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MSDS Material Safety Data Sheet
CAS

74-88-4
76-06-2

File Name: 66330-43_midas_98_2_12_20_2007_1_50_48_pm.asp
                                              MATERIAL SAFETY DATA SHEET

MIDAS 98:2 Page 1 of 8

Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store, dispose
of or handle this product. Please make sure this information is given to them. It also contains information
to help you meet community right-to-know/emergency response reporting requirements under SARA Title
III and many other laws. If you resell this product, this MSDS must be given to the buyer or the information
contained herein must be incorporated in your MSDS.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: MIDAS 98:2
EPA REGISTRATION NUMBER(S): 66330-43
SYNONYM(S): TM-42501


COMPANY EMERGENCY TELEPHONE NUMBERS
Arysta LifeScience North America Corporation HEALTH EMERGENCY: SPILL EMERGENCY:
15401 Weston Parkway, Suite 150
1-866-303-6952, or 1-800-424-9300, or
Cary, NC 27513
1-651-632-8946 1-703-527-3887

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

Active Ingredient(s)/ CAS # Exposure Limits % %
Hazardous Inert Ingredient(s) Weight Volume

a
Methyl Iodide (Iodomethane) 74-88-4 97.80 NDA
TWA
b
OSHA PEL : 5 ppm
3
28 mg/m
c
ACGIH TLV : 2 ppm
3
12 mg/m
d
NIOSH REL : 2 ppm
3
10 mg/m

Chloropicrin 76-06-2 1.99 NDA
TWA
OSHA PEL: 0.1 ppm
3
0.7 mg/m
ACGIH TLV: 0.1 ppm
3
0.67 mg/m
NIOSH REL: 0.1 ppm
3
0.7 mg/m
e
DFG MAK : 0.1 ppm
3
0.68 mg/m
f
PEAK
g
DFG MAK: I
Other ingredients 0.21 NDA

Only the identities of the active ingredient(s) and any hazardous inert ingredients are listed. Specific information on
all of this product鈥檚 ingredients can be obtained by the treating medical professional or spill emergency responder for
the management of exposures, spills, or safety assessments.


EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 2 of 8

*Source: Guide to Occupational Exposure Values 2000, published by ACGIH
a
TWA: Time-weighted average exposure concentration for a conventional 8-hour (TLV, PEL) or up to a 10-hour
(REL) workday and a 40-hour workweek.
b
OSHA PEL: Occupational Safety and Health Administration Permissible Exposure Limits.
c
ACGIH TLV: American Conference of Governmental Industrial Hygienists, Inc., Threshold Limit Values.
d
NIOSH REL: National Institute for Occupational Safety and Health Recommended Exposure Limits.
e
DFG MAK: Federal Republic of Germany (DFG), Commission for the Investigation of Health Hazards of Chemical
Compounds in the Work Area 1999 Maximum Concentration Values in the Workplace (MAKs).
f
PEAK: Federal Republic of Germany (DFG), Commission for the Investigation of Health Hazards of Chemical
Compounds in the Work Area 1999 Maximum Concentration Values in the Workplace (MAKs) peak level.
g
Local irritants; peak level is 2 times MAK; maximum duration per shift is 5-min, momentary value; maximum
frequency per shift is 8. The monetary value is a level which the concentration should never exceed. It represents a
limit to be observed in work area technical planning; the analytical testing can then be carried out by use of sampling
procedures designed for recording average values.


SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

DANGER: - CORROSIVE
- CAUSES IRREVERSIBLE EYE DAMAGE AND SKINBURNS
- MAY BE FATAL IF SWALLOWED OR INHALED
- HARMFUL IF ABSORBED THROUGH SKIN
- DO NOT GET IN EYES, ON SKIN OR ON CLOTHING
- DO NOT BREATHE VAPOR
- PROLONGED SKIN CONTACT MAY CAUSE ALLERGIC REACTIONS

Acute Health Hazards
Eye Contact: Vapors can cause irritation. Splashes may cause severe irritation with permanent
eye damage.

Skin Contact: Prolonged contact can cause severe irritation or related adverse skin effects.

Inhalation: Inhalation of vapors can irritate the respiratory tract. Overexposure may produce
symptoms of vertigo, delirium and mental disturbances. Other symptoms may include slurred
speech, drowsiness, coughing, nausea and vomiting. Higher exposures can cause a build up of
fluid in the lungs, which can cause death.

Ingestion: Ingestion may damage the gastro-intestinal tract. Severe intoxication can occur with
symptoms of central nervous system depression. Coma, convulsions, and death may follow.

Chronic Health Hazards (Including Cancer): See Section 11.

SECTION 4: FIRST AID MEASURES

Eyes: Hold eye(s) open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses,
if present, after the first 5 minutes, then continue rinsing eye(s). Call a poison control center or doctor for
treatment advice.



EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 3 of 8

Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call
a poison control center or doctor for treatment advice.

Inhalation: Move person to fresh air. If person is not breathing call 9-1-1 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further
treatment advice.

Ingestion: Call a poison control center or doctor immediately for medical advice. Have person sip a glass
of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or
doctor. Never give anything by mouth to an unconscious person.

NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.
Symptoms of overexposure may include irritation to eyes, skin, and respiratory system, shortness of
breath, nausea, vomiting, dizziness, ataxia, slurred speech, drowsiness, blurred vision, staggering gait and
mental imbalance, with probable recovery after period of no exposure. Treatment is symptomatic.

SECTION 5: FIRE FIGHTING MEASURES

Flammable Limits in Air (% by volume):
NDA
Upper:
NDA
Lower:
NA
Flash Point:
NA
Method Used:
NDA
Autoignition Temperature:
NDA
LEL/UEL:
NFPA Hazard Classification:
3
Health:
1
Flammability:
0
Reactivity:
NDA
Other:
Dry chemical, foam, CO2 or water spray
Extinguishing Media:
In the event of a fire, wear full protective clothing and NIOSH-
Special Fire Fighting Procedures:
approved SCBA with full facepiece operated in the positive
pressure mode.
NDA
Unusual Fire/Explosion Hazards:
Hazardous Combustion Products: Fire may produce poisonous or irritating gases.

SECTION 6: ACCIDENTAL RELEASE MEASURES

EMERGENCY PHONE NUMBERS
Exposure Calls (PROSAR): 1-866-303-6952 or 1-651-632-8946 (International)
Spill Calls (CHEMTREC): 1-800-424-9300 or 1-703-527-3887

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8.
Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover
liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g.,
vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials,
such as sawdust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases
to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard
National Response Center is (800) 424-8802. Eliminate source of the spill. Wear protective clothing.
Ventilate area with explosion-proof apparatus. Avoid breathing vapor. Dike and contain the spill with
suitable absorbent (e.g. sand, silica). Transfer the liquid and the absorbent to separate containers for
recovery or disposal. Scrub contaminated surface with detergent solution.



EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 4 of 8

SECTION 7: HANDLING AND STORAGE

Keep in a tightly closed light-resistant container, stored in a cool, dry, ventilated area. Protect against
physical damage. Wear special protective equipment (See Section 8) for maintenance break-in or where
exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting
restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid
cross-contamination of street clothes. Wash hands before eating and do not eat, drink or smoke in
workplace. Containers of this material may be hazardous when empty since they retain product residues
(vapors, liquid); observe all warnings and precautions listed for the product. Avoid breathing vapor and
avoid contact with skin and eyes while handling. Wash all exposed skin with soap and water after
handling. Launder the protective clothing before reuse. It is a violation of federal law to use this product in
a manner inconsistent with its labeling. Read entire label. Use strictly in accordance with label
precautionary statements and directions. Read and observe all precautions on product label.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

AIR CONCENTRATION LEVEL: Air concentrations of chloropicrin are measured with direct reading

devices, such as Kitagawa tubes, certified for chloropicrin. Persons involved in the application of MIDAS
98:2 or in reentry into treated fields must wear an air-purifying respirator when required by the restrictions

given in the AGRICULTURAL USE REQUIREMENTS section of the MIDAS 98:2 label.

Respiratory/Ventilation Requirements: Avoid breathing vapor. Ventilate the work area. A system of
local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure
Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. If the exposure limit is
exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece SCBA.

Eye Protection: Do not get this material in your eyes. Eye contact can be avoided by wearing eye
protection such as a full-face shield or safety glasses with side and brow protection. Do not wear goggles
as they may trap vapors.

Skin Protection: Avoid skin contact with this material. Wear protective clothing and gloves (NIOSH
recommends Viton鈩? (gloves suits), Responder鈩? suits, Tychem 1000鈩? suits).

User Safety Requirements:
o Do not wear jewelry, gloves, goggles, tight clothing or any rubber protective clothing/boots
that can trap iodomethane or chloropicrin vapors against your skin. Iodomethane and
chloropicrin vapors can be trapped inside clothing and cause skin injury.
o Remove all clothing that comes in contact with liquid material at once.
o Aerate all effected clothing thoroughly prior to washing with hot water and detergent.
o Discard any clothing or absorbent materials (e.g. leather), that have been drenched or
heavily contaminated with this product. Do not reuse them.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Clear to light yellow
Appearance:
Acrid odor
Odor:
Liquid
Physical State:
6.55
pH:
NDA
Boiling Point:
NDA
Melting Point:
NDA
Freezing Point:

EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 5 of 8

410 Torr @ 25掳C
Vapor Pressure:
NDA
Vapor Density:
2.28 g/ml @ 20.3掳C
Specific Gravity:
NDA
Evaporation Rate:
NDA
Solubility:
NDA
Percent Solids by Weight:
100
Percent Volatile:
NDA
Volatile Organic Compounds (VOC):
NDA
Molecular Weight:
20.5掳 = 0.521 mPa 鈥? sec
C
Viscosity:
40.5掳 = 0.432 mPa 鈥? sec
C


SECTION 10: STABILITY AND REACTIVITY

Stable at room temperature in sealed containers. Turns
Chemical Stability:
yellow, red, or brown on exposure to light, due to
decomposition and liberation of free iodine. Decomposes at
270掳 (518掳
C F).
Will not occur
Hazardous Polymerization:
NDA
Flash Point:
NDA
Flammable Point:
NDA
Auto Ignition:
Strong oxidizers, powdered metals, reducing agents. Do not
Incompatibility With Other Materials:
use application devices containing natural rubber, aluminum,
magnesium or their alloys.
Burning may produce toxic iodine vapors.
Hazardous Decomposition Products:

SECTION 11: TOXICOLOGICAL INFORMATION

Acute:
LD50 (oral) rat = 151 mg/kg (male), 82 mg/kg (female)
LC50 (inhalation) rat = 618 ppm (3.6 mg/L)
LD50 (dermal) rat = > 2,000 mg/kg

Developmental / Reproductive:
Iodomethane: Pregnant rabbits exposed to 20 ppm iodomethane daily throughout pregnancy experienced
an increase in fetal loss mediated by excess iodine exposure to the fetus. The No effect level for this
effect was 10 ppm.

Carcinogenicity:
Iodomethane: IARC determined that iodomethane is Group 3, not classifiable as to its carcinogenicity to
humans based on limited evidence in experimental animals and inadequate evidence in humans.
Iodomethane is not listed in the current U.S. National Toxicology Program Report on Carcinogens as a
potential carcinogen, and not identified by OSHA as a potential carcinogen.

Chloropicrin: IARC has not identified chloropicrin as a potential carcinogen. Chloropicrin is not listed in the
current U.S. National Toxicology Program Annual Report on Carcinogens as a potential carcinogen, and
not identified by OSHA as a potential carcinogen.

SECTION 12: ECOLOGICAL INFORMATION

Environmental Fate and Distribution (based on Iodomethane technical material):
Soil: Dissipation/degradation in tarped strawberry and tomato field soil is very rapid 鈥? T1/2 = 5 days.

EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 6 of 8

The aerobic metabolic half life in sandy loam is 2 hours.

Water: Under anaerobic aquatic conditions, the major route of dissipation is volatilization - T1/2 = 42 hours.

This material is not an ozone depletor (ODP = 0.0015).

Avian Toxicity (based on Iodomethane technical material):
Northern bobwhite (C. virginianus) Oral LD50 = 57 mg/kg
Northern bobwhite (C. virginianus) 4-hr inhalation LC50 = 395 ppm (> 2 mg/l).

Aquatic Organism Toxicity:
Iodomethane:
Water flea (D. magna) 48 hr EC50 = 0.57 mg/L
Rainbow trout (O. mykiss) 96 hr LC50 = 1.4 mg/L

Chloropicrin:
Bluegill sunfish 96 hr LC50 = 0.105 mg/L
Trout 96 hr LC50 = 0.017 mg/L

SECTION 13: DISPOSAL CONSIDERATIONS

Check governmental regulations and local authorities for approved disposal of this material. Dispose in
accordance with applicable laws and regulations.

SECTION 14: TRANSPORT INFORMATION

Toxic by inhalation liquid, n.o.s.
D.O.T. Shipping Name:
Methyl iodide 98%, chloropicrin 2%
Technical Shipping Name:
I
Packing Group:
6.1
D.O.T. Hazard Class:
UN3382
U.N/N.A. Number:
102 lbs (methyl iodide)
Product RQ (lbs):
6.1 (poison inhalation hazard)
D.O.T. Label:
6.1 (poison inhalation hazard)
D.O.T. Placard:
No
Marine Pollutant:
Zone B
PIH :

Forbidden for transport by air
IATA :

IMO:
TOXIC BY INHALATION LIQUID, N.O.S., (CONTAINS 98%
Shipping Description:
METHYL IODIDE ,2% CHLOROPICRIN)
6.1
IMO Label:
6.1
IMO Placard:
I
Packing Group:
UN3382
UN Number:
Category D. Clear of living quarters.
Stowage and segregation:

RID/ARD:
6.1
Class:
6.1
Label:
6.1
Placard:



EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 7 of 8

SECTION 15: REGULATORY INFORMATION

U.S Federal Regulations
FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act): All pesticides are governed
under FIFRA. Therefore, the regulations presented below are pertinent only when handled outside
of the normal use and applications of pesticides. This includes waste streams resulting from
manufacturing/formulation facilities, spills or misuse of products, and storage of large quantities of
products containing hazardous or extremely hazardous substances.

CERCLA (Comprehensive Response Compensation, and Liability Act): Methyl iodide
Reportable Quantity = 100 lbs.

EPCRA (Emergency Planning and Community Right-to-Know Act) Section 313: Yes
(Chloropicrin and Methyl iodide)

OSHA (Occupational Safety and Health Administration): This product is hazardous under the
criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.

RCRA (Resource Conservation and Recovery Act): U138 (Waste Code for Methyl iodide)

SARA Title III (SUPERFUND Amendments and Reauthorization Act):
Section 302 (EHS) TPQ: NONE

Section 304 (EHS) RQ: NONE

Section 311/312 CATEGORIES 1. Immediate (Acute) Health Effects; YES
2. Delayed (Chronic) Health Effect; YES
3. Fire Hazard; NO
4. Sudden Release of Pressure Hazard; NO
5. Reactivity Hazard; NO

TSCA (Toxic Substance Control Act): This product is exempt from TSCA Regulation under
FIFRA Section 3 (2)(B)(ii) when used as a pesticide.

State Regulations: Each state may promulgate standards more stringent than the federal government.
This section cannot encompass an inclusive list of all state regulations. Therefore, the user should consult
state or local authorities.

California Proposition 65: 鈥淲ARNING. This product contains a chemical known to the
State of California to cause cancer.鈥? Methyl iodide is on the May 27, 2005 list of
Chemicals Known to the State to Cause Cancer or Reproductive Toxicity.

International Regulations:
EEC Classification: NDA

Risk Phrases: NDA

Safety Phrases: NDA

SECTION 16: OTHER INFORMATION

Changes to Section 1
Reason for issue:
Ashley R. Brown
Prepared by:
10/18/07
Issue date:
09/17/07
Supersedes date:

EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable
MIDAS庐 98:2 Page 8 of 8

00143
MSDS number:

The information in this MSDS is based on data available to us as of the issue date given herein, and
believed to be correct. Contact Arysta LifeScience North America Corporation at (919) 678-4900 to
determine if additional data and information have become available since the issue date.

Judgments as to the suitability of information herein for the individual鈥檚 own uses or purposes are
necessarily the individual鈥檚 own responsibility. Although reasonable care has been taken in the preparation
of such information, Arysta LifeScience North America Corporation extends no warranties, makes no
representations, and assumes no responsibility as to the accuracy or suitability of such information for
application to the individual's purposes or the consequences of its use.




EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00143 Issue Date: 10/18/07
NDA = No Data Available NA = Not Applicable

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69814-none_mite_off_11_15_2004_2_03_32_pm.asp N/A

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