MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : NALCO(R) EC5113A
COMPANY IDENTIFICATION : Nalco Company
1601 W. Diehl Road
Naperville, Illinois
60563-1198
EMERGENCY TELEPHONE NUMBER(S) : (800) 424-9300 (24 Hours) CHEMTREC
NFPA 704M/HMIS RATING
HEALTH : 2/3 FLAMMABILITY : 1/1 INSTABILITY : 0/0 OTHER :
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
2. COMPOSITION/INFORMATION ON INGREDIENTS
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the
nature of the hazard(s).
Hazardous Substance(s) CAS NO % (w/w)
2-Bromo-2-nitropropane-1,3-diol 52-51-7 60.0 - 100.0
3. HAZARDS IDENTIFICATION
**EMERGENCY OVERVIEW**
DANGER
May be fatal if swallowed. Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin,
or on clothing. Harmful if swallowed and/or absorbed through the skin. Wear protective eye wear (goggles, face
shield or safety glasses) protective clothing and rubber gloves when handling. Wash thoroughly with soap and
water after handling. Remove contaminated clothing and wash before reuse.
Do not get in eyes, on skin, on clothing. Do not take internally. Do not breathe dust. Wear suitable protective
clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After
contact with skin, wash immediately with plenty of water.
May evolve oxides of nitrogen (NOx) under fire conditions. May evolve hydrogen bromide and bromine under fire
conditions.
PRIMARY ROUTES OF EXPOSURE :
Eye, Skin
HUMAN HEALTH HAZARDS - ACUTE :
EYE CONTACT :
Can cause moderate irritation. Causes irreversible eye damage.
SKIN CONTACT :
Can cause moderate to severe irritation. Causes skin burns. Harmful if absorbed through skin.
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MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
INGESTION :
Not a likely route of exposure. May be harmful if swallowed.
INHALATION :
Dust irritating to eyes, nose, throat and lungs.
SYMPTOMS OF EXPOSURE :
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS :
A review of available data does not identify any worsening of existing conditions.
4. FIRST AID MEASURES
IF IN EYES: Hold eyelids open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing. Call poison control center or doctor for treatment advice.
IF SWALLOWED: Call a Poison Control Center or doctor immediately for treatment advice. Have person sip a glass
of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor.
IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a
poison control center or doctor for treatment advice.
IF INHALED: Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial
respiration, preferable mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice.
NOTE TO PHYSICIAN :
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and
clinical condition.
5. FIRE FIGHTING MEASURES
FLASH POINT : None
EXTINGUISHING MEDIA :
Carbon dioxide, Dry powder, Foam, Other extinguishing agent suitable for Class B fires, For large fires, use water
spray or fog, thoroughly drenching the burning material.
FIRE AND EXPLOSION HAZARD :
May evolve oxides of nitrogen (NOx) under fire conditions. May evolve hydrogen bromide and bromine under fire
conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
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MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS :
Notify appropriate government, occupational health and safety and environmental authorities. Use personal
protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
METHODS FOR CLEANING UP :
Sweep up and shovel. Reclaim into recovery or salvage drums. Dispose of material in compliance with regulations
indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS :
Do not contaminate surface water., ^^This pesticide is toxic to fish. Do not discharge effluent containing this active
ingredient into lakes, streams, ponds estuaries, oceans, or public waters.^
7. HANDLING AND STORAGE
HANDLING :
Do not take internally. Ensure all containers are labeled. Avoid eye and skin contact. Avoid generating dusts.
STORAGE CONDITIONS :
Store separately from oxidizers. Keep in dry place. Store away from heat and sources of ignition.
UNSUITABLE CONSTRUCTION MATERIAL :
Metals
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS :
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are
shown below.
ACGIH/TLV :
Substance(s)
Respirable Nuisance TWA: 3 mg/m3
Particulates
Inhalable (Total) Nuisance TWA: 10 mg/m3
Particulates
OSHA/PEL :
Substance(s)
Respirable Nuisance TWA: 5 mg/m3
Particulates
Inhalable (Total) TWA: 15 mg/m3 (total dust)
Nuisance Particulates
Manufacturer's Recommendation :
Substance(s)
2-Bromo-2-nitropropane- TWA: 0.5 mg/m3
1,3-diol
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
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MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
ENGINEERING MEASURES :
General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are
generated.
RESPIRATORY PROTECTION :
Respiratory protection is not normally needed. An approved respirator must be worn if the occupational exposure
limit is likely to be exceeded. A dust respirator may be used.
HAND PROTECTION :
Nitrile gloves, PVC gloves, Neoprene gloves, Rubber gloves, Butyl gloves
SKIN PROTECTION :
When handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended.
EYE PROTECTION :
Wear chemical splash goggles.
HYGIENE RECOMMENDATIONS :
Keep an eye wash fountain available. Keep a safety shower available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Solid
APPEARANCE White
ODOR None
SOLUBILITY IN WATER Miscible
Note: These physical properties are typical values for this product and are subject to change.
10. STABILITY AND REACTIVITY
STABILITY :
Stable under normal conditions.
HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.
CONDITIONS TO AVOID :
Moisture
MATERIALS TO AVOID :
Metals
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
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MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
HAZARDOUS DECOMPOSITION PRODUCTS :
Under fire conditions: Oxides of nitrogen, Hydrogen bromide
11. TOXICOLOGICAL INFORMATION
The following results are for the product.
ACUTE ORAL TOXICITY :
Species LD50 Test Descriptor
Rat 307 mg/kg Product
Mouse 327 mg/kg Product
ACUTE DERMAL TOXICITY :
Species LD50 Test Descriptor
Rat 1,600 mg/kg Product
CARCINOGENICITY :
None of the substances in this product are listed as carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial
Hygienists (ACGIH).
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL EFFECTS :
The following results are for the product.
ACUTE FISH RESULTS :
Species Exposure LC50 Test Descriptor
Rainbow Trout 96 hrs 20 mg/l Product
Bluegill Sunfish 96 hrs 35.7 mg/l Product
Sheepshead Minnow 96 hrs 57.6 mg/l Product
ACUTE INVERTEBRATE RESULTS :
Species Exposure LC50 EC50 Test Descriptor
Brown Shrimp 96 hrs 121 mg/l Product
Mysid Shrimp (M. litoralis) 96 hrs 5.9 mg/l Product
AVIAN RESULTS :
Species Exposure LC50 Test Descriptor
Mallard Duck 96 hrs 510 mg/kg Product
If released into the environment, see CERCLA/SUPERFUND in Section 15.
13. DISPOSAL CONSIDERATIONS
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
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MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a
violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your
State Pesticide or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA
Regional Office for guidance.
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties,
and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT :
Proper Shipping Name : 2-BROMO-2-NITROPROPANE-1,3-DIOL
Technical Name(s) :
UN/ID No : UN 3241
Hazard Class - Primary : 4.1
Packing Group : III
Flash Point : None
AIR TRANSPORT (ICAO/IATA) :
Proper Shipping Name : 2-BROMO-2-NITROPROPANE-1,3-DIOL
Technical Name(s) :
UN/ID No : UN 3241
Hazard Class - Primary : 4.1
Packing Group : III
IATA Cargo Packing Instructions : 434
IATA Cargo Aircraft Limit : 50 KG (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO) :
Proper Shipping Name : 2-BROMO-2-NITROPROPANE-1,3-DIOL
Technical Name(s) :
UN/ID No : UN 3241
Hazard Class - Primary : 4.1
Packing Group : III
15. REGULATORY INFORMATION
NATIONAL REGULATIONS, USA :
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 :
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are
shown below.
2-Bromo-2-nitropropane-1,3-diol : Irritant
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
6/9
MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
CERCLA/SUPERFUND, 40 CFR 117, 302 :
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311,
312, AND 313 :
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) :
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) :
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following
indicated EPA hazard categories:
X Immediate (Acute) Health Hazard
- Delayed (Chronic) Health Hazard
- Fire Hazard
- Sudden Release of Pressure Hazard
- Reactive Hazard
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely
hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372) :
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA) :
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
CALIFORNIA PROPOSITION 65 :
This product does not contain substances which require warning under California Proposition 65.
MICHIGAN CRITICAL MATERIALS :
None of the substances are specifically listed in the regulation.
STATE RIGHT TO KNOW LAWS :
The following substances are disclosed for compliance with State Right to Know Laws:
NATIONAL REGULATIONS, CANADA :
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) :
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION :
Pesticide controlled products are not regulated under WHMIS.
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
7/9
MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) :
Substances regulated under the Pest Control Products Act are exempt from CEPA New Substance Notification
requirements.
16. OTHER INFORMATION
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures should
be evaluated so that appropriate handling practices and training programs can be established to insure safe
workplace operations. Please consult your local sales representative for any further information.
REFERENCES
Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American
Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM
Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-
ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services,
Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety
and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati,
OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel
Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By : Product Safety Department
Date issued : 04/16/2007
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
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8/9
MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO(R) EC5113A
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
Version Number : 1.0
Nalco Company 1601 W. Diehl Road 鈥? Naperville, Illinois 60563-1198 鈥? (630)305-1000
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