3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) TB Spray Disinfectant - Discontinued
3M
MANUFACTURER:
Building & Commercial Services Division
DIVISION:
3M Center
ADDRESS:
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
06/28/2007
Issue Date:
12/13/2004
Supercedes Date:
Document Group: 18-1559-6
Product Use:
Intended Use: Disinfectant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
ETHYL ALCOHOL 64-17-5 37
WATER 7732-18-5 10 - 30
BUTANE 106-97-8 15 - 30
PROPANE 74-98-6 7 - 13
ALKYL DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDE 68956-79-6 0.05
ALKYL DIMETHYL AMMONIUM CHLORIDES 68391-01-5 0.05
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Aerosol
Odor, Color, Grade: Clear colorless, fresh scent
General Physical Form: Gas (Aerosol)
Immediate health, physical, and environmental hazards: Flammable liquefied gas. Closed containers exposed to heat from fire
may build pressure and explode. Aerosol container contains flammable material under pressure. Vapors may travel long distances
_________________________________________________________________________________________________
Page 1 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
along the ground or floor to an ignition source and flash back. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Single exposure, above recommended guidelines, may cause:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness,
and nose and throat pain.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
Target Organ Effects:
Single exposure, above recommended guidelines, may cause:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity:
NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of
ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an
expected effect during the foreseeable use of this product. Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation
ETHYL ALCOHOL 64-17-5 Group 1 International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
_________________________________________________________________________________________________
Page 2 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. Get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
<=00 潞F [Test Method: Tagliabue Closed Cup]
Flash Point
1.9
Flammable Limits - LEL
19
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Flammable liquefied gas. Closed containers exposed to heat from fire may build pressure
and explode. Aerosol container contains flammable material under pressure. Vapors may travel long distances along the ground or
floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal
decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use
only non-sparking tools. Ventilate the area with fresh air. If possible, seal leaking container. Place leaking containers in a
well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate
packaging for the leaking container or its contents is available. Dilute in a large excess of water. Carefully, and with stirring, add
appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. For large spills, if necessary, get assistance from
professional spill clean up team. For small spills, carefully neutralize spill by adding appropriate dilute acid such as vinegar. Work
slowly to avoid boiling or spattering. Continue to add neutralizing agent until reaction stops. Let cool before collecting. Or use a
_________________________________________________________________________________________________
Page 3 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
commercially available caustic (alkaline or basic) spill clean-up kit. Follow kit directions exactly. Clean up residue. Collect the
resulting residue containing solution. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. Do not spray near
flames or sources of ignition. Aerosol container contains flammable gas under pressure. Avoid eye contact with vapors, mists, or
spray. Avoid prolonged or repeated skin contact. Avoid breathing of vapors, mists or spray. Keep out of the reach of children.
7.2 STORAGE
Store away from heat. Store out of direct sunlight. Do not store containers on their sides. Store below 120 F (49 C).
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure
assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
BUTANE ACGIH TWA 1000 ppm
BUTANE OSHA TWA 800 ppm Table Z-1A
ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4
ETHYL ALCOHOL OSHA TWA 1000 ppm Table Z-1
PROPANE ACGIH TWA 1000 ppm
PROPANE OSHA TWA 1000 ppm Table Z-1
_________________________________________________________________________________________________
Page 4 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Aerosol
Specific Physical Form:
Clear colorless, fresh scent
Odor, Color, Grade:
Gas (Aerosol)
General Physical Form:
No Data Available
Autoignition temperature
<=00 潞F [Test Method: Tagliabue Closed Cup]
Flash Point
1.9
Flammable Limits - LEL
19
Flammable Limits - UEL
No Data Available
Boiling point
No Data Available
Density
No Data Available
Vapor Density
No Data Available
Vapor Pressure
0.73
Specific Gravity
10 - 11
pH
Not Applicable
Melting point
Complete
Solubility in Water
No Data Available
Evaporation rate
70 - 80 %
Volatile Organic Compounds
Approximately 100 %
Percent volatile
655 g/l
VOC Less H2O & Exempt Solvents
No Data Available
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat; Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
_________________________________________________________________________________________________
Page 5 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
UPC ID Number UPC
ID Number
70-0711-5631-2 00-48011-34770-2
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
_________________________________________________________________________________________________
Page 6 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
FIFRA
Status Registration Number
Registered 67603-4-10350
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
INTERNATIONAL REGULATIONS
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 2
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known
to be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS庐) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS庐 ratings are to be used with a fully implemented HMIS庐 program. HMIS庐 is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
Section 1: Product use information was modified.
Section 1: Division name was modified.
Copyright was modified.
Section 3: Immediate physical hazard(s) was modified.
_________________________________________________________________________________________________
Page 7 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) TB Spray Disinfectant 06/28/2007
Section 3: Potential effects from inhalation information was modified.
Section 5: Unusual fire and explosion hazard information was modified.
Section 6: Release measures information was modified.
Section 7: Handling information was modified.
Section 8: Eye/face protection phrase was modified.
Section 8: Skin protection phrase was modified.
Section 8: Prevention of swallowing information was modified.
Section 13: Waste disposal method information was modified.
Section 4: First aid for inhalation - termination of exposure - was modified.
Section 4: First aid for inhalation - medical assistance - was modified.
Section 1: Trade name status was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED
WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE
OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of
which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether
it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 8 of 8
|