MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET
Metzger/McGuire Page: 4 of 4 (Armor-Hard Extreme Part A) Metzger/McGuire Page: 1 of 4 (Armor-Hard Extreme Part A)
Concord, NH 03302 Date Prepared: 09/13/06 P. O. Box 2217 Date Prepared: 09/13/06
Telephone: (800) 223-6680 Revision Number: 1 Concord, NH 03302 Revision Number: 1
--------------------------------------------------------------------------------------------------------------------------- Telephone: (800) 223-6680
Section 14 - Transport Information ---------------------------------------------------------------------------------------------------------------------------
---------------------------------------------------------------------------------------------------------------------------- Section 1 - Material Identification
DOT Non-Bulk Shipping Name: Resin compound - not regulated ---------------------------------------------------------------------------------------------------------------------------
UN#: Not regulated Product Name: Armor-Hard Extreme (Resin)
DOT Bulk Shipping Name: Resin compound - not regulated Product Type: Epoxy Resin Compound
Packing Group: Not regulated Emergency Number (s): (800) 255-3924 24 hrs. (Continental U.S.)
(813) 248-0585 24 hrs. (Outside Continental U.S.)
Technical Shipping Name: NMFC Item 46030, Class 55
Revision Notes: Section 3
IMO Shipping Data: Resin compound - not regulated
---------------------------------------------------------------------------------------------------------------------------
DOT Hazard Class: Not regulated
Section 2 - Hazardous Ingredients
ICAO/IATA Shipping Data: Resin compound - not regulated
---------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
# wt % CAS Number Chemical Name
Section 15 - Regulatory Information
1. >1% Trade Secret Epoxy Resin
----------------------------------------------------------------------------------------------------------------------------
US FEDERAL REGULATIONS:
OSHA & ACGIH EXPOSURE LIMITS
Toxic Substances Control Act (TSCA): All components are included in the EPA Toxic Substances
Control Act (TSCA) Chemical Substance Inventory or are not required to be listed on the TSCA
TWA STEL CEILING
Inventory.
ppm mg/m3 Ppm mg/m3 Ppm mg/m3
OSHA (29CFR1910.1200) Hazard Class(es): Irritant. Sensitizer
N/E N/E N/E N/E N/E N/E
EPA Sara Title III Section 312 (40CFR370) Hazard Classes: Immediate Health Hazard. 1. OSHA
N/E N/E N/E N/E N/E N/E
Delayed Health Hazard. ACGIH
EPA Sara Title III Section 313 (40CFR372): Toxic chemicals above 鈥渄e minimus鈥? level: None
N/E = Not Established
----------------------------------------------------------------------------------------------------------------------------
STATE REGULATIONS:
Section 3 - Health Hazards
California Proposition 65 Substances: (components known to the State of California to cause
----------------------------------------------------------------------------------------------------------------------------
cancer and/or reproductive toxicity and subject to warning and discharge requirements under the
鈥淪afe Drinking Water and Toxic Enforcement Act of 1986鈥?). None ********************************************************************************
EMERGENCY OVERVIEW
********************************************************************************
INTERNATIONAL REGULATIONS
HMIS HEALTH RATING: 2 FLAMMABILITY: 1 REACTIVITY: 0
Canada: WHMIS Hazard Classification: Class D, division 2B
=======================================================================
WHMIS Risk Phrases: Eye or skin irritant. Skin sensitizer.
HMIS Hazard Rating 飪? Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4
WHMIS Symbols: Stylized T
=======================================================================
----------------------------------------------------------------------------------------------------------------------------
A cloudy, white liquid with a slight 鈥渟weet鈥? odor. Causes eye and skin irritation. Can burn in fire,
Section 16 - Other Information
releasing possible hazardous vapors, gases and fumes. Do not burn or weld on cured epoxy.
----------------------------------------------------------------------------------------------------------------------------
Hazardous fumes and vapors may be released.
To the best of our knowledge, the information contained herein is accurate. However, neither
Metzger/McGuire nor any of its agents assume any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any Routes of Exposure: Eye Contact, Skin Contact, Ingestion.
material is the sole responsibility of the user. All materials may present unknown health hazards Health Hazards: May cause eye irritation. May cause skin sensitization. Moderate skin irritant.
and should be used with caution. Although certain hazards are described herein, we cannot Target Organs: Eyes, Skin.
guarantee that these are the only hazards which exist. Signs and Symptoms of Exposure (Acute Effects): Contact with skin or eyes causes irritation,
redness and discomfort.
Revision Date: 09/13/06 Replaces Revision Dated: N/A Signs and Symptoms of Exposure (Possible Longer Term Effects): Repeated and/or prolonged
exposure may cause allergic reaction/ sensitization. Repeated and/or prolonged exposure may result
in adverse eye effects (such as conjunctivitis or corneal damage), adverse skin effects (such as rash,
irritation or corrosion).
Medical Conditions Generally Aggravated by Exposure: Eye disease, skin disorders and
allergies.
Carcinogens under OSHA, ACGIH, NTP, IARC, other: This product contains no carcinogens in
concentrations of 0.1 percent or greater.
MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET
Metzger/McGuire Page: 3 of 4 (Armor-Hard Extreme Part A)
Metzger/McGuire Page: 2 of 4 (Armor-Hard Extreme Part A)
Concord, NH 03302 Date Prepared: 09/13/06
Concord, NH 03302 Date Prepared: 09/13/06
Telephone: (800) 223-6680 Revision Number: 1
Telephone: (800) 223-6680 Revision Number: 1
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Section 8 - Personal Protection/Exposure Controls
Section 4 - First Aid
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Eye Protection: Chemical safety goggles recommended. Contact lenses should not be worn while
Eye Contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15
using this product.
minutes. Seek medical attention.
Hand Protection: Chemical resistant gloves recommended, such as neoprene or nitrite rubber.
Skin Contact: Remove contaminated clothing/shoes and wipe excess from skin. Flush skin with
Respiratory Protection: Not necessary under most operating conditions. NIOSH approved organic
water. Follow by washing with soap and water. If irritation occurs, seek medical attention. If contact
vapor respirator should be used in confined areas, or when conditions cause high vapor
with hot product occurs, immediately flush with cool water for 15 minutes. Carefully remove
concentrations. If the percent oxygen is below normal then use self-contained breathing apparatus.
clothing; if clothing is stuck to a burn area do not pull it off, but cut around it. Cover burn area with
Protective Clothing: Clean, body covering clothing should be utilized.
a clean material. Get medical attention immediately.
Work and Hygienic Practices: Eye wash stations and safety showers should be easily accessible.
Inhalation: Remove victim to fresh air and provide oxygen. If breathing is difficult, seek medical
----------------------------------------------------------------------------------------------------------------------------
attention.
Section 9 - Typical Physical and Chemical Properties
Ingestion: If swallowed, call physician immediately. Induce vomiting only as directed by medical
----------------------------------------------------------------------------------------------------------------------------
personnel. Never give anything by mouth to an unconscious person. Get medical attention
Physical Form: Liquid Vapor Density: Heavier than air
immediately.
> 200 飩癋
Color: Cloudy, White Boiling Point:
----------------------------------------------------------------------------------------------------------------------------
Odor: Slight Sweet Melting Point: Not Applicable
Section 5 - Fire and Explosion Data
pH: No Data Solubility in Water: Negligible
----------------------------------------------------------------------------------------------------------------------------
> 200 飩癋 Vapor Pressure: No Data Specific Gravity: 1.15
Flash Point (closed cup):
----------------------------------------------------------------------------------------------------------------------------
Upper Explosion Limit (UEL): No data
Section 10 - Stability and Reactivity
Auto Ignition Temperature: No data
----------------------------------------------------------------------------------------------------------------------------
Lower Explosion Limit (LEL): No data
Chemical Stability: Stable
Fire Hazard Classification (OSHA/NFPA): This product is not considered flammable nor
Conditions to Avoid (if unstable): None
combustible, but will burn if involved in a fire.
Incompatibility (Materials to Avoid): Acids, strong oxidizing agents.
Extinguishing Media: Foam, Carbon Dioxide (CO2), or dry chemical.
Hazardous Decomposition Products: None
Special Fire Fighting Procedures: Keep personnel removed from area and upwind of fire. Wear
Hazardous Polymerization: Contact with epoxy hardeners under uncontrolled
full fire-fighting turn-out gear (full bunker gear) and respiratory protection (SCBA). Cool fire
conditions. May release excess heat and vapors.
exposed containers with water spray.
Unusual Fire and Explosion Hazards: Hazardous combustion products may be present. Section 11 - Toxicological Properties
Combustion may form aldehydes, nitrous oxides, carbon monoxide (CO), and carbon dioxide (CO2). ----------------------------------------------------------------------------------------------------------------------------
Acute Oral Toxicity (LD50, RAT): No data available.
---------------------------------------------------------------------------------------------------------------------------- Acute Dermal Toxicity (LD50, RABBIT): No data available.
Section 6 - Accidental Release Measures Acute Inhalation Toxicity (LC50, RAT): No data available.
---------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------------------------------------------------------------------------
Containment Techniques (Removal of ignition sources, diking, etc.): Stop the leak, if possible. Section 12 - Ecological Information
Shut off or remove all ignition sources. Construct a dike to prevent spreading. ----------------------------------------------------------------------------------------------------------------------------
Clean-Up Procedures: Spread absorbent material over area. Wipe or scrape up material. Dispose
of material in accordance with local, state and federal regulations. Wash area with soap and water. No data available.
Prevent washings from entering sewers or waterways. ----------------------------------------------------------------------------------------------------------------------------
Other Emergency Advice: Wear protective clothing, boots, gloves, respirator, and eye protection. Section 13 - Disposal Considerations
----------------------------------------------------------------------------------------------------------------------------
---------------------------------------------------------------------------------------------------------------------------- Waste Disposal: This material does not contain any VOC鈥檚 (volatile organic compounds). Dispose
Section 7 - Handling and Storage of material in accordance with applicable, local, state, and federal laws and regulations. The state
---------------------------------------------------------------------------------------------------------------------------- and local regulations and laws may differ from federal regulations, and laws may change or be
Storage: Store in a cool (60-80 飩癋), dry, ventilated place. Crystallization may occur if storage reinterpreted. This information only applies to the material as manufactured. Processing, use, or
contamination may make the information in appropriate, inaccurate, or incomplete. Responsibility
temperature drops below 55飩癋 for a prolonged period of time. Store in closed containers.
for proper waste disposal is with the owner of the waste.
Handling: Avoid contact with skin, eyes, or clothing. When handling, do not eat, drink, or smoke.
Other Precautions: Wash thoroughly after handling. Remove contaminated clothing and gear.
Decontaminate. Destroy leather or any articles which can not be decontaminated.
MATERIAL SAFETY DATA SHEET
Metzger/McGuire Co. Page: 4 of 4 (Armor-Hard Extreme Part B)
Concord, NH 033024473 Date Prepared: 09/13/06
MATERIAL SAFETY DATA SHEET
Telephone: (800) 223-6680 Revision Number: 1
----------------------------------------------------------------------------------------------------------------------------------
Metzger/McGuire Page: 1 of 4 (Armor-Hard Extreme Part B)
Section 14 - Transport Information
P. O. Box 2217 Date Prepared: 09/13/06
----------------------------------------------------------------------------------------------------------------------------------
Concord, NH 03302 Revision Number: 1
DOT Non-Bulk Shipping Name: Caustic Alkali Liquids, N.O.S.
Telephone: (800) 223-6680
UN#: UN1719
----------------------------------------------------------------------------------------------------------------------------------
DOT Bulk Shipping Name: Caustic Alkali Liquids, N.O.S.
Section 1 - Material Identification
Packing Group: III
----------------------------------------------------------------------------------------------------------------------------------
Technical Shipping Name: Contains Aliphatic Amine & Polyamide
Product Name: Armor-Hard Extreme (Hardener)
IMO Shipping Data: Caustic Alkali Liquid N.O.S.
Product Type: Epoxy Hardener Compound
DOT Hazard Class: 8
Emergency Number (s): (800) 255-3924 24hrs. (Continental U.S.)
ICAO/IATA Shipping Data: Caustic Alkali Liquid N.O.S.
(813) 248-0585 24hrs. (Outside Continental U.S.)
----------------------------------------------------------------------------------------------------------------------------------
Revision Notes: Section 3
Section 15 - Regulatory Information
----------------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------------
Section 2 - Hazardous Ingredients
US FEDERAL REGULATIONS:
----------------------------------------------------------------------------------------------------------------------------------
Toxic Substances Control Act (TSCA): All components are included in the EPA Toxic Substances
# wt % CAS Number Chemical Name
Control Act (TSCA) Chemical Substance Inventory or are not required to be listed on the TSCA Inventory.
1. >1% 80-05-7 4, 4鈥?-Isopropylidenediphenol
OSHA (29CFR1910.1200) Hazard Class(es): Corrosive. Sensitizer.
2. >1% 111-40-0 Diethylenetriamine
EPA Sara Title III Section 312 (40CFR370) Hazard Classes: Immediate Health hazard. Delayed
Health Hazard.
EPA Sara Title III Section 313 (40CFR372): Toxic chemicals above 鈥渄e minimus鈥? level:
OSHA & ACGIH EXPOSURE LIMITS
4, 4鈥? -
TWA STEL CEILING
Isopropylidenediphenol
Ppm Mg/m3 Ppm mg/m3 Ppm mg/m3
N/E N/E N/E N/E N/E N/E
1. OSHA
STATE REGULATIONS:
N/E N/E N/E N/E N/E N/E
ACGIH
California Proposition 65 Substances: (components known to the State of California to cause cancer
and/or reproductive toxicity and subject to warning and discharge requirements under the 鈥淪afe Drinking
1.0 4.0 N/E N/E N/E N/E
2. OSHA
Water and Toxic Enforcement Act of 1986鈥?). None
1.0 4.2 N/E N/E N/E N/E
ACGIH
INTERNATIONAL REGULATIONS
N/E = Not Established
----------------------------------------------------------------------------------------------------------------------------------
Canada: WHMIS Hazard Classification: Class D, Division 2A
Section 3 - Health Hazards
Class D, Division 2B
----------------------------------------------------------------------------------------------------------------------------------
Class E
*************************************************************************************
WHMIS Risk Phrases: Causes burns. Skin Sensitizer. Lung sensitizer.
EMERGENCY OVERVIEW
WHMIS Symbols: Stylized T, test tube/hand
*************************************************************************************
----------------------------------------------------------------------------------------------------------------------------------
HMIS HEALTH RATING: 3 FLAMMABILITY: 1 REACTIVITY: 0
Section 16 - Other Information
===========================================================================
----------------------------------------------------------------------------------------------------------------------------------
HMIS Hazard Rating 飪? Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4
To the best of our knowledge, the information contained herein is accurate. However, neither
===========================================================================
Metzger/McGuire nor any of its agents assume any liability whatsoever for the accuracy or
An yellow liquid with an amine odor. Corrosive to skin. Corrosive to eyes. Severe skin irritant. Severe
completeness of the information contained herein. Final determination of suitability of any material is
eye irritant. May cause skin sensitization. May cause respiratory sensitization. Can burn in fire, releasing
the sole responsibility of the user. All materials may present unknown health hazards and should be
possible hazardous vapors, gases and fumes.
used with caution. Although certain hazards are described herein, we cannot guarantee that these are
Do not burn or weld on cured epoxy. Hazardous fumes and vapors may be released.
the only hazards which exist.
*************************************************************************************
Routes of Exposure: Eye Contact, Skin Contact, Inhalation, Ingestion.
Revision Date: 09/13/06 Replaces Revision Dated: N/A Health Hazards: Corrosive to skin. Corrosive to eyes. Severe skin irritant. Severe eye irritant. May
cause skin sensitization. May cause respiratory sensitization.
Target Organs: Eyes, Skin, and Respiratory System.
Signs and Symptoms of Exposure (Acute Effects): Burns of the eye may cause blindness. Contact of
undiluted products with the eyes or skin quickly causes severe irritation and pain and may cause burns,
necrosis, and permanent injury. Inhalation of mists may severely damage contacted tissue and produce
scarring. Product is readily absorbed through the skin and may cause discomfort, injury or serious health
unless treated properly.
Signs and Symptoms of Exposure (Possible Longer Term Effects): This substance may cause Other Precautions: Emergency showers and eye wash stations should be readily accessible. Wash
respiratory sensitization to exposed workers. thoroughly after handling. Remove contaminated clothing and gear. Decontaminate. Destroy leather or
any articles, which can not be decontaminated.
Medical Conditions Generally Aggravated by Exposure: Asthma, chronic respiratory disease (e.g.
Bronchitis, emphysema). Eye disease, skin disorders and allergies.
MATERIAL SAFETY DATA SHEET
MATERIAL SAFETY DATA SHEET Metzger/McGuire Co. Page: 3 of 4 (Armor-Hard Extreme Part B)
Concord, NH 033024473 Date Prepared: 09/13/06
Metzger/McGuire Page: 2 of 4 (Armor-Hard Extreme Part B) Telephone: (800) 223-6680 Revision Number: 1
Concord, NH 03302 Date Prepared: 09/13/06 ----------------------------------------------------------------------------------------------------------------------------------
Telephone: (800) 223-6680 Revision Number: 1 Section 8 - Personal Protection/Exposure Controls
---------------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------------------------------------------------------------------------------
Section 3 - Health Hazards (con鈥檛.) Eye Protection: Full-face shield with chemical safety goggles. Contact lenses should not be worn while
---------------------------------------------------------------------------------------------------------------------------------- using this product.
Carcinogens under OSHA, ACGIH, NTP, IARC, other: This product contains no carcinogens in Hand Protection: Neoprene rubber gloves. Cuffed butyl rubber gloves. Nitrile rubber gloves.
concentrations of 0.1 percent or greater. Respiratory Protection: Not necessary under most operating conditions. NIOSH approved organic vapor
---------------------------------------------------------------------------------------------------------------------------------- respirator should be used in confined areas, or when conditions cause high vapor concentrations. If the
Section 4 - First Aid percent oxygen is below normal then use self-contained breathing apparatus.
---------------------------------------------------------------------------------------------------------------------------------- Protective Clothing: Impervious clothing. Slickersuit. Rubber boots. Full rubber suit (rain gear). Butyl
Eye Contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. or latex protective clothing.
Seek medical attention. Work and Hygienic Practices: Eye wash stations and safety showers should be easily accessible.
Skin Contact: Remove contaminated clothing/shoes and wipe excess from skin. Immediately flush ----------------------------------------------------------------------------------------------------------------------------------
affected area with water for at least 15 minutes. Cover the affected area with a sterile dressing or clean Section 9 - Typical Physical and Chemical Properties
sheeting and seek medical attention immediately. DO NOT APPLY GREASES OR OINTMENTS. ----------------------------------------------------------------------------------------------------------------------------------
Control shock if present. Physical Form: Liquid Vapor Density: Heavier than air
> 200 飩癋
Inhalation: Remove victim to fresh air and provide oxygen. If breathing is difficult, seek medical
Color: Yellow Boiling Point:
attention.
Odor: Amine Melting Point: Not applicable
Ingestion: In the event of ingestion, administer 3-4 glasses of milk or water. DO NOT INDUCE
pH: No Data Solubility in Water: Negligible
VOMITING. Seek medical attention immediately.
Vapor Pressure: No Data Specific Gravity: 1.02
----------------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------------
Section 5 - Fire and Explosion Data
Section 10 - Stability and Reactivity
----------------------------------------------------------------------------------------------------------------------------------
Flash Point (closed cup): > 200 飩癋
----------------------------------------------------------------------------------------------------------------------------------
Lower Explosion Limit (LEL): No data
Chemical Stability: Stable Conditions to Avoid (if stable): None
Upper Explosion Limit (UEL): No data Auto Ignition Temperature: No data
Incompatibility (Materials to Avoid): Acids, strong oxidizing agents.
Fire Hazard Classification (OSHA/NFPA): This product is considered neither flammable nor
Hazardous Decomposition Products: None
combustible, but will burn if involved in a fire.
Hazardous Polymerization: Contact with epoxy resins under uncontrolled conditions. May release
Extinguishing Media: Foam, Carbon Dioxide (CO2), or dry chemical.
excess heat and vapors.
Special Fire Fighting Procedures: Keep personnel removed from area and upwind of fire. Wear full fire-
----------------------------------------------------------------------------------------------------------------------------------
fighting turnout gear (full bunker gear) and respiratory protection (SCBA). Cool fire exposed containers
Section 11 - Toxicological Properties
with water spray.
----------------------------------------------------------------------------------------------------------------------------------
Unusual Fire and Explosion Hazards: Hazardous combustion products may be present. Combustion
Acute Oral Toxicity (LD50, RAT): No data available.
may form aldehydes, nitrous oxides, carbon monoxide (CO), and carbon dioxide (CO2).
Acute Dermal Toxicity (LD50, RABBIT): No data available.
----------------------------------------------------------------------------------------------------------------------------------
Acute Inhalation Toxicity (LC50, RAT): No data available.
Section 6 - Accidental Release Measures
----------------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------------
Section 12 - Ecological Information
Containment Techniques (Removal of ignition sources, diking etc.): Reduce vapor spreading with a
----------------------------------------------------------------------------------------------------------------------------------
water spray. Stop the leak, if possible. Shut off or remove all ignition sources. Construct a dike to prevent
No Data Available
spreading.
Clean-Up Procedures: Spread absorbent material over area. Transfer to containers by suction. For large
----------------------------------------------------------------------------------------------------------------------------------
spills, recover spilled material with a vacuum truck. Dispose of material in accordance with local, state and
Section 13 - Disposal Considerations
federal regulations. Wash area with soap and water. Prevent washings from entering sewers or waterways.
----------------------------------------------------------------------------------------------------------------------------------
Other Emergency Advice: Wear protective clothing, boots, gloves, respirator, and eye protection.
Waste Disposal: This material does not contain any VOC鈥檚 (volatile organic compounds). Dispose of
----------------------------------------------------------------------------------------------------------------------------------
material in accordance with applicable, local, state, and federal laws and regulations. The state and local
Section 7 - Handling and Storage
regulations and laws may differ from federal regulations, and laws may change or be reinterpreted. This
----------------------------------------------------------------------------------------------------------------------------------
information only applies to the material as manufactured. Processing, use, or contamination may make the
Storage: Store in a cool (60飩?- 80飩癋), dry ventilated place. Store in closed containers. information in appropriate, inaccurate, or incomplete. Responsibility for proper waste disposal is with the
Handling: Avoid breathing of vapors. Handle in well-ventilated workspace. Avoid contact with skin, owner of the waste.
eyes, or clothing. When handling, do not eat, drink, or smoke.
MATERIAL SAFETY DATA SHEET
MATERIAL SAFETY DATA SHEET
Metzger/McGuire Co. Page: 4 of 4 (Armor-Hard Extreme Part C)
Metzger/McGuire Co. Page: 1 of 4 (Armor-Hard Extreme Part C)
Concord, NH 03302 Date Prepared: 09/13/06
P. O. Box 2217 Date Prepared: 09/13/06
Telephone: (800) 223-6680 Revision Number: 1
Concord, NH 03302 Revision Number: 1
----------------------------------------------------------------------------------------------------------------------------
Telephone: (800) 223-6680
Section 15 - Regulatory Information
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Section 1 - Material Identification
US FEDERAL REGULATIONS:
----------------------------------------------------------------------------------------------------------------------------
Toxic Substances Control Act (TSCA): All components are included in the EPA Toxic Substances
Product Name: Armor-Hard Extreme (Filler)
Control Act (TSCA) Chemical Substance Inventory or are not required to be listed on the TSCA
Product Type: Aggregate Filler
Inventory.
Emergency Number (s): (800) 255-3924 24 hrs. (Continental U.S.)
OSHA (29CFR1910.1200) Hazard Class(es): Irritant. Carcinogen.
(813) 248-0585 24 hrs. (Outside Continental U.S.)
EPA Sara Title III Section 312 (40CFR370) Hazard Classes: Immediate Health Hazard. Delayed
Revision Notes: None
Health Hazard.
EPA Sara Title III Section 313 (40CFR372): Toxic chemicals above 鈥渄e minimus鈥? level: None. ----------------------------------------------------------------------------------------------------------------------------
Section 2 - Hazardous Ingredients
----------------------------------------------------------------------------------------------------------------------------
STATE REGULATIONS:
# wt % CAS Number Chemical Name
California Proposition 65 Substances: (components known to the State of California to cause
1. >1% 14808-60-7 Silica, Crystalline, Quartz
cancer and/or reproductive toxicity and subject to warning and discharge requirements under the
鈥淪afe Drinking Water and Toxic Enforcement Act of 1986鈥?). None
OSHA & ACGIH EXPOSURE LIMITS
INTERNATIONAL REGULATIONS
TWA STEL CEILING
Canada: WHMIS Hazard Classification: Class D, division 2B. Class D, division 2A.
Ppm Mg/m3 ppm Mg/m3 Ppm mg/m3
WHMIS Risk Phrases: Eye or skin irritant. May cause cancer.
N/E 15 dust N/E N/E N/E N/E
1. OSHA
WHMIS Symbols: Stylized T
N/E 10 dust N/E N/E N/E N/E
ACGIH
----------------------------------------------------------------------------------------------------------------------------
Section 16 - Other Information
N/E = Not Established
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
To the best of our knowledge, the information contained herein is accurate. However, neither
Section 3 - Health Hazards
Metzger/McGuire nor any of its agents assume any liability whatsoever for the accuracy or
----------------------------------------------------------------------------------------------------------------------------
completeness of the information contained herein. Final determination of suitability of any
material is the sole responsibility of the user. All materials may present unknown health hazards ********************************************************************************
and should be used with caution. Although certain hazards are described herein, we cannot EMERGENCY OVERVIEW
guarantee that these are the only hazards which exist. ********************************************************************************
HMIS HEALTH RATING: 1* FLAMMABILITY: 0 REACTIVITY: 0
Revision Date: 09/13/06 Replaces Revision Dated: N/A =======================================================================
HMIS Hazard Rating 飪? Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4
=======================================================================
A tan, grey or red granular solid. Causes eye and skin irritation. Prolonged inhalation of respirable
silica will result in permanent lung damage, silicosis.
Routes of Exposure: Eye Contact, Skin Contact, Inhalation.
Health Hazards: May cause eye irritation. Skin irritant.
Target Organs: Eyes, Skin, Lungs.
Signs and Symptoms of Exposure (Acute Effects): Contact with skin or eyes causes irritation,
redness and discomfort.
Signs and Symptoms of Exposure (Possible Longer Term Effects): Repeated and/or prolonged
exposure may cause allergic reaction/ sensitization. Repeated and/or prolonged exposure may result
in adverse eye effects (such as conjunctivitis or corneal damage), adverse skin effects (such as rash,
irritation or corrosion). Chronic exposure to quartz containing limestone dust in excess of TLV鈥檚 can Confined spaces, rooms, or tanks are areas where concern for TLV鈥檚 is especially important.
cause silicosis. Reference OSHA Regulation CFR 29 1910.134 for recommended respiratory protection.
Medical Conditions Generally Aggravated by Exposure: Eye disease, skin disorders and Protective Clothing: Clean, body covering clothing should be utilized.
allergies. Work and Hygienic Practices: Eye wash stations and safety showers should be easily accessible.
Carcinogens under OSHA, ACGIH, NTP, IARC, other: Silica, crystalline, quartz.
MATERIAL SAFETY DATA SHEET
MATERIAL SAFETY DATA SHEET
Metzger/McGuireCo. Page: 2 of 4 (Armor-Hard Extreme Part C)
Metzger/McGuire Co. Page: 3 of 4 (Armor-Hard Extreme Part C)
Concord, NH 03302 Date Prepared: 09/13/06
Concord, NH 03302 Date Prepared: 09/13/06
Telephone: (800) 223-6680 Revision Number: 1
Telephone: (800) 223-6680 Revision Number: 1
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Section 4 - First Aid
Section 9 - Typical Physical and Chemical Properties
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Eye Contact: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15
Physical Form: Granular Solid Density: Heavier than air
minutes. Seek medical attention.
> 200 飩癋
Color: Varies (tan, grey or red) Boiling Point:
Skin Contact: Remove contaminated clothing/shoes and wipe excess from skin. Flush skin with
Odor: None Melting Point: Not Applicable
water. Follow by washing with soap and water. If irritation occurs, seek medical attention.
pH: No Data Solubility in Water: Negligible
Inhalation: Remove victim to fresh air and provide oxygen. If breathing is difficult, seek medical
Vapor Pressure: No Data Specific Gravity: 2.65
attention.
----------------------------------------------------------------------------------------------------------------------------
Ingestion: If swallowed, call physician immediately. Induce vomiting only as directed by medical
Section 10 - Stability and Reactivity
personnel. Never give anything by mouth to an unconscious person. Get medical attention
----------------------------------------------------------------------------------------------------------------------------
immediately.
Chemical Stability: Stable
----------------------------------------------------------------------------------------------------------------------------
Conditions to Avoid (if unstable): None
Section 5 - Fire and Explosion Data
Incompatibility (Materials to Avoid): Acids, strong oxidizing agents.
----------------------------------------------------------------------------------------------------------------------------
Hazardous Decomposition Products: None
Flash Point (closed cup): N/A Upper Explosion Limit (UEL): No data
Hazardous Polymerization: None.
Auto Ignition Temperature: No data Lower Explosion Limit (LEL): No data
----------------------------------------------------------------------------------------------------------------------------
Fire Hazard Classification (OSHA/NFPA): None. Extinguishing Media: N/A.
--Section 11 - Toxicological Properties
Special Fire Fighting Procedures: N/A. Unusual Fire and Explosion Hazards: None known.
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Acute Oral Toxicity (LD50, RAT): No data available.
Section 6 - Accidental Release Measures
Acute Dermal Toxicity (LD50, RABBIT): No data available.
----------------------------------------------------------------------------------------------------------------------------
Acute Inhalation Toxicity (LC50, RAT): No data available.
Containment Techniques (Removal of ignition sources, diking, etc.): None necessary.
----------------------------------------------------------------------------------------------------------------------------
Clean-Up Procedures: Dust may be created due to spillage. Cleanup personnel may be exposed to
Section 12 - Ecological Information
excessive respriable dust. Wetting of spilled material and/or use of appropriate respirators may be
----------------------------------------------------------------------------------------------------------------------------
necessary.
No data available.
Other Emergency Advice: Wear protective clothing, boots, gloves, respirator, and eye protection.
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Section 13 - Disposal Considerations
Section 7 - Handling and Storage
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Storage: Store in a cool (60-80 飩癋), dry, ventilated place. Waste Disposal: This material does not contain any VOC鈥檚 (volatile organic compounds). Dispose
of material in accordance with applicable, local, state, and federal laws and regulations. The state
Handling: Avoid contact with skin, eyes, or clothing. When handling, do not eat, drink, or smoke.
and local regulations and laws may differ from federal regulations, and laws may change or be
Other Precautions: Wash thoroughly after handling. Remove contaminated clothing and gear.
reinterpreted. This information only applies to the material as manufactured. Processing, use, or
Decontaminate.
contamination may make the information in appropriate, inaccurate, or incomplete. Responsibility
----------------------------------------------------------------------------------------------------------------------------
for proper waste disposal is with the owner of the waste.
Section 8 - Personal Protection/Exposure Controls
----------------------------------------------------------------------------------------------------------------------------
----------------------------------------------------------------------------------------------------------------------------
Section 14 - Transport Information
Eye Protection: Chemical safety goggles recommended. Contact lenses should not be worn while
----------------------------------------------------------------------------------------------------------------------------
using this product.
DOT Non-Bulk Shipping Name: Sand NOI
Hand Protection: As needed to limit dust accumulation on hands.
UN#: N/A
Respiratory Protection: Use chemical goggles and impervious gloves. Selection of specific items
DOT Bulk Shipping Name: Sand NOI
such as boots and apron will depend on operation. Wear respirator protection whenever airborne
Packing Group: Not regulated
concentrations exceed TLV ceilings or TWA, use NIOSH approved respirators for listed hazard.
Technical Shipping Name: NMFC Item 90220, Class 50
IMO Shipping Data: Sand NOI
DOT Hazard Class: Not regulated
ICAO/IATA Shipping Data: Sand NOI
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