Material Safety Data Sheet
PURESPRAY 10E
1. Product and company identification
: PURESPRAY 10E
Common name
: SPREM10, 440-177
Code
: Emulsified Spray Oils are severely hydrotreated mineral oils with added emulsifier, used as
Material uses
dormant oils for agricultural spray.
: PETRO-CANADA
Manufacturer
P.O. Box 2844
Calgary, Alberta
T2P 3E3
In case of emergency : Petro-Canada: 403-296-3000
Canutec Transportation:
613-996-6666
Poison Control Centre: Consult local telephone directory for emergency number(s).
2. Hazards identification
: Viscous liquid.
Physical state
: No odour or slight petroleum oil like.
Odor
: While this material is not considered hazardous by the OSHA Hazard Communication
OSHA/HCS status
Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the
safe handling and proper use of the product. This MSDS should be retained and
available for employees and other users of this product.
: No specific hazard.
Emergency overview
: Dermal contact. Eye contact. Inhalation. Ingestion.
Routes of entry
Potential acute health effects
: Slightly irritating to the eyes.
Eyes
: Slightly irritating to the skin.
Skin
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Ingestion
: Repeated or prolonged contact with spray or mist may produce chronic eye irritation and
Medical conditions
severe skin irritation. Repeated skin exposure can produce local skin destruction or
aggravated by over-
dermatitis.
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
Name CAS number %
Mixture of severely hydrotreated and hydrocracked base oil (petroleum). Mixture -
The base oil may be a mixture of the following CAS#s: 8042-47-5, 64742-46-7, 64742-52-5, 64742-54-7, 72623-84-8,
72623-85-9, 72623-86-0, 72623-87-1, 178603-64-0, 178603-65-1, 178603-66-2, 445411-73-4
4. First aid measures
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Eye contact
Get medical attention if irritation occurs.
: Wash skin thoroughly with soap and water or use recognized skin cleanser. Get medical
Skin contact
attention if irritation occurs. Remove contaminated clothing and shoes. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give
Inhalation
artificial respiration. Get medical attention.
: Do not induce vomiting unless directed to do so by medical personnel. Never give
Ingestion
anything by mouth to an unconscious person. If potentially dangerous quantities of this
material have been swallowed, call a physician immediately.
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PURESPRAY 10E Page Number: 2
4. First aid measures
: No action shall be taken involving any personal risk or without suitable training. It may
Protection of first-aiders
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
5. Fire-fighting measures
: May be combustible at high temperature.
Flammability of the product
: Carbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete
Products of combustion
combustion.
Extinguishing media
: Use an extinguishing agent suitable for the surrounding fire.
Suitable
: None known.
Not suitable
: In a fire or if heated, a pressure increase will occur and the container may burst.
Special exposure hazards
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
Special protective
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
: Low fire hazard. This material must be heated before ignition will occur.
Special remarks on fire
hazards
: Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or
Special remarks on
sources of ignition.
explosion hazards
6. Accidental release measures
: No action shall be taken involving any personal risk or without suitable training.
Personal precautions
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
Environmental precautions
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
: Large spill: Stop leak if without risk. Move containers from spill area. Approach release
Methods for cleaning up
from upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see section
1 for emergency contact information and section 13 for waste disposal.
7. Handling and storage
: Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire
Handling
risk. Evaporate the residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable
protective clothing. If ingested, seek medical advice immediately and show the container
or the label. Keep away from incompatibles.
: Keep container tightly closed. Store away from incompatible materials (see section 10).
Storage
Keep container in a cool, well-ventilated area.
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PURESPRAY 10E Page Number: 3
8. Exposure controls/personal protection
Product name Exposure limits
Mixture of severely hydrotreated and ACGIH TLV (United States). Notes: (oil mist)
hydrocracked base oil (petroleum). TWA: 5 mg/m鲁 8 hour(s).
STEL: 10 mg/m鲁 15 minute(s).
Consult local authorities for acceptable exposure limits.
: No special ventilation requirements. Good general ventilation should be sufficient to
Engineering measures
control worker exposure to airborne contaminants. If this product contains ingredients
with exposure limits, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any recommended or statutory
limits.
Personal protection
: Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before handling
this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: organic vapor filter
: Chemical-resistant, impervious gloves complying with an approved standard should be
Hands
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Recommended: neoprene, nitrile, polyvinyl alcohol (PVA), Viton.
: Wash hands, forearms and face thoroughly after handling chemical products, before
Hygiene measures
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
9. Physical and chemical properties
Viscous liquid.
Physical state :
Open cup: 173掳C (343.4掳F) [Cleveland.]
Flash point :
Not available.
Auto-ignition temperature :
Not available.
Flammable limits :
Colorless to light yellow.
Color :
No odour or slight petroleum oil like.
Odor :
Not available.
pH :
Not available.
Boiling/condensation point :
Not available.
Pour point :
Not available.
Melting/freezing point :
0.8532 kg/L @ 15潞C (59潞F)
Relative density :
Not available.
Vapor pressure :
Not available.
Vapor density :
Not available.
Volatility :
Not available.
Odor threshold :
Not available.
Evaporation rate :
9.6 cSt @ 40掳C (104潞F), 2.5 cSt @ 100掳C (212潞F)
Viscosity :
Insoluble in water. Easily dispersed in water.
Solubility :
Not available.
LogKow :
Not available.
Softening Point :
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PURESPRAY 10E Page Number: 4
9. Physical and chemical properties
: Not available.
Dropping Point
: Not available.
Penetration
: Not available.
Physical/chemical
properties comments
10 . Stability and reactivity
: The product is stable.
Stability and reactivity
: Not available.
Conditions of instability
: Reactive with oxidizing agents, acids and alkalis.
Incompatibility with various
substances
: COx, smoke and irritating vapours when heated to decomposition.
Hazardous decomposition
products
: Will not occur.
Hazardous polymerization
11 . Toxicological information
Toxicity data
Product/ingredient name Test Result Route Species
PURESPRAY SPRAY OIL 10E LD50 >2000 mgkkg Oral Rat
LD50 >2000 mg/kg Dermal Rabbit
LC50 >5 mg/L (4 Inhalation Rat
hours)
Specific effects
: Not listed as carcinogen by OSHA, NTP or IARC.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Teratogenicity /
Reproductive toxicity
Sensitization
No known significant effects or critical hazards.
Ingestion :
No known significant effects or critical hazards.
Inhalation :
Slightly irritating to the eyes.
Eyes :
Slightly irritating to the skin.
Skin :
Not available.
Synergistic products :
12 . Ecological information
Ecotoxicity data
Product/ingredient name Species Period Result
: No known significant effects or critical hazards.
Environmental precautions
Not available.
Bioconcentration factor
Not available.
BOD and COD
Not available.
Biodegradable/OECD
Not available.
Mobility
Not available.
Special remarks on the
products of biodegradation
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PURESPRAY 10E Page Number: 5
13 . Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
: The generation of waste should be avoided or minimized wherever possible. Dispose of
Waste disposal
surplus and non-recyclable products via a licensed waste disposal contractor. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
14 . Transport information
Regulatory UN number Proper shipping Class PG* Label Additional
information name information
Not - - - -
TDG Classification
regulated.
Not available. Not available. Not - -
DOT Classification
available.
PG* : Packing group
15 . Regulatory information
United States
: Not regulated.
HCS Classification
Canada
: Not controlled under WHMIS (Canada).
WHMIS (Canada)
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
International regulations
International lists
: Listed
CANADA INVENTORY (DSL)
: Listed
EC INVENTORY (EINECS/ELINCS)
: Listed
TSCA 8(b) inventory
16 . Other information
1
Hazardous Material : Health
Information System (U.S.A.)
1
Fire hazard
0
Reactivity
B
Personal protection
National Fire Protection :
Flammability
1
Association (U.S.A.)
1 0
Health Instability
Special
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PURESPRAY 10E Page Number: 6
16 . Other information
: Available upon request.
References
* Marque de commerce de Petro-Canada - Trademark
Date of printing : 1/19/2007.
: 1/19/2007.
Date of issue
Date of previous issue : No previous validation.
Responsible name : Product Safety - JDW
Version : 1
Internet: www.petro-canada.ca/msds
For Copy of (M)SDS :
Lubricants:
Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564
Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax: 1-800-
201-6285
Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 1-800-201-6285
For Product Safety Information: (905) 804-4752
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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