and data that we have on hazards, properties, and
handling of this product under the recommended conditions of use. Any use of this product or method of application which is not
described in the Data Sheet is the responsibility of the user. This Material Data Safety Sheet was prepared to comply with the OSHA
Hazard Communication regulations. While some components are claimed Trade Secret under OSHA Hazard Communication
regulations, all known OSHA hazards associated with the Trade Secret component(s), if contained in this product, are fully disclosed.

Buckman Laboratories, Inc. warrants that this product conforms to its chemical description and is reasonably fit for the purpose
referred to in the directions for use when used in accordance with the directions under normal conditions. Buyer assumes the risk of any
use contrary to such directions.

Seller makes no other warranty or representation of any kind, express or implied, concerning the product, including NO IMPLIED
WARRANTY OF MERCHANTABILITY OR FITNESS OF THE GOODS FOR ANY OTHER PARTICULAR PURPOSE. No such
warranties shall be implied by law and no agent of seller is authorized to alter this warranty in any way except in writing with a specific
reference to this warranty.

The exclusive remedy against seller shall be in a claim for damages not to exceed the purchase price of the product, without regard to
whether such a claim is based upon breach of warranty or tort.

Any controversy or claim arising out or relating to this contract, or breach thereof, shall be settle by arbitration in accordance with the
commercial arbitration rules of the American Arbitration Association, and judgement upon the rendered by the Arbitrator(s) may be
entered in any court having jurisdiction thereof.

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