Material Safety Data Sheet
Transportation and Medical Emergency Phone: 800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 67690-1
Effective Date: October 1, 1998
Pipron* Liquid Concentrate SePRO Corporation Carmel, IN
SKIN: Prolonged or repeated exposure may cause
1. CHEMICAL PRODUCT & COMPANY
severe skin irritation. Repeated contact may cause
IDENTIFICATION
drying or flaking of the skin. Did not cause allergic
Product: Pipron* Liquid Concentrate
skin reactions when tested in guinea pigs. A single
prolonged exposure is not likely to result in the
Company:
material being absorbed through the skin in harmful
SePRO Corporation
amounts. The LD50 for skin absorption in rabbits is
11550 North Meridian Street, Suite 600
>5650 mg/kg.
Carmel, IN 46032-4565
www.sepro.com
INGESTION: Single dose oral toxicity is low. Small
amounts swallowed incidental to normal handling
2. COMPOSITION/INFORMATION ON INGREDIENTS
operations are not likely to cause injury; however,
Piperalin: 3-(2-methylpiperidino)propyl-3,4- swallowing larger amounts may cause injury. If
dichlorobenzoate aspirated (liquid enters the lung), may cause lung
CAS # 003478-94-2 ......................................... 84.4% damage or even death due to chemical pneumonia.
Proprietary Ingredients, Total, Including .......... 15.6% The oral LD50 for rats is between 500 and 5000
Aromatic 150 CAS # 064742-94-5 mg/kg.
Naphthalene CAS # 000091-20-3
INHALATION: Mists may cause irritation of upper
This document is prepared pursuant to the OSHA respiratory tract. Excessive exposure to vapors may
Hazard Communication Standard (29 CFR cause irritation to the upper respiratory tract and
1910.1200). In addition, other substances not lungs. Signs and symptoms of excessive exposure
鈥楬azardous鈥? per this OSHA Standard may be listed. may be central nervous effects and anesthetic or
Where proprietary ingredient shows, the identity may narcotic effects. The LC50 for rats is between .50 and
be made available as provided. 3.85 mg/L for 4 hours.
3. HAZARDS IDENTIFICATION SYSTEMIC (OTHER TARGET ORGAN) EFFECTS:
EMERGENCY OVERVIEW No significant toxicologic effects were observed in
laboratory animals fed piperalin at high dietary
Warning: Combustible liquid. Viscous, reddish-
concentrations. Cataracts and other eye effects
orange liquid with a mild aromatic odor. May cause
have been reported in humans repeatedly exposed
severe eye irritation with corneal injury. Prolonged or
to naphthalene vapors, a component of the solvent
repeated exposure may cause severe skin irritation
in this formulation.
and drying or flaking of the skin. LD50 for skin
absorption in rabbits is >5650 mg/kg. Oral LD50 for
CANCER INFORMATION: No relevant information
rats is between 500 and 5000 mg/kg. The inhalation
found.
LC50 for rats is between .50 and 3.85 mg/L for 4
hours.
TERATOLOGY (BIRTH DEFECTS): For piperalin
EMERGENCY TELEPHONE NUMBER:
and the solvent: did not cause birth defects in
800-535-5053
laboratory animal tests; other fetal effects occurred
only at doses toxic to the mother.
POTENTIAL HEALTH EFFECTS: This section
includes possible adverse effects which could occur
REPRODUCTIVE EFFECTS: No relevant
if this material is not handled in the recommended
information found.
manner.
4. FIRST AID
EYE: May cause severe eye irritation with corneal
EYES: Flush eyes with plenty of water. Seek
injury which may result in permanent impairment of
medical attention if irritation develops.
vision, even blindness. Vapors may irritate eyes.
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* Trademark of SePRO Corporation
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 67690-1
Effective Date: October 1, 1998
Pipron Liquid Concentrate Fungicide SePRO Corporation Carmel, IN
SKIN: Wash off in flowing water or shower. Seek 6. ACCIDENTIAL RELEASE MEASURES
medical attention if irritation develops. ACTION TO TAKE FOR SPILLS/LEAKS: Use
absorbent material to contain and clean up small
INGESTION: If swallowed, do not induce vomiting. spills and dispose as waste. Report large spills to
Call a physician or poison control center. If available, INFOTRAC and consult SePRO Corporation for
administer activated charcoal (6-8 heaping assistance. Prohibit use of hot or sparking
teaspoonsful) with a large quantity of water. Do not equipment in immediate area. Prevent runoff.
give anything by mouth to an unconscious person.
Immediately transport to a medical care facility and
7. HANDLING AND STORAGE
see a physician.
PRECAUTIONS TO BE TAKEN IN HANDLING AND
STORAGE: Keep out of reach of children. Causes
INHALATION: If discomfort occurs, remove
substantial but temporary eye irritation. Harmful if
individual to fresh air. If breathing difficulty occurs,
swallowed, inhaled, or absorbed through the skin.
seek medical attention. If not breathing, provide
Do not get in eyes, on skin, or on clothing. Avoid
cardiopulmonary resuscitation and seek medical
breathing vapors and spray mist. Users should
attention immediately.
wash hands before eating, drinking, chewing gum,
using tobacco, or using the toilet. Read the product
NOTE TO PHYSICIAN: This product contains an
label for information relative to the end-use of this
aromatic hydrocarbon and can be extremely harmful
product and concerning the use of personal
if swallowed. Aspiration of this product may produce
protective equipment (PPE) under the Worker
a severe pneumonitis. Stomach lavage with a cuffed
Protection Standard of 1993 (see Section 8). Store
endotracheal tube in place and immediate
in original container with the lid tightly closed.
administration of activated charcoal, 6 to 8 heaping
teaspoonsful with water should be considered.
8. EXPOSURE CONTROLS/PERSONAL
Treatment is otherwise symptomatic and supportive
PROTECTION
based on judgment of the physician in response to
These precautions are suggested for conditions with
reactions of the patient.
a high potential for exposure. If handling procedures
are such that there is only a low potential for
5. FIRE FIGHTING MEASURES
exposure, less protection may be needed.
FLASH POINT: 160oF (71.1oC)
Emergency conditions may require additional
Method Used: SCC
precautions.
FLAMMABLE LIMITS: LFL: 0.9 +/- 0.1%
EXPOSURE GUIDELINES: OSHA PEL and ACGIH
UFL: 1.2 +/- 0.1%
TLV for piperalin and Aromatic 150 have not been
established. The manufacturer鈥檚 recommended
AUTO-IGNITION TEMPERATURE: 563oF (295oC)
exposure guideline for Aromatic 150 is 100 ppm total
hydrocarbon based on composition. Naphthalene
EXTINGUISHING MEDIA: Use water, CO2 or dry
ACGIH TLV and OSHA PEL are 10 ppm TWA, 15
chemicals.
ppm STEL. PELs are in accord with those
recommended by OSHA, as in the 1989 revision of
FIRE AND EXPLOSION HAZARDS: Classified as a
PELs.
combustible liquid. Closed containers may explode
due to pressure build-up when subjected to
ENGINEERING CONTROLS: Provide general and
excessive heat or intense fire.
or local exhaust ventilation to control airborne levels
below the exposure guidelines.
FIRE-FIGHTING EQUIPMENT: Wear positive-
pressure, self-contained breathing apparatus and full
RESPIRATORY PROTECTION: If respiratory
protective clothing.
irritation is experienced, use a NIOSH approved air-
2
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 67690-1
Effective Date: October 1, 1998
Pipron Liquid Concentrate Fungicide SePRO Corporation Carmel, IN
purifying respirator. In misty atmospheres, use a
NIOSH approved respirator for mist. 10. STABILITY AND REACTIVITY
STABILITY: (CONDITIONS TO AVOID) Do not
SKIN PROTECTION: For handling prior to end-use store near heat or flame.
of this product, use protective clothing impervious to
this material when prolonged or frequently-repeated INCOMPATIBILITY: (SPECIFIC MATERIALS TO
contact could occur. Selection of specific items such AVOID) Avoid freezing.
as faceshield, gloves, boots, apron, or full body suit
will depend on operation. For handling relative to the HAZARDOUS DECOMPOSITION PRODUCTS:
end-use of this product, the Worker Protection Hydrogen chloride and oxides of nitrogen may form
Standard of 1993 requires that applicators and other if product is involved in a fire.
handlers must wear coveralls over a long-sleeved
shirt and long pants; chemical resistant gloves such HAZARDOUS POLYMERIZATION: Does not occur.
as Barrier Laminate, Nitrile Rubber, Butyl Rubber, or
Viton; chemical resistant footwear and socks; and
11. TOXICOLOGICAL INFORMATION
chemical resistant headgear for overhead exposure.
MUTAGENICITY: In-vitro mutagenicity studies on
Chemical resistant apron must be worn when
the components were negative. For piperalin,
cleaning equipment, mixing, or loading. Remove
laboratory animal mutagenicity studies were
clothing immediately if pesticide gets inside, then
negative.
wash thoroughly and put on clean clothing. Users
should remove personal protective equipment (PPE)
12. ENVIRONMENTAL INFORMATION
immediately after handling the product. Wash the
Do not apply directly to water or wetlands. Do not
outside of gloves before removing. As soon as
contaminate water, food or feed by storage or
possible, wash thoroughly and put on clean clothing.
disposal. Do not contaminate water when disposing
Discard clothing and other absorbent materials that
of equipment wash water.
may have been drenched or heavily contaminated
with this product鈥檚 concentrate. Do not reuse them.
Follow manufacturer鈥檚 instructions for 13. DISPOSAL CONSIDERATIONS
cleaning/maintaining PPE. If there are no such Disposal: Do not contaminate water, food, or feed by
instructions for washables, use detergent and hot storage or disposal. Wastes resulting from the use of
water. Keep and wash PPE separately from other this product may be disposed on site per label use
laundry. directions or at an approved waste disposal facility.
Follow all local, state, and federal requirements for
EYE PROTECTION: Use chemical goggles. If vapor disposal.
exposure causes eye discomfort, use a full-face
NIOSH approved respirator. Applicators and other 14. TRANSPORTATION INFORMATION
end-use handlers must wear protective eyewear.
For DOT regulatory information, if required, consult
transportation regulations, product shipping papers,
9. PHYSICAL AND CHEMICAL PROPERTIES or your SePRO Corporation representative.
BOILING POINT: (@ 1 atmosphere) 280.4oF
(138oC) 15. REGULATORY INFORMATION
SOLUBILITY IN WATER: Emulsifies in water
NOTICE: The information herein is presented in
VAPOR PRESSURE: Approximately 3 mmHg @
good faith and believed to be accurate as of the
25oC
effective data shown above. However, no warranty,
SPECIFIC GRAVITY: 1.130 @ 20oC
express or implied, is given. Regulatory
APPEARANCE: Viscous, reddish-orange liquid
requirements are subject to change and may differ
VAPOR DENSITY: 4.8 relative to air @ 25oC
from one location to another, it is the user鈥檚
ODOR: Mild aromatic
responsibility to ensure that its activities comply with
pH: (aqueous 50/50) 8.50
federal, state, and local laws. The following specific
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Material Safety Data Sheet
Transportation and Medical Emergency Phone: 800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 67690-1
Effective Date: October 1, 1998
Pipron Liquid Concentrate Fungicide SePRO Corporation Carmel, IN
information is made for the purpose of complying PA3=Pennsylvania Environmental Hazardous
with numerous federal, state, and local laws and Substance (present at >/= to 1.0%)
regulations.
TOXIC SUBSTANCES CONTROL ACT (TSCA): All
SARA 313 INFORMATION: This product contains ingredients are on the TSCA inventory or are not
the following substances subject to the reporting required to be listed on the TSCA inventory.
requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of OSHA HAZARD COMMUNICATION STANDARD:
1986 and 40 CFR Part 732: This product is a 鈥楬azardous Chemical鈥? as defined
by the OSHA Hazard Communication Standard (29
Nominal CFR 1910.1200).
Chemical Name CAS Number Concentration
COMPREHENSIVE ENVIRONMENTAL
Naphthalene 000091-20-3 1% RESPONSE COMPENSATION AND LIABILITY
ACT (CERCLA, OR SUPERFUND): This product
SARA HAZARD CATEGORY: This product has contains the following substance(s) listed as
been reviewed according to the EPA 鈥淗azard 鈥淗azardous Substances鈥? under CERCLA which may
Categories鈥? promulgated under Sections 311 and require reporting of released:
312 of the Superfund Amendments and
Reauthorization Act of 1986 (SARA Title III) and is % in
considered, under applicable definitions, to meet the Chemical Name CAS # RQ Product
following categories:
An immediate health hazard Naphthalene 000091-20-3 100 1%
A delayed health hazard
A fire hazard RCRA CATEGORIZATION: US EPA Hazardous Waste
Number for Naphthalene = U165
NATIONAL FIRE PROTECTION ASSOCIATION
(NFPA 704): (4=Extreme; 3 = High; 2=Moderate; 16. OTHER INFORMATION
1=Slight; 0=Insignificant) MSDS Status:
Revised to ANSI Standard 16 Section MSDS
Health: 2 Updated all sections
Flammability: 2 Replaces MSDS dated: August 25, 1994
Reactivity: 0
STATE RIGHT-TO-KNOW: This following product
components are cited on certain state lists as
mentioned. Non-listed components may be shown in
Section 1 of the MSDS.
Chemical Name CAS Number List
Naphthalene 000091-20-3 NJ2, NJ3, PA1,
PA3
NJ2=New Jersey Environmental Hazardous
Substance (present at >/= to 1.0%)
NJ3=New Jersey Workplace Hazardous Substance The Information Herein Is Given In Good Faith, But
(present at >/= to 1.0%) No Warranty, Express Or Implied, Is Made. Consult
PA1=Pennsylvania Hazardous Substance (present SePRO Corporation For Further Information.
at >/= to 1.0%)
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