MATERIAL SAFETY DATA SHEET DIAZINON AG600 WBC
FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL CHEMTREC - DAY OR NIGHT 1-800-424-9300
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FORMULATED FOR:
Loveland Products, Inc. 24-Hour Emergency Phone: 1-800-424-9300
P.O. Box 1286 鈥? Greeley, CO 80632-1286 Medical Emergencies: 1-800-301-7976
U.S. Coast Guard National Response Center: 1-800-424-8802
PRODUCT NAME: DIAZINON AG600 WATER-BASED CONCENTRATE INSECTICIDE
CHEMICAL NAME: Diazinon; (O-O-diethyl O- (2-isopropyl-6-methyl-4-pyrimidinyl) phosphorothioate)
CHEMICAL FAMILY: Organophosphate Insecticide
EPA REG. NO.: 66222-103-34704
MSDS Number: 66222103-04-LPI MSDS Revisions: New Date Of Issue: 09/03/04 Supersedes: New
2. HAZARDS IDENTIFICATION SUMMARY
KEEP OUT OF REACH OF CHILDREN 鈥? CAUTION 鈥? Harmful if swallowed, inhaled or absorbed through skin. Causes eye irritation. Avoid contact with
skin, eyes, or clothing. Avoid breathing vapor or spray mist. Avoid contamination of food and feed. Food utensils such as tablespoons and measuring cups
should not be used for food purposes after use in measuring pesticides. Keep out of reach of domestic animals. Do not use on humans, household pets or
livestock. Do not contaminate ornamental fishponds.
This product is an off-white liquid with slight sulfur-like odor.
Warning Statements:
NOTE TO PHYSICIAN: This product is an organophosphate (cholinesterase-inhibiting) insecticide. Atropine is antidotal and should be given in multiple
doses as necessary until the patient is atropinized. 2-PAM is also antidotal, but should be administered only in conjunction with Atropine. Monitor serum
and RBC cholinesterase. Morphine, theophylline, aminophylline, phenothiazines, reserpine, furosemide, or ethacrynic acid are contraindicated in
organophosphate poisonings. Administer intravenous fluids cautiously, if needed, to correct dehydration. Symptoms of cholinesterase inhibition can
include headache, dizziness, blurred vision, weakness, nausea, cramps, diarrhea, discomfort in the chest, nervousness, sweating, miosis, tearing,
salivation, pulmonary edema, uncontrollable twitches, convulsions, coma, and loss of reflexes and sphincter control.
3. COMPOSITION, INFORMATION ON INGREDIENTS
Chemical Ingredients: Percentage by Weight: CAS No. TLV (Units)
3
Diazinon 56.00 333-41-5 0.01 mg/m (Skin)
Inert Ingredients 44.00
This product is hazardous according to the OSHA Hazard Communication Standard (29 CFR 1910.1200)
4. FIRST AID MEASURES
If swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an
unconscious or convulsing person.
If in eyes: Hold eye open and rinse slowly and gently with water 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably
mouth-to-mouth. Call a poison control center or doctor for further treatment advice.
If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center
or doctor for treatment advice.
.
1-800-301-7976. Have the product container or label with you when calling a poison control
FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL:
center or doctor or going for treatment.
5. FIRE FIGHTING MEASURES
O O
FLASH POINT (掳F/Test Method): 220 F/104.5 C (PMCC)
FLAMMABLE LIMITS (LFL & UFL): None established
EXTINGUISHING MEDIA: This product is water-based; use medium appropriate to surrounding fire. Dry chemical, carbon dioxide,
foam, water spray or fog.
HAZARDOUS COMBUSTION PRODUCTS: Thermal decomposition products include, but are not limited to, various aliphatic organophosphates,
substituted pyrimidines, and hydrogen cyanide.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus with full protective clothing. Fight fire from upwind and keep
all non-essential personnel out of area.
UNUSUAL FIRE AND EXPLOSION HAZARDS: If water is used to fight fire or cool containers, dike to prevent runoff contamination of municipal
sewers and waterways.
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MATERIAL SAFETY DATA SHEET DIAZINON AG600 WBC
6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Wear chemical safety glasses with side shields or chemical goggles, rubber gloves, rubber boots, long-sleeved shirt, long pants, head covering, and a
NIOSH-approved pesticide respirator or air-supplied respirator.
For small spills, absorb with an absorbent material such as pet litter. Sweep up and place in an approved chemical container for proper disposal. Check
local, state and federal regulations for proper disposal. For large spills, contain liquid by diking the area, keep product out of water supplies. If possible use a
pump to pick up liquid, then use absorbent material to absorb any residual liquid. Place both in an approved container. Flush the area with a household
bleach and water mixture (1:1) and then absorb the liquid as described in small spills.
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.
7. HANDLING AND STORAGE
HANDLING: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide
gets inside. Then wash thoroughly and put on clean clothing. Remove PPE after handling this product. Wash the outside of
gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Do not use, pour, spill or store
near heat or open flame.
O O
STORAGE: If freezing occurs, place the product in a warm room (68 F/20 C or above) and allow to thaw. Roll or shake container
frequently until thawing is complete. Do not contaminate water, food or feed by storage or disposal.
Personal Protective Equipment: Mixers, loaders, applicators and other handlers using engineering controls must wear: long sleeved shirt and
long pants, shoes plus socks, chemical resistant gloves if mixing or loading, and chemical resistant apron if mixing or loading. Handlers performing
tasks, such as cleaning equipment or spill clean-up for which engineering controls are not feasible must wear: coveralls over long sleeved
shirts and long pants, chemical resistant gloves, chemical resistant footwear plus socks, chemical resistant apron if exposed to concentrate, and a
NIOSH-approved respirator with an organic vapor (OV) cartridge or canister with any R, P, or HE prefilter. Follow manufacturer鈥檚 instructions for cleaning
and maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. Discard
clothing and other absorbent material that鈥檚 have been drenched or heavily contaminated with this product鈥檚 concentrate. Do not reuse them.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets with requirements listed in the
Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE
requirements may be reduced or modified as specified in the WPS.
RESPIRATORY PROTECTION: Not normally required, if vapors or mists exceed acceptable levels, wear a NIOSH approved pesticide respirator.
EYE PROTECTION: Chemical goggles or shielded safety glasses.
SKIN PROTECTION: Wear protective clothing: long-sleeved shirts and pants, shoes with socks. Wear chemical-resistant gloves.
OSHA PEL 8 hr TWA ACGIH TLV-TWA
3
Diazinon not listed 0.01 mg/m (Skin)
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR: Off-white liquid with slight sulfur-like odor. SOLUBILITY: Slight
SPECIFIC GRAVITY (Water = 1): 1.07 g/ml BULK DENSITY: 8.93 lbs/gal. pH: 7-8 (1% solution)
o
VAPOR PRESSURE: <0.1 mm Hg @ 25 C BOILING POINT: Not established
PERCENT VOLATILE (by volume): > 30% EVAPORATION RATE: Not established
Note: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items.
10. STABILITY AND REACTIVITY
STABILITY: Stable CONDITIONS TO AVOID: Excessive heat and ignition sources.
INCOMPATIBILITY: Strong bases, acids, and oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition 鈥? aliphatic organophosphates, substituted pyrimidines, and hydrogen cyanide.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Oral LD50 (rat): 1600 mg/kg Acute Dermal LD50 (rabbit): > 2020 mg/kg
Eye Irritation (rabbit): Causes irritation Skin Irritation (rabbit): Non-irritating
Inhalation LC50 (rat): >2.5 mg/L (4 hr) Skin Sensitization (Guinea Pig): Not a sensitizer
Carcinogenic Potential: None listed in OSHA, NTP, IARC or ACGIH
12. ECOLOGICAL INFORMATION
Summary of Effects: Diazinon is highly toxic to birds, fish, and other wildlife. Avoid exposure to waterfowl. Keep out of lakes, streams, ponds, tidal
marches, and estuaries. Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high water mark.
Drift and runoff may be hazardous to aquatic organisms in neighboring areas. Shrimp and crab may be killed at application rates on the product label.
Do not apply this product where fish, shrimp, crab, and other aquatic life are important resources. Do not contaminate water by cleaning of equipment or
disposal of equipment wash waters. Highly toxic to bees exposed to direct treatment or to residues on blooming crops or weeds. Do not apply this
product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area.
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MATERIAL SAFETY DATA SHEET DIAZINON AG600 WBC
Eco-Acute Toxicity
96 HR LC50 48 HR LC50
Rainbow Trout 1.8 mg A.I./L Daphnia Magna 0.0011 mg A.I./L
Bluegill Sunfish 0.21 mg A.I./L
Bobwhite Oral LD50: 5.2 mg/kg Eco-Chronic Toxicity
Mallard Oral LD50: 1.44 mg/kg Diazinon: Fish (Fathead minnow) Early Life Stage MATC >0.092 and <0.17 mg/L
Bobwhite 8-day Dietary LC50: 235 ppm Invertebrate (Daphnia Magna) Life Cycle MATC >0.00017 and <0.00032 mg/L
Mallard 8-day Dietary LC50: 33 ppm A.I. Mallard Reproduction NOEC 10 ppm (ChE inhibition <5 ppm)
Bobwhite Reproduction NOEC 40 ppm (ChE inhibition < 10 ppm)
13. DISPOSAL CONSIDERATIONS
Do not reuse product container. Plastic: Triple rinse (or equivalent), then offer for recycling at an ACRC site (go to http://www.acrecycle.org/ for
locations) or by reconditioning, or puncture and dispose of in a sanitary landfill, or, incineration, or, if allowed by state and local authorities, by burning. If
burned, stay out of smoke. Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. Do
not contaminate water, food or feed by storage or disposal.
14. TRANSPORT INFORMATION
DOT Shipping Description: RQ ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, UN3082, III (DIAZINON) MARINE
POLLUTANT ERG GUIDE 171
U.S. Surface Freight Classification: INSECTICIDES, INSECT REPELLENTS, NOI, OTHER THAN POISON (NMFC 102120, CLASS: 60)
Consult appropriate ICAO/IATA and IMDG regulations for shipment requirements in the Air and Maritime shipping modes.
15. REGULATORY INFORMATION
NFPA & HMIS Hazard Ratings: NFPA HMIS
1 Health 0 Least 1 Health
1 Flammability 1 Slight 1 Flammability
0 Instability 2 Moderate 0 Reactivity
3 High H PPE
4 Severe
SARA Hazard Notification/Reporting
SARA Title III Hazard Category: Immediate __Y__ Fire __N__ Sudden Release of Pressure __N__
Delayed __Y __ Reactive __N__
Reportable Quantity (RQ) under U.S. CERCLA: Diazinon (CAS: 333-41-5): 1 pound
SARA, Title III, Section 313: Diazinon (CAS: 333-41-5) 56.0%
RCRA Waste Code: Not listed
CA Proposition 65: Not listed.
16. OTHER INFORMATION
MSDS STATUS: New
PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental/ Regulatory Services
This product is a RESTRICTED USE PESTICIDE due to Avian and Aquatic Toxicity
Although the information and recommendations set forth herein (hereinafter 鈥淚nformation鈥?) are presented in good faith and believed to be correct, Loveland
Products, Inc., the manufacturer or the seller makes no representations as to the completeness or accuracy thereof. Information is supplied upon the
condition that the persons receiving it will make their own determination as to its suitability for their purposes prior to use.
The product covered by this information sheet is furnished 鈥渁s is鈥? by Loveland Products, Inc., the manufacturer or the seller, and is subject only to the
warranties, if any, that appear on the product鈥檚 label or are otherwise expressly provided herein.
Except as expressly provided on the product鈥檚 label or otherwise provided herein, no warranties, guarantees, or representations of any kind, either express
or implied, or by usage of trade, statutory or otherwise, are made by Loveland Products, Inc., the manufacturer or the seller with regard to the product or
use of the product, including, but not limited to, merchantability, fitness for a particular purpose, use or eligibility of the product for any particular trade
usage.
Except as expressly stated herein, Loveland Products, Inc., the manufacturer or the seller makes no warranty of results to be obtained by use of the
product covered by this information. Buyer鈥檚 or user鈥檚 exclusive remedy, and the total liability of Loveland Products, Inc., the manufacturer or the seller,
shall be limited to damages not exceeding the cost of the product. No agent or employee of Loveland Products, Inc., the manufacturer or the seller is
authorized to amend the terms of this warranty disclaimer or the product鈥檚 label or to make a representation or recommendation different from or
inconsistent with the label of this product.
IN NO EVENT SHALL LOVELAND PRODUCTS, INC., THE MANUFACTURER OR THE SELLER BE LIABLE FOR CONSEQUENTIAL, SPECIAL OR
INDIRECT DAMAGES RESULTING FROM THE USE, HANDLING, APPLICATION, STORAGE OR DISPOSAL OF THIS PRODUCT OR FOR
DAMAGES IN THE NATURE OF PENALTIES AND THE BUYER AND USER WAIVE ANY RIGHT THEY MAY HAVE TO SUCH DAMAGES.
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