SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET MM 231
Threshold Limited Value
ALDON 3
TWA: 0.2 mg/m as manganese dust and compounds: (ACGIH 1992-93).
1533 W.Henrietta Rd.
MM 231
Avon, New York 14414 MSDS No.
庐
CORPORATION September 30, 1996
Effective Date
(716) 226-6177
Effects of Overexposure EYES AND SKIN: May cause irritation. INHALATION: Long
term exposure to Manganese compounds can cause
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE Manganese poisoning. Symptoms include headfache, apathy
and spasms. INGESTION: Mild irritation.
Product MANGANOUS SULFATE CHEMTREC 1
Health
800-424-9300
Chemical
Emergency and INGESTION: If swallowed, if conscious, give one or two glasses of water
Manganese (II) Sulfate, Monohydrate
Synonyms 0
Fire
Day 716-226-6177 to drink, induce vomiting and call a physician. Never give anything by
First Aid Procedures
Formula MnSO4鈥2 O mouth to an unconscious person. INHALATION: Remove to fresh air. If
1
Reactivity
NFPA irritation or illness develops, get medical attention. If not breathing, give
HAZARD RATING HMIS *
Unit Size up to 2.5 Kg. artificial respiration. If breathing is difficult, give oxygen. SKIN: Flush
LEAST SLIGHT MODERATE HIGH EXTREME
thoroughly with water, then wash with mild soap and water. EYES: Flush
0 1 2 3 4
C.A.S. No. 10034-96-5 thoroughly with water for at least 15 minutes, lifting upper and lower eyelids
SECTION II INGREDIENTS OF MIXTURES occasionally. Get medical attention.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Excessive heat and fire.
Manganous Sulfate 100% See Section V.
Stable X
Incompatibility
Strong reducing agents.
(Materials to Avoid)
WARNING! HARMFUL IF SWALLOWED
Hazardous
OR INHALED. HARMFUL DUST. Sulfur dioxide and other oxides.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Stable 57-117掳C (134-242掳F) 2.95
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) N/A 48% X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) N/A N/A
=1)
( Butyl acetate
Steps to be taken in case
Vapor Density (Air=1) N/A Those involved in clean-up should use protection against skin
material is released or spilled contact or inhalation of dust or mist. Scoop up solid and place in
Solubility in Water 98.47 @ 48掳C (118掳F) sealable container for recovery or disposal. Reclaim and reuse
as much as possible.
Appearance & Odor Pale red, slightly efflourescent powder; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Non-flammable. N/A
% by Volume
(Method Used)
Dispose of in accordance with federal, state and local regulations.
Extinguisher
Water or dry chemical is suitable. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be needed in normal laboratory handling. If dusty conditions prevail,
Respiration Protection
wear a NIOSH-approved dust mask or respirator for fumes.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
In fire conditions, wear a NIOSH/MSHA-approved
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
self-contained breathing apparatus and full
protective clothing. Other Protective
Goggles, lab coat, eye wash station, ventilation hood, proper gloves.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Keep container tightly closed when not in use. Store in a cool,
in Handling & Storing
dry, well-ventilated area. Wash thoroughly after handling.
EXPLOSION HAZARDS Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Fire or excessive heat may produce hazardous Other Precautions
decomposition products of oxides of sulfur.
Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Use
with adequate ventilation. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date MR
No. 3 9/30/96 Michael Raszeja Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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