MATERIAL SAFETY DATA SHEET
Section 1. Chemical Product and Company Identification
IN CASE OF EMERGENCY:
Product name/ RS-88 Part A Polyol
Trade Name POLYOL AMINE MIXTURE
INFOTRAC: 1-800-535-5053
Manufacturer
Metzger McGuire Co INFORMATION: 1-800-669-5217
PO Box 2217
Concord, NH 03302
Date of Preparation: 1/18/07 Replaces: 1-26-05
Preparers Name Peter Spinney
Section 2. Composition, Information on Ingredients
Component Information Exposure Limits
CAS# OSHA PEL, TWA
TLV(ppm)ACGIH
Chemical Name
Poly(oxyalkylene) Amine Mixture N/A N/E
N/E
TLV鈥?-Threshold Limit Value exposure (8 hour, time weighted average unless otherwise noted) established by the American Conference of Governmental
Industrial Hygienists. PEL - OSHA Permissible Exposure Limit. N/E indicates that no exposure limit has been established.
Section 3. Hazards Identification
OSHA Hazard Classification: Non-Hazardous
Potential Health Effects Primary Routes of Exposure:
X Skin contact X Skin Absorption X Eye Contact X Inhalation X Ingestion
Routes of Exposure Symptoms
May cause lung damage with high acute exposure. Vapors and/or aerosols which may be formed
Inhalation
at elevated temperatures may be irritating to eyes and upper respiratory tract.
Dermal exposure can cause severe irritation and/or burns characterized by redness, swelling, and
Skin
scab formation. Prolonged skin exposure may cause permanent damage.
Severe irritation and/or burns can occur following exposure. Direct contact may cause impairment
Eyes
of vision and corneal damage. Rinsing of the eye should take place immediately.
Irritation and/or burns can occur to the gastrointestinal tract, including the stomach and intestines,
characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, and/or tissue ulceration
Ingestion
and perforation. Aspiration may lead to lung damage.
Inhalation: Prolonged or repeated exposure will cause more severe irritation and possibly lung
damage.
Skin Contact: Prolonged or repeated exposure may cause extensive permanent skin damage.
Chronic
Effects secondary to tissue destruction may also occur upon prolonged or repeated exposure.
Ingestion: There are no known or reported effects from chronic ingestion except for effects
similar to those experienced from single exposure.
OSHA: Not Regulated NTP: Not Listed IARC: Not Listed
Carcinogenicity
Section 4. First Aid Measures
Immediately wash the eyes with large amounts of tepid water for at least 15 minutes, occasionally
Eyes
lifting the lower and upper lids. Get medical attention immediately.
Immediately flush skin with plenty of water for 15 minutes. If clothing comes in contact with the
product, the clothing should be removed immediately and should be laundered before re-use. Get
Skin
medical attention immediately.
Remove individual to fresh air. Seek medical attention if breathing becomes difficult.
Inhalation
Call a physician immediately. DO NOT induce vomiting unless directed to do so by a physician.
Ingestion
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MATERIAL SAFETY DATA SHEET
Never give anything by mouth to an unconscious person.
Section 5. Fire Fighting Measures
Extinguishing Media:
X Water X Carbon Dioxide X Dry Chemical X Foam X Alcohol Foam
>200OF SETA Flash LEL: N/D UEL: N/D
Flash Point
Flash Pt. N/A Class Liquid
Flammability Classification OSHA/NFPA
Water, Carbon dioxide, dry chemical, alcohol foam.
Extinguishing Media
Isolate fire area and deny unnecessary entry.
Fire fighters should wear positive-pressure self-contained breathing apparatus (
SCBA) and protective clothing.
Unusual Fire and Explosions Hazards
Cool closed containers with WATER SPRAY to avoid rupture.
Heat from fire can generate vapor and decomposition products that may cause a
health hazard.
Section 6. Accidental Release Measures
Personal Protection for Emergency Situations: Additional protective clothing must be worn to prevent personal contact with
this material. Those items include but are not limited to boots, impervious gloves, hard hat, splash-proof goggles, impervious
clothing, i.e., chemically impermeable suit, self contained breathing apparatus.
Spill Mitigation Procedures
Air Release: Vapors may be suppressed by the use of water fog. Contain all liquid for treatment or neutralization.
Water Release: Notify all downstream users of possible contamination. Divert water flow around spill if possible and safe to do
so. Continue to handle as described in land spill.
Land Release: Create a dike or trench to contain materials. Absorb spill with inert material (e.g. dry sand, clay, earth or
commercial absorbent), then place in a chemical waste container. Do not place spill materials back in their original containers.
Dilute spilled materials with large amounts of water.
Additional Spill Information: Stop sources of spill as soon as possible and notify appropriate personnel. Utilize emergency
response personal protection equipment prior to the start of any response. Evacuate all non-essential personnel. Dispose of spill
residues per guidelines under Section XIII, Disposal consideration.
Section 7. Handling & Storage
Store material in a clean, cool, ventilated area away from all sources of ignition. Clean up spills at once. Keep container
tightly closed when not in use. Avoid skin and eye contact. Avoid breathing vapors if generated. Always wear protective
equipment. Wash hands and other exposed areas thoroughly after handling.
Provide appropriate ventilation/respiratory protection against nuisance dust during sanding/grinding of cured product.
Section 8. Exposure Controls/Personal Exposure
Avoid splashing. Wear chemical-resistant safety goggles or face shield. Contact
Eye Protection
lenses must not be worn.
Wear impervious gloves, boots and apron to avoid skin contact. A full
impervious suit is recommended if exposure is possible to a large portion of the
Skin Protection
body.
NIOSH approved air purifying respirator with organic vapor cartridge and
dust/mist filter. Air purifying respirators should not be used in oxygen deficient
Respiratory Protection
or IDLH atmospheres or if exposure concentrations exceed ten (10) times the
published limit.
Local exhaust ventilation or other engineering controls are necessary when
Ventilation
handling or using this product.
Emergency eye wash fountains and safety showers should be available in the
Other Precautions
immediate vicinity of any potential exposure.
Section 9. Physical and Chemical Properties
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MATERIAL SAFETY DATA SHEET
Percent Volatile Content by
Negligible 1.02
Specific Gravity (gm/cc)
Volume(PBV) or Weight (PBW)
No Data 8.5 lbs
VOC Content ( less water) Note 1 Weight per Gallon
No Data No Data
Boiling Point Evaporation Rate
No Data complete
Vapor Pressure (mm Hg) Solubility in Water
>1 liquid with ammonical odor
Vapor Density (Air=1) Appearance and Odor
Section 10. Stability and Reactivity
Stable
Stability
Oxidizing agents. Contact with water. High temperatures. Isocyanates.
Conditions to Avoid
Acids, strong oxidizing agents.
Incompatibility
Ammonia, carbon dioxide, carbon monoxide, oxides of nitrogen.
Hazardous Decomposition Products
Mixing large quantities of polyamines and diisocyanates will generate
significant heat. Uncontrolled cure conditions may char and decompose the
Hazardous Polymerization
resultant polymer generating unidentified toxic fumes and vapors.
Section 11. Toxicological Information Acute Toxicity (see Section 3. for Exposure Symptons)
Chemical Identity ORAL LD 50 DERMAL LD 50 Inhalation LC 50
No Data No Data No Data
Section 12. Ecological Information
No information available
Section 13 Disposal Considerations
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THIS
MATERIAL. THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES, AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR
HAZARDOUS AND NON HAZARDOUS WASTES.
If this product becomes a waste, it DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, in that it
does not exhibit the characteristics of hazardous waste of Subpart C, nor is listed as a hazardous waste under Subpart D.
As a non-hazardous waste, it should be disposed of in accordance with local, state and federal regulations.
No components subject to land ban restrictions.
Section 14 Transportation Information
THIS MATERIAL IS NOT REGULATED BY DOT.
Land (U.S.DOT): Liquid Plastic N.O.I.
SAME AS LAND
Water (IMO)
SAME AS LAND
Air (IATA/ICAO)
N/A
Identification
N/A
Packing Group
None
Label
Section 15. Regulatory Information
Regulations Governing Product:
Inventory Status: United States (TSCA) 鈥? The components of this product are listed on the TSCA Inventory of Existing
Chemical Substances.
SARA TITLE III
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MATERIAL SAFETY DATA SHEET
Hazard Categories Sections 311/312 (40 CFR 370.2): Health : None Physical : None.
Health Flammability Chemical Reactivity
HMIS Rating 1 1 0
Regulations Governing Ingredients
Chemical Name CAS #/ Category# CERCLA RQ EPCRA 313 RQ EPCRA 302 RQ EHS
Section 16 Other Information
REFERENCES
CRC Press: Handbook of Chemical and Physical Constants by David R. Lide
Merck & Company: The Merck Index
Sigma-Aldrich Company: Aldrich Handbook of Fine Chemicals
Dictionary of Toxicology by Robert Lewis
US Department of Transportation, Research and Special Programs Administration: Hazardous Materials Table
The information contained herein is given in good faith but no guarantee or warranty of any kind, expressed or implied,
is made with respect to the information above. Metzger McGuire Co. expressly disclaims any liability that may be
incurred in using the information contained herein.
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